Stability of thin wetting films on chemically nanostructured surfaces.

The morphology and stability of thin volatile wetting films on model chemically patterned surfaces composed of periodic arrays of alternating completely and partially wettable nanostripes are investigated. The equilibrium film morphology is recorded as a function of undersaturation using noncontact atomic force microscopy. Films spanning the entire pattern are found to be stable only for thicknesses in excess of a critical value, h(c), whereas thinner films spontaneously dewet the partially wettable regions of the substrate. The critical thickness h(c) increases linearly with the width of the partially wettable stripes in good agreement with an interface displacement model derived from microscopic density functional theory. These results provide detailed insights into the dewetting of thin films driven by competing intermolecular forces.

Wetting of nanopatterned grooved surfaces.

The wetting by perfluoromethylcyclohexane of a well-defined silicon grating with a channel width of 16 nm has been studied using transmission small angle x-ray scattering. Prefilling, capillary filling, and postfilling wetting regimes have been identified. A detailed comparison of the data with theory reveals the importance of long-ranged substrate-fluid and fluid-fluid interactions for determining the wetting behavior on these length scales, especially at the onset of capillary condensation and in the prefilling regime.

The surface structure of concentrated aqueous salt solutions.

The surface-normal electron density profile rhos(z) of concentrated aqueous salt solutions of RbBr, CsCl, LiBr, RbCl, and SrCl2 was determined by x-ray reflectivity (XR). For all but RbBr and SrCl2 rhos(z) increases monotonically with depth z from rhos(z)=0 in the vapor (z<0) to rhos(z)=rhob of the bulk (z>0) over a width of a few angstroms. The width is commensurate with the expected interface broadening by thermally excited capillary waves. Anomalous (resonant) XR of RbBr reveals a depletion at the surface of Br- ions to a depth of approximately 10 A. For SrCl2, the observed rhos(z)>rhob may imply a similar surface depletion of Cl- ions to a depth of a few angstorms. However, as the deviations of the XRs of RbBr and SrCl2 from those of the other solutions are small, the evidence for a different ion composition in the surface and the bulk is not strongly conclusive. Overall, these results contrast earlier theoretical and simulational results and nonstructural measurements, where significant surface layering of alternate, oppositely charged, ions is concluded.