ABSTRACT
Methane (CH4)/air lean combustion can be enhanced by increasing the concentration of the oxidizer, like oxygen (O2) enrichment, or adding a strong oxidant to the reactant. Hydrogen peroxide (H2O2) is a strong oxidizer that yields O2, steam, and appreciable heat after decomposition. This study numerically investigated and compared the effects of H2O2 and O2-enriched conditions on the adiabatic flame temperature, laminar burning velocity, flame thickness, and heat release rates of CH4/air combustion using the San Diego mechanism. The result showed that in fuel-lean conditions, the adiabatic flame temperature changed from H2O2 addition > O2-enriched scenario to O2-enriched scenario > H2O2 addition with increasing α. This transition temperature was not affected by the equivalence ratio. Adding H2O2 enhanced the laminar burning velocity of the CH4/air lean combustion more than the O2-enriched scenario. The thermal and chemical effects are quantified in various H2O2 additions, and it is found that the chemical effect has a noticeable contribution to the laminar burning velocity compared with the thermal effect, especially in higher H2O2 addition. Further, the laminar burning velocity had a quasi-linear correlation with (OH)max in the flame. The maximum heat release rate was observed at lower temperatures for H2O2 addition and higher temperatures for the O2-enriched scenario. The flame thickness was significantly reduced upon adding H2O2. Finally, the dominant reaction to the heat release rate changed from the reaction of CH3 + O â CH2O + H in the CH4/air or O2-enriched scenario to the reaction of H2O2 + OH â H2O + HO2 in the H2O2 addition scenario.
ABSTRACT
In recent years, cases of the improper utilization of steel furnace slag have been widely reported, resulting in a crisis of nowhere for recycled resources such as inorganic slag. The misplacement of resource materials that originally had sustainable-use value not only has a great impact on society and the environment but also greatly reduces industrial competitiveness. To solve the dilemma of steel furnace-slag reuse, it is critical to find solutions to the stabilization of steelmaking slag under the innovative thinking of the circular economy. In addition to enhancing the reuse value of recycled resources, the balance between economic development and environmental impact is also crucial. The high-performance building material could provide a solution based on a high-value market. With the development of society and the increasing requirements for quality of life, the requirements for the soundproof and fireproof performance of lightweight decorative panels common in cities have gradually become popular. Therefore, the high performance of fire retardant and soundproofing could be the main development focus of high-value building materials to ensure circular economic feasibility. This study continues the research results of the application of inorganic re-cycled engineering materials in recent years, and the application of electric-arc furnace (EAF)-reducing slag to the development of base materials for reinforced cement boards, in order to complete the development of high-value panels with fireproof and sound-insulation properties in line with the engineering characteristics of the boards. The research results showed the optimization of the proportions of the cement boards with EAF-reducing slag as a raw material. The proportions of EAF-reducing slag to fly ash at ratios of 70:30 and 60:40 all met the requirements of ISO 5660-1 Class I flame resistance; the sound transmission loss in the overall frequency band can reach more than 30 dB, which is higher by 3-8 dB or more than the same board with similar specifications (such as 12 mm gypsum board) in the present building-materials market The products could be developed into building partitions and ceiling decoration boards with high performance in terms of fire retardant and soundproofing values, and also reduce the use of natural raw materials by more than 35%. The results of this study could meet environmental compatibility targets and contribute towards greener buildings. This model of circular economics would achieve energy reduction, emissions reductions, and be environmentally friendly.
ABSTRACT
Because of incomplete recycling resource management and technology development, inorganic sludge and slag has been misused in Taiwan. The recycling of inorganic sludge and slag is a pressing crisis. Resource materials with a sustainable use value are misplaced and have a significant impact on society and the environment, which greatly reduces industrial competitiveness. To solve the dilemma of EAF oxidizing slag recycled from the steel-making process, it is important to find solutions to improve the stability of EAF oxidizing slags based on the innovative thinking of the circular economy. We can improve the value of recycling resources and solve the contradiction between economic development and environmental impact. The project team intends to investigate the development and application of reclaiming EAF oxidizing slags blended with fire-retardant materials, which will integrate R&D work from four different aspects. First, a verification mechanism is carried out to establish stainless steel furnace materials. Suppliers must be assisted in conducting quality management for EAF oxidizing slags to ensure the quality of the materials provided. Next, high-value building materials must be developed using slag stabilization technology, and fire-retardant tests must be conducted on the recycled building materials. A comprehensive evaluation and verification of the recycled building materials must be undertaken, and high-value green building materials must be produced with fire-retardant and sound-proofing characteristics. Integration with national standards and regulations can drive the market integration of high-value building materials and the industrial chain. On the other hand, the applicability of existing regulations to facilitate the legal use of EAF oxidizing slags will be explored.
