ABSTRACT
The structural and magnetic properties of the Y1-x Tb x MnO3 (0.1 ⩽ x ⩽ 0.3) compounds were investigated. Neutron diffraction patterns for all three samples, recorded at room temperature (RT), were fitted to the nuclear structure confirming the paramagnetic nature of the compounds. At 2.8 K, for the x = 0.1 sample magnetic moments of the Tb3+ ionic as well as Mn3+ ionic were ordered. At 5 K for the x = 0.2 sample only the Mn3+ ionic magnetic moments were ordered. There were six sites for Mn atoms. Three on the z = 0 plane and three on the z = 0.5 plane (where z corresponds to +c axis).The Mn3+ionic moments were confined to the a-b plane with a net magnitude of 2.78(3) µ B, and 2.90(3) µ B for the x = 0.1 and the x = 0.2 samples. The Tb3+ionic moments had a magnitude of 1.36(4) µ B at 2.8 K and were aligned antiferromagnetically along the crystallographic c-axis for the x = 0.1 sample. The low moment in comparison with Mn3+ free ions has been attributed to crystalline electric fields similar to that found in the parent compound YMnO3 and also in another rare earth manganite viz HoMnO3. The x = 0.3 sample was found to be a canonical spin glass. To investigate the role of the above spin ordering in Y1-x Tb x MnO3 in governing the phonon dynamics, temperature dependent Raman measurements were carried out. We observed the deviation of the phonon frequency near 685 cm-1 and its line-width from the expected anharmonic behaviour around magnetic ordering temperature for Tb substituted compounds with x = 0.1 and 0.2. This was attributed to the spin-phonon coupling in these systems. The anomalous behaviour of this phonon mode in the canonical spin glass compound with x = 0.3, indicated that the coupling sustained even in the presence of only local magnetic ordering.
ABSTRACT
We report the synthesis and electric properties of nano-crystalline Tb1-xYxMnO3 (x = 0, 0.1, 0.2, 0.3 and 0.4) compounds prepared by gel-combustion method. These samples were characterized by a number of techniques including X-ray diffraction (XRD), Raman spectroscopy, specific-heat measurement, neutron diffraction, and magnetic field dependent pyrocurrent measurement. All the samples crystallize in the orthorhombic structure with space group Pnma at room temperature. Anomalies were observed in low temperature specific-heat measurement corresponding to magnetic and electric phase transitions. The magnetic phase transitions occurred at ~35, ~22-28 and ~7 K for all the samples. Signatures of coupling between magnetic and electric order parameters were revealed by pyrocurrent measurements carried out in presence of magnetic fields.
ABSTRACT
A high-temperature neutron diffraction study has been carried out on La(0.75)Sr(0.25)CrO(3) compound in the temperature range 300-1400 K. On doping the parent compound LaCrO(3) with Sr at the La site, the orthorhombic (Pbnm) to rhombohedral ([Formula: see text]) structural transition shifts to lower temperatures. From quantitative Rietveld analysis it is found unequivocally that there is a two-phase coexistence (orthorhombic and rhombohedral phases with â¼89 and 11 weight%, respectively) in the temperature range 300-470 K and a three-phase coexistence (with a new cubic phase with space group Pm3m) in the temperature range 480-1400 K. The weight percentages of the orthorhombic, rhombohedral and cubic phases were found to be â¼49%, 37% and 14%, respectively, in the temperature range 480-1300 K, while over 1350-1400 K, the average weight percentages of orthorhombic, rhombohedral and cubic phases were found to be â¼41%, 41% and 18%, respectively. The coefficients of volume thermal expansion and linear thermal expansion have been determined for all three phases. The importance of the present study has been discussed for practical applications of the studied compound in solid oxide fuel cells.
