1.
ACS Macro Lett
; 3(1): 51-54, 2014 Jan 21.
Article
in English
| MEDLINE
| ID: mdl-35651108
ABSTRACT
Bulky monophosphine-ligated Pd complexes served as unprecedented admirable catalysts for the polymerization of a disubstituted acetylene. The moderately high polymer yields and cis content of the formed polyacetylene contrasted with those observed for traditional Mo catalyst-based polymer. These Pd catalysts are strong tools to promote the understanding of the structure-property relationships of disubstituted acetylenes.