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1.
ACS Appl Mater Interfaces ; 13(2): 2483-2495, 2021 Jan 20.
Article in English | MEDLINE | ID: mdl-33404219

ABSTRACT

Influenza, pneumonia, and pathogenic infection of the respiratory system are boosted in cold environments. Low temperatures also result in vasoconstriction, restraint of blood flow, and decreased oxygen to the heart, and the risk of a heart attack would increase accordingly. The present face mask fabric fails to preserve its air-filtering function as its electrostatic function vanishes once exposed to water. Therefore, its filtering efficacy would be decreased meaningfully, making it nearly impracticable to reuse the disposable face masks. The urgent requirement for photothermal fabrics is also rising. Nanobased polyethyleneimine-polypyrrole nanopigments (NPP NPs) have been developed and have strong near-infrared spectrum absorption and exceptional photothermal convertible performance. Herein, the mask fabric used PE-fiber-constructed membrane (PEFM) was coated by the binding affinity of the cationic polyethyleneimine component of NPP NPs forming NPP NPs-PEFM. To the best of our knowledge, no study has investigated NPP NP-coated mask fabric to perform infrared red (solar or body) photothermal conversion efficacy to provide biocompatible warming, remotely photothermally captured antipathogen, and antivasoconstriction in vivo. This pioneering study showed that the developed NPP NPs-PEFM could be washable, reusable, breathable, biocompatible, and photothermal conversable for active eradication of pathogenic bacteria. Further, it possesses warming preservation and antivasoconstriction.


Subject(s)
Coated Materials, Biocompatible/chemistry , Nanostructures/chemistry , Polyethylene/chemistry , Polyethyleneimine/chemistry , Polymers/chemistry , Pyrroles/chemistry , Textiles/analysis , Animals , Anti-Bacterial Agents/chemistry , Infrared Rays , Masks/microbiology , Nanostructures/ultrastructure , Photochemical Processes , Rabbits , Rats , Temperature , Textiles/microbiology
2.
Int J Mol Sci ; 20(12)2019 Jun 14.
Article in English | MEDLINE | ID: mdl-31208013

ABSTRACT

Bacterial infections have caused serious threats to public health due to the antimicrobial resistance in bacteria. Recently, gold nanoclusters (AuNCs) have been extensively investigated for biomedical applications because of their superior structural and optical properties. Great efforts have demonstrated that AuNCs conjugated with various surface ligands are promising antimicrobial agents owing to their high biocompatibility, polyvalent effect, easy modification and photothermal stability. In this review, we have highlighted the recent achievements for the utilizations of AuNCs as the antimicrobial agents. We have classified the antimicrobial AuNCs by their surface ligands including small molecules (< 900 Daltons) and macromolecules (> 900 Daltons). Moreover, the antimicrobial activities and mechanisms of AuNCs have been introduced into two main categories of small molecules and macromolecules, respectively. In accordance with the advancements of antimicrobial AuNCs, we further provided conclusions of current challenges and recommendations of future perspectives of antimicrobial AuNCs for fundamental researches and clinical applications.


Subject(s)
Anti-Infective Agents/chemistry , Metal Nanoparticles/chemistry , Nanoconjugates/chemistry , Anti-Infective Agents/pharmacology , Bacteria/drug effects , Gold/chemistry
3.
J Phys Chem Lett ; 8(8): 1824-1830, 2017 Apr 20.
Article in English | MEDLINE | ID: mdl-28387117

ABSTRACT

Indoor utilization of emerging photovoltaics is promising; however, efficiency characterization under room lighting is challenging. We report the first round-robin interlaboratory study of performance measurement for dye-sensitized photovoltaics (cells and mini-modules) and one silicon solar cell under a fluorescent dim light. Among 15 research groups, the relative deviation in power conversion efficiency (PCE) of the samples reaches an unprecedented 152%. On the basis of the comprehensive results, the gap between photometry and radiometry measurements and the response of devices to the dim illumination are identified as critical obstacles to the correct PCE. Therefore, we use an illuminometer as a prime standard with a spectroradiometer to quantify the intensity of indoor lighting and adopt the reverse-biased current-voltage (I-V) characteristics as an indicator to qualify the I-V sampling time for dye-sensitized photovoltaics. The recommendations can brighten the prospects of emerging photovoltaics for indoor applications.

4.
Dalton Trans ; 44(33): 14613-24, 2015 Sep 07.
Article in English | MEDLINE | ID: mdl-26212237

ABSTRACT

We have synthesized four Ir(iii) metal complexes () bearing dual fluorine-free cyclometalates that are derived from 2',6'-dimethoxy-4-t-butyl-2,3'-bipyridine (pypy)H or 2-(2,4-dimethoxypyrimidin-5-yl)-4-t-butylpyridine (pmpy)H and a third ancillary, e.g. 5-pyridin-2-yl-pyrazolate (Pz) or 5-pyridin-2-yl-pyrrolide (Pr), respectively. The Ir(iii) complexes and were examined by X-ray diffraction studies for providing the structural proofs. Photophysical properties were next measured in CH2Cl2 at RT, among which the pypy complexes and showed an identical structured emission with an E0-0 peak located at 458 nm, while the corresponding pmpy derivative displayed the most blue-shifted E0-0 peak at 444 nm. Organic light-emitting diodes (OLEDs) were fabricated using multiple layered architecture and the aforementioned phosphor at 8 wt% doping level. The associated OLED performances, cf. max. E.Q.E. = 9.0%, 14.3%, 5.8% and 9.4% and CIEx,y coordinates at (0.16, 0.22), (0.16, 0.24), (0.16, 0.17) and (0.16, 0.20) at 100 cd m(-2) for phosphors in sequence, confirmed their potential to act as blue dopants for phosphorescent OLEDs.

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