Effects of different permeable lenses on nitrobenzene transport during air sparging remediation in heterogeneous porous media.

Air sparging (AS) is considered an effective remediation technology for groundwater contaminated by volatile organic compounds. However, the effects of AS remediation of heterogeneous aquifers with lenses of different permeability are still unclear, which limits the application of AS technology. In this study, the effects of different permeable lenses on nitrobenzene (NB) transport were quantitatively analysed by tracking the temporal and spatial evolutions of the NB concentration and using light transmission visualisation technology to observe airflow. Experimental results showed that the NB outside the airflow zone of the heterogeneous aquifer containing a gravel lens was rapidly removed, which is a special phenomenon. Through moisture content monitoring and colour tracer technology, the bubble-induced water circulation zone in a gravel lens was discovered during AS. At this time, the zone of influence (ZOI) included air flow zone and water circulation zone, while previous studies believed that the ZOI only contained the air flow zone. The presence of water circulation zone in the heterogeneous aquifer with a gravel lens increased the ZOI area and average contaminant removal flux by 5 and 2.3 times, respectively, compared with those in homogeneous aquifer. These findings have modified the conventional cognition about the ZOI and are conducive to an in-depth understanding of the remediation mechanisms and a better design of AS technology in heterogeneous aquifers with different permeable lenses.

Effects of air flowrate distribution and benzene removal in heterogeneous porous media during air sparging remediation.

The decrease of remediation effect during air sparging (AS) remediation in heterogeneous porous media has attracted increasing attention. In this study, an improved light transmission visualization method was used to investigate the air accumulation, migration and flowrate distribution in benzene-contaminated heterogeneous porous media during AS. Experimental results indicated that the benzene removal rate in the porous media was mainly controlled by air flowrate distribution which could be used as a major factor to evaluate the remediation effect. Visualization of air migration showed that air accumulation occurred below the geologic heterogeneous interface when ΔPe > 0 kPa (ΔPe: the air entry pressure difference of the media above and below the interface), and the accumulation thickness and length presented exponential decay increases with increasing ΔPe and air injection rates. Air flowrate was monitored by gas flow sensors, and the flowrate distributions were found as Gaussian distribution when ΔPe ≤ 0 kPa, trapezoidal distribution when 0 <ΔPe< 0.3 kPa and fingered distribution when ΔPe ≥ 0.3 kPa. Fingered distribution of air flowrate resulted in extremely nonuniform benzene removal above the interface and reduced the overall benzene removal rate. These findings reveal the reasons for the poor performance of AS remediation in heterogeneous porous media, leading to a better understanding of the remediation mechanisms in heterogeneous aquifer.

Mechanism study of the air migration and flowrate distribution in an aquifer with lenses of different permeabilities during air sparging remediation.

The poor performance of air sparging (AS) remediation in heterogeneous porous media is receiving increasing attention. However, understanding of the air migration and flowrate distribution mechanisms in heterogeneous aquifers is still lacking. In this study, for experimental purposes, a heterogeneous aquifer with lenses of different permeabilities was designed in the laboratory. The effects of the double interface between a lens and the background media on the air migration were visually observed for the first time, and four types of double interfaces and their related air flowrate distributions were identified. These were bimodal distribution (∆Pe ≤ -1.1 kPa, i.e., the air entry suction difference between the background media and the lens), fingered distribution for a low-permeability lens (-1.1 <∆Pe ≤ -0.3 kPa), Gaussian distribution (-0.3 <∆Pe < 0.4 kPa), and fingered distribution for a high-permeability lens (∆Pe ≥ 0.4 kPa). The experimental results indicated that double interface characteristics and air injection rates affected air accumulation behavior. A mathematical model was established to simulate the experimental data of the air flowrate distribution, and it could well describe the air flowrate distribution patterns in heterogeneous aquifers. These findings are significant for improving our understanding of the mechanisms of air migration and flowrate distribution in heterogeneous aquifers, leading to a better design and prediction of the AS remediation required for heterogeneous aquifer pollution.

Study on the effects of alcohol-enhanced air sparging remediation in a benzene-contaminated aquifer: a new insight.

In this study, the effects of medium carbon chain alcohol (1-heptanol)-enhanced air sparging (AS) on the remediation of benzene-contaminated aquifers in different media (medium sand, channelized flow; gravel, bubbly flow) were investigated by comparison with a commonly used surfactant (sodium dodecylbenzene sulfonate (SDBS)). The results showed that the addition of 1-heptanol and SDBS significantly increased the air saturation in AS process under different airflow modes. Combined with water retention curves, 1-heptanol had the same effect on reducing the surface tension of groundwater and stabilizing bubbles as SDBS. In the study of benzene pollution removal, when the removal efficiency of the benzene pollutant exceeded 95%, the time required for surfactant-enhanced AS (SEAS) and alcohol-enhanced AS (AEAS) in medium sand was shortened by 28.6% and 52.4%, respectively, and the time required for SEAS and AEAS in gravel media was shortened by 16.7% and 58.3%, respectively, compared with the time required for AS. This finding indicated that the addition of SDBS or 1-heptanol could significantly increase the removal rate of benzene pollutants. Under the same surface tension conditions, the removal effect of 1-heptanol on the benzene pollutant was better than that of SDBS. This difference was due to the disturbance of the flow field during AEAS process causing the 1-heptanol on the gas-liquid interface to volatilize in the carrying gas, thereby inducing Marangoni convection on the interface, enhancing the gas-liquid mass transfer rate, and increasing the removal rate of benzene on the interface. Therefore, 1-heptanol is promising as a new reagent to enhance AS to remediate groundwater pollution.