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1.
Environ Int ; 178: 108072, 2023 08.
Article in English | MEDLINE | ID: mdl-37406371

ABSTRACT

Though with bioaccumulation and toxicity, chlorinated paraffins (CPs) are still high produced and widely utilized in various daily necessities for extender plasticization and flame retardation. CPs can be released during the reprocessing processes of finishing materials and distributed in multi-environmental media. Herein, concentrations and compositions of CPs in four representative media including interior finishing materials, PM10, total suspended particulate (TSP), and dust samples collected from eight interior finishing stages were studied. Unexpectedly, CP concentrations in ceramic tiles was found to be high with a mean value of 7.02 × 103 µg g-1, which could be attributed to the presence of CPs in the protective wax coated on ceramic tiles surfaces. Furthermore, the pollution characteristics of short-chain and medium-chain CPs (SCCPs and MCCPs) in those samples were inconsistent. According to the investigation regarding Kdust-TSP and [Formula: see text] , the occurrence and distribution of CPs in indoor atmospheric particles (PM10 and TSP) and dust were highly affected by reprocessing processes (cutting, hot melting, etc.) compared to that in the finishing materials. Moreover, dermal contact was the primary pathway of CP exposure for the occupational population (interior construction workers) for most interior finishing stages, and the interior finishing process is the prime CP exposure period for the occupational groups. As suggested by our assessment, though hardly posing an immediate health risk, CPs exposure still presents unneglected adverse health effects, which calls for adequate personal protections during interior finishing, especially in developing countries.


Subject(s)
Hydrocarbons, Chlorinated , Paraffin , Humans , Paraffin/analysis , Hydrocarbons, Chlorinated/analysis , Multimedia , Environmental Monitoring , Dust/analysis , China
2.
J Hazard Mater ; 441: 129911, 2023 01 05.
Article in English | MEDLINE | ID: mdl-36103764

ABSTRACT

Microplastics (MPs) pollution has become a serious global environment problem. It is therefore of practical significance to investigate the MP pollution caused by using plastic materials on a daily basis. In this study, different protective mobile phone cases (PMPCs) were selected as a representative plastic commodity that are in contact with the human body for long periods to explore the generation and transportation of MPs during 3 months of actual use. The average abundances were 1122 particles cm-2 on the PMPC and 314 particles cm-2 on the palm, respectively. There were four main kinds of MPs produced during the use of different PMPCs, which indicated that waste plastics may be recycled and used as raw materials, resulting in a complex PMPC composition. The median sizes of MPs on the surfaces of PMPCs and palms were 28 and 32 µm, respectively, which were smaller than the sizes reported in other studies. The combined effect of ultraviolet ageing and friction was the main reason for MP generation during daily PMPC use. Based on the results of a fitted regression equation and Monte Carlo simulation, the sharply generation of MPs may occur when PMPC was used for approximately 33 days.


Subject(s)
Cell Phone , Water Pollutants, Chemical , Environmental Monitoring , Humans , Microplastics , Plastics , Water Pollutants, Chemical/analysis
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