The development of carbohydrate polymer- and protein-based biomaterials and their role in environmental health and hygiene: A review.

Biological macromolecules have been significantly used in the medicine due to their certain therapeutic values. Macromolecules have been employed in medical filed in order to enhance, support, and substitute damaged tissues or any other biological function. In the past decade, the biomaterial field has developed considerably because of vast innovations in regenerative medicine, tissue engineering, etc. Different types of biological macromolecules such as natural protein and polysaccharide etc. and synthetic molecules such as metal based, polymer based, and ceramic based etc. have been discussed. These materials can be modified by coatings, fibres, machine parts, films, foams, and fabrics for utilization in biomedical products and other environmental applications. At present, the biological macromolecules can used in different areas like medicine, biology, physics, chemistry, tissue engineering, and materials science. These materials have been used to promote the healing of human tissues, medical implants, bio-sensors and drug delivery, etc. These materials also considered as environmentally sustainable as they are prepared in association with renewable natural resources and living organisms in contrast to non-renewable resources (petrochemicals). In addition, enhanced compatibility, durability and circular economy of biological materials make them highly attractive and innovative for current research.The present review paper summarizes a brief about biological macromolecules, their classification, methods of synthesis, and their role in biomedicine, dyes and herbal products.

Chlorophyll sensitized (BiO)2CO3/ CdWO4/rGO nano-hybrid assembly for solar assisted photo-degradation of chlorzoxazone.

In the present laboratory scale experiment, we report the fabrication of chlorophyll sensitized (BiO)2CO3/CdWO4/rGO (BCR) photo-catalyst. The green approach has been adopted for boosting the optical activity by chlorophyll as a sensitizer. The functionality, nature and surface compositions of synthesized photo-catalyst have been identified by FTIR, XRD and XPS instrumentation. The internal and surface morphology has been studied using FE-SEM and HR-TEM. The optical activity has been investigated by UV-vis and photoluminescence spectroscopy. The catalytic activity of chlorophyll sensitized BCR have been tested for the photo degradation of Chlorzoxazone (CZX) under simulated visible light for 90 min. The detailed comparison has been studied for the different loading amount of chlorophyll and RGO onto BCR photo-catalyst. The potential of BCR for the photo-degradation of CZX was investigated under various operational parameters such as catalysts dosage, pollutant concentration, effect of pH and ions etc. Approximately, 96.2% of CZX has been degraded over 90 min with the optimum catalyst amount 250 mgL-1 at pH 7. The ●OH radical has been identified as major reactive species using radical scavenging experiment. The mineralization of CZX has been evaluated in terms of HR-MS and TOC-COD analysis.