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1.
Huan Jing Ke Xue ; 41(9): 4042-4052, 2020 Sep 08.
Article in Chinese | MEDLINE | ID: mdl-33124284

ABSTRACT

Eutrophication of shallow lakes in the middle and lower reaches of the Yangtze River has become an increasingly serious problem. In this study, we investigated the temporal and spatial variations in nutrient loads (nitrogen, N and phosphorus, P) in the Changdang Lake Catchment located to the northwest of Lake Taihu through field sampling and laboratory analysis in 2016-2017. The results show the severity of the N and P pollution in the Changdang Lake catchment. The mean river water concentrations of TN, NO3--N, NH4+-N, TP, Chla, and permanganate index are (3.70±0.76) mg ·L-1, (1.81±0.42) mg ·L-1, (1.03±0.61) mg ·L-1, (0.38±0.31) mg ·L-1, (25.74±37.00) µg ·L-1, and (6.35±0.81) mg ·L-1, respectively. N pollution in the river is more severe in winter and spring than in summer and autumn whereas P pollution in the river is worse in autumn and winter than in spring and summer. Spatially, the magnitude of river N and P pollution follows the order of northern > northwestern > southern > eastern part of the study area. The rivers are in a state of moderate to severe eutrophication. The mean lake water concentrations of TN, NO3--N, NH4+-N, TP, Chla, and permanganate index are (2.25±0.94) mg ·L-1, (0.98±0.47) mg ·L-1, (0.19±0.14) mg ·L-1, (0.11±0.03) mg ·L-1, (18.71±8.76) µg ·L-1, and (4.59±1.09) mg ·L-1, respectively. The water quality in Changdang Lake is categorized as worse than class Ⅲ for TN and TP concentrations, which show decreasing trends from the west to the east to the south of the lake. The lake is in a status of slight to moderate eutrophication. The lake water quality is affected by the combination of sewage discharge and non-point source pollutant losses. The inflow rivers including the Danjinlicao River, Tongji River, and Xuebu River are the dominant pollution sources for Changdang Lake. The Danjinlicao River transports 10-12 times the total N and P loads transported by Tongji and Xuebu rivers. Changes in land use and atmospheric deposition are the driving factors of the deterioration of water quality and eutrophication in the catchment.


Subject(s)
Rivers , Water Pollutants, Chemical , China , Environmental Monitoring , Eutrophication , Lakes , Nitrogen/analysis , Nutrients , Phosphorus/analysis , Water Pollutants, Chemical/analysis
2.
RSC Adv ; 9(58): 33710-33715, 2019 Oct 18.
Article in English | MEDLINE | ID: mdl-35528890

ABSTRACT

A suitable annealing temperature was found by adopting the sol-gel method to prepare silicon-based molybdenum sulfide film heterojunction solar cells. As shown by the results, a change in the efficiency of the solar cells, which was attributed to the fact that as the annealing temperature rises, the degree of crystallization of the film increases continuously, the degree of order of the crystal particles goes up first and then goes down, and the temperature change affects the proportion of Mo in different valence states. By comparison, it was found that when the temperature reached 500 °C, the degree of order of the film was raised and the film was in the initial zone from the amorphous to the microcrystal phase change and the proportion of Mo 6+ was relatively large, increasing the conversion efficiency of the device power to 7.55% and laying a good basis for preparing high-performance solar batteries made in the two-dimensional materials. When the annealing temperature continues to rise, the intergranular defects increase, and the overall degree of order of the film decreases. Furthermore, the highly crystalline thin films and the improvement in the device efficiency can be controlled if we obtained the relationship between the annealing temperature and the layers of the two-dimensional materials.

3.
Environ Sci Pollut Res Int ; 25(35): 35287-35300, 2018 Dec.
Article in English | MEDLINE | ID: mdl-30341757

ABSTRACT

The water quality of headwater streams is a worldwide concern because of their critical roles in supplying clean water for drinking and other consumptive uses. Here, we evaluate temporal trends and spatial dynamics of the permanganate index (COD), ammonia-nitrogen (AN), and total phosphorus (TP) for 31 sites in headwater watersheds of the Huai River Basin, China. The seasonal Mann-Kendall test and correlation and variance analyses were applied to long-term time series (2003-2010) of water quality data in order to investigate the patterns of water quality trends, as well as their linkages with the watershed landscape. The results indicated that (1) more than 1/3 of headwater monitoring sites have exhibited either significantly increasing or decreasing trends in COD, AN and TP, while only TP increased for most them; (2) obvious increasing concentration gradients were observed for all water quality parameters along the upstream to the downstream continuum. Such spatial patterns can be highly explained by land cover and landscape configuration metrics. The percent of urban land and urban-related landscape metrics (such as the Landscape Division Index) were the primary explanatory variables for AN, while the aggregation metrics of cropland and urban land cover were the main predictors of COD and TP; (3) historical dynamics of COD, AN, and TP were influenced by land cover transitions. The trends of COD and TP may be attributable to the change in the wetland landscape, while the trends of AN were likely related to changes in forestland area as well as environmental management. Overall, our study determined the spatial and temporal dynamics of water quality parameters in the headwater watersheds and interpreted the possible reasons behind their spatio-temporal dynamics, which can have important implications for sustainable landscape planning as well as headwater watershed management.


Subject(s)
Environmental Monitoring , Water Pollution, Chemical/statistics & numerical data , China , Phosphorus/analysis , Rivers , Spatio-Temporal Analysis , Water/analysis , Water Pollutants, Chemical/analysis , Water Quality
4.
Sci Total Environ ; 557-558: 296-306, 2016 07 01.
Article in English | MEDLINE | ID: mdl-27016677

ABSTRACT

As an internationally important wetland for migratory waterbirds, China's Poyang Lake region has experienced substantial changes in land use during the past two decades owing to climate change and anthropogenic disturbances. Recent dam constructions on the Yangtze River and its tributaries for agriculture and hydroelectric power exert strong effects on the hydrological regimes of this lake. However, few studies have investigated how the land-use changes through time affect the habitat suitability for wintering Anseriformes-the largest community in this region. Thus, it is necessary to timely monitor changes in the habitat quality and understand the potential factors that alter it. In this study, three periods (1995, 2005 and 2014) of typical environmental indicators that have direct impacts on foraging and resting for the Anserformes, including proximity to water (density of lakes, rivers and ponds), human disturbances (density of residences and various road networks), preferred land cover types and food availability (NDVI), are integrated to develop a habitat suitability index model for habitat mapping. The results indicate that long-term lake shrinkage in low-water periods led to greatly expanded wetlands in these years, which provided more suitable habitat for migratory waterfowl. The amount of highly suitable habitat in 2014 was nearly twice as much as in 1995. Recent survey data from 1997 to 2013 also revealed an increase in the population size, and confirmed the improvement of habitat suitability in the Poyang Lake region. Spatial analysis revealed that land use changes contributed most to the improved habitat coverage between 1995 and 2014. However, the relative significances of these transformations for highly suitable and moderately suitable habitats are strikingly different. Increases in wetland and paddy field area are the main reasons for explaining these improvements, respectively. The framework model proposed in this study will help governments to evaluate habitat conservation and restoration for protecting waterbirds in a spatially explicit way.


Subject(s)
Anseriformes/physiology , Ecosystem , Environmental Monitoring , Agriculture , Animals , China , Climate Change , Conservation of Natural Resources , Lakes , Wetlands
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