ABSTRACT
The key components of photovoltaic (PV) systems are PV modules representing basic devices, which are able to operate durably in outdoor conditions. PV modules can be manufactured using different materials by different fabrication technologies. The main criteria supporting or limiting a successful placement of particular technologies on the market is the cost of electricity produced by PV systems. The Levelized Cost of Energy (LCOE) method takes into account the investment cost, the operating costs, and the total energy produced during the system service life. The influence of price, efficiency and service life of PV modules on LCOE (together with the availability of materials) sets limits for applicable technologies. Over the past 15 years a categorisation of generations of PV cell and module technology groups has been frequently used. The main features of individual technology groups are discussed from the view of the above criteria. Currently, PV modules are required to have: efficiency higher than 14%, price below 0.4 USD/Wp and service life of more than 15 years. At present, the wafer-based crystalline silicon technologies have best met the criteria due to their high efficiency, low cost and long service time; and due to the abundance of materials, they are set to lead in future PV power generation.
ABSTRACT
Optical absorptance spectroscopy of polycrystalline CH3NH3PbI3 films usually indicates the presence of a PbI2 phase, either as a preparation residue or due to film degradation, but gives no insight on how this may affect electrical properties. Here, we apply photocurrent spectroscopy to both perovskite solar cells and coplanar-contacted layers at various stages of degradation. In both cases, we find that the presence of a PbI2 phase restricts charge-carrier transport, suggesting that PbI2 encapsulates CH3NH3PbI3 grains. We also find that PbI2 injects holes into the CH3NH3PbI3 grains, increasing the apparent photosensitivity of PbI2. This phenomenon, known as modulation doping, is absent in the photocurrent spectra of solar cells, where holes and electrons have to be collected in pairs. This interpretation provides insights into the photogeneration and carrier transport in dual-phase perovskites.
