Rapid characterization of sulfur and phosphorus in organic waste by near infrared spectroscopy.

Near-infrared spectroscopy (NIRS) has recently emerged as a valuable tool for monitoring organic waste utilized in anaerobic digestion processes. Over the past decade, NIRS has significantly improved the characterization of organic waste by enabling the prediction of several crucial parameters such as biochemical methane potential, carbohydrate, lipid and nitrogen contents, Chemical Oxygen Demand, and kinetic parameters. This study investigates the application of NIRS for predicting the levels of Sulfur (S) and Phosphorus (P) within organic waste materials. The results for sulfur prediction exhibited a high level of accuracy, yielding an error of 1.21 g/Kg[TS] in an independently validated dataset, coupled with an R-squared value of 0.84. Conversely, the prediction of phosphorus proved to be slightly less successful, showing an error of 1.49 g/Kg[TS] with an R-squared value of 0.70. Furthermore, the disparities in performance seem to stem from the inherent correlation between the spectral data and the sulfur or phosphorus contents. Significantly, a variable selection technique known as CovSel was employed, shedding light on the differing approaches used for sulfur and phosphorus predictions. In the case of sulfur, the prediction was achieved through a direct correlation with wavelengths associated with sulfur-related functional groups (such as R - S(=O)2 - OH, -SH, and R-S-S-R) present in the NIR spectra. In contrast, phosphorus prediction relied on an indirect correlation with absorption bands related to organic matter (including CH, CH2, CH3, -CHO, R-OH, C = O, -CO2H, and CONH).

Determination of the optimal feed recipe of anaerobic digesters using a mathematical model and a genetic algorithm.

Recently, numerous experimental studies have been undertaken to understand the interactions between different feedstocks in anaerobic digestion. They have unveiled the potential of blending substrates in the process. Nevertheless, these experiments are time-intensive, prompting the exploration of various optimization approaches. Notably, genetic algorithms have gained interest due to their population-based structures allowing them to efficiently yield multiple Pareto-optimal solutions in a single run. This study uses a simplified static anaerobic co-digestion model as the fitness function for a multi-objective optimization. The optimization aims to achieve a methane production set-point while reducing the output ammonia nitrogen and increasing the recipe' profitability. Thus, the study employs genetic algorithms to identify Pareto fronts and constraints confined the solution space within feasible boundaries. It also underscores the influence of economic considerations on the viable solution space. Ultimately, the optimal feed recipe not only ensures stable operations within the digester but also enhances associated profits.

Combining pH and electrical conductivity measurements to improve titrimetric methods to determine ammonia nitrogen, volatile fatty acids and inorganic carbon concentrations.

Volatile fatty acids (VFA), inorganic carbon (IC) and total ammonia nitrogen (TAN) are key variables in the current context of anaerobic digestion (AD). Accurate measurements like gas chromatography and infrared spectrometry have been developed to follow the concentration of these compounds but none of these methods are affordable for small AD units. Only titration methods answer the need for small plant monitoring. The existing methods accuracy was assessed in this study and reveals a lack of accuracy and robustness to control AD plants. To solve these issues, a new titrimetric device to estimate the VFA, IC and TAN concentrations with an improved accuracy was developed. This device named SNAC (System of titration for total ammonia Nitrogen, volatile fatty Acids and inorganic Carbon) has been developed combining the measurement of electrical conductivity and pH. SNAC were tested on 24 different plant samples in a range of 0-0.16 mol.L(-1) TAN, 0.01-0.21 mol.L(-1) IC and 0-0.04 mol.L(-1) VFA. The standard error was about 0.012 mol.L(-1) TAN, 0.015 mol.L(-1) IC and 0.003 mol.L(-1) VFA. The coefficient of determination R(2) between the estimated and reference data was 0.95, 0.94 and 0.95 for TAN, IC and VFA respectively. Using the same data, current methods based on key pH points lead to standard error more than 14.5 times higher on VFA and more than 1.2 times higher on IC. These results show that SNAC is an accurate tool to improve the management of AD plant.