On Developing a Hydrophobic Rubberized Cement Paste.

It is well known that most cement matrix materials are hydrophilic. For structural materials, hydrophilicity is harmful because the absorption of water will induce serious damage to these materials. In this study, crumb rubber was pretreated by partial oxidation and used as an additive to develop a hydrophobic rubberized cement paste. The pretreated crumb rubber was investigated using Fourier-transform infrared spectrometry (FT-IR) to understand the function groups on its surface. The pyrolysis oil adsorbed on the surface of the crumb rubber was observed by FT-IR and nuclear magnetic resonance (NMR) spectroscopy. A colloid probe with calcium silicate hydrate (C-S-H) at the apex was prepared to measure the intermolecular interaction forces between the crumb rubber and the C-S-H using an atomic force microscope (AFM). Pure cement paste, cement paste with the as-received crumb rubber, and cement paste with pretreated crumb rubber were prepared for comparison. FT-IR, X-ray diffraction (XRD), and scanning electron microscopy (SEM) were used to understand the microstructure of the pastes. The static contact angle was used as the index of the hydrophobicity of the pastes. Experimental results showed that the hardened cement paste containing partially oxidized crumb rubber had excellent hydrophobic properties with an insignificant reduction in the compressive strength.

Application of Crumb Rubber in Cement-Matrix Composite.

Many studies have used rubber as an additive to form a cement-matrix composite (rubcrete). However, rubcrete has a lower mechanical strength than standard concrete. To improve the properties of rubcrete, this study performed surface modifications on crumb rubber through a partial oxidization reaction. The optimal ratio of air to nitrogen was determined by experiments to be 1:4. Fourier transform infrared spectroscopy (FT-IR) was used to identify the functional groups on the surface of the crumb rubber. A colloidal probe of calcium silicate hydrate (C⁻S⁻H) was prepared, and the intermolecular interactions between the rubber and the C⁻S⁻H were measured using an atomic force microscope (AFM). The experimental results showed that the partially oxidized crumb rubber contained more hydrophilic S⁻O bonds. The intermolecular force between C⁻S⁻H and treated rubber increased by 23% compared to the force between the original rubber and C⁻S⁻H. The compressive strength of the hardened cement paste (56 days) with the treated crumb rubber increased 50% in comparison with that of the hardened cement paste with the as-received crumb rubber.

Recovery of cutting fluids and silicon carbide from slurry waste.

The wafer slicing process generates large amounts of slurry waste. The recovery of cutting oil and abrasives from slurry waste can reduce both the cost and environmental damage. A process combining magnetic precipitation and flocculation was developed for the recovery of cutting oil. A magnetic precipitation tank was employed for storage of the slurry and acceleration of the settlement of suspended particles. The larger particles further aggregate upon adding a non-aqueous flocculant comprising polyacrylamide (PAM) and ethylene glycol (EG). The recycled oil product is obtained by centrifugation and bag filtration. The physical properties and wafer dicing tests indicate that the recycled oil is qualified. Wafer manufacturers can thus reduce costs by using this process to produce recycled oil. A magnetic reactor with alkaline aqueous successfully recycled the SiC powder from the slurry waste by converting all the silicon species into sodium silica for further use. The results demonstrate that the magnetic reactor is able to remove most metal species and that the alkaline aqueous medium can recover all the Si substances in a sodium silicate solution, also called water glass.

Recurrent Pregnancy Loss in Women with Killer Cell Immunoglobulin-Like Receptor KIR2DS1 is Associated with an Increased HLA-C2 Allelic Frequency.

PROBLEM: During human pregnancy, the uterine lining is highly populated with killer-immunoglobulin-like receptor (KIR)-expressing NK cells that recognize HLA-C molecules on trophoblast cells. The goal of this study was to analyze the KIR gene contents and frequencies in a N. American cohort of women with RPL of unknown etiology to evaluate whether there is a genetic susceptibility to RPL based on a woman's KIR repertoire and her HLA-C group, as well as the HLA-C group of the partner. METHOD OF STUDY: The frequencies of KIR and HLA-C1 and HLA-C2 genes were evaluated in 139 Caucasian women with RPL; HLA-C1, and HLA-C2 group genes were analyzed in their partners (n = 42). The gene frequencies were compared with data reported from corresponding populations. RESULTS: Overall, the frequencies of HLA-C groups and KIR genes and genotypes in RPL cohort resembled the frequencies for US Caucasians. The HLA-C1 and HLA-C2 group distribution was significantly different between women with or without KIR2DS1. Women positive for KIR2DS1 (45.3% of the study cohort) had an increased frequency of its ligand, HLA-C2 (0.5159 versus 0.3684 in KIR2DS1 negative women, P = 0.014). CONCLUSION: Our results indicate that among KIR2DS1 pos women, the co-expression of HLA-C2 is associated with RPL.