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Angew Chem Int Ed Engl
; 58(11): 3466-3470, 2019 Mar 11.
Article
in English
| MEDLINE
| ID: mdl-30632661
ABSTRACT
While the coordination chemistry of monometallic complexes and the surface properties of extended metal particles are well understood, the control of metal nanocluster formation has remained challenging. The isolation of discrete metal clusters provides an especially rare snapshot at the nanoscale of cluster growth. The synthesis and full characterization of the first early-transition-metal alkynyl cubane and the first µ3 -alkynyl Mn3 motif are reported.