Advances in Surface-Enhanced Raman Scattering Sensors of Pollutants in Water Treatment.

Water scarcity is a world issue, and a solution to address it is the use of treated wastewater. Indeed, in these wastewaters, pollutants such as pharmaceuticals, pesticides, herbicides, and heavy ions can be present at high concentrations. Thus, several analytical techniques were initiated throughout recent years for the detection and quantification of pollutants in different types of water. Among them, the surface-enhanced Raman scattering (SERS) technique was examined due to its high sensitivity and its ability to provide details on the molecular structure. Herein, we summarize the most recent advances (2021-2023) on SERS sensors of pollutants in water treatment. In this context, we present the results obtained with the SERS sensors in terms of detection limits serving as assessment of SERS performances of these sensors for the detection of various pollutants.

Study of the influence of the supersaturation coefficient on scaling rate using the pre-calcified surface of a quartz crystal microbalance.

Scale deposition is a common issue in industrial plants, which creates technical problems, i.e. reduction of heat transfer, decrease of flow rate due to an obstruction of pipes. Therefore, the development of some appropriate methods based on well suitable in situ sensors to evaluate and predict the scaling propensity of water is a major concern in current research. This would be a good strategy for the optimization of anti-scaling treatments. In this study, scaling tests were carried out using a sensitive sensor, which has been developed using a quartz crystal microbalance with a pre-calcified electrode surface (SQCM). This technique allowed studying the influence of the supersaturation on the scaling rate. The set-up was tested with different water samples which were brought to a given supersaturation coefficient by degassing the dissolved CO2. The prediction of the scaling propensity of water was then possible through the relationship between the scaling rate on a pre-calcified surface and the supersaturation coefficient. In addition, the kinetics of CaCO3 deposit on the pre-calcified SQCM surface was found to be slower for natural water than for synthetic water (same calcium concentration). Furthermore, the activation energy for scale deposit, in synthetic water, was found to be 22 kJ.mol-1, which may be related to the diffusion of ions and/or CaCO3 nuclei in solution.