Photoluminescence of Nitrogen-Vacancy Centers by Ultraviolet One- and Two-Photon Excitation of Fluorescent Nanodiamonds.

Fluorescent nanodiamonds contain nitrogen-vacancy (NV) centers as quantum defects. When exposed to a continuous-wave 325 nm laser or a femtosecond 344 nm laser, the particles emit red fluorescence from NV0 centers at ∼620 nm. Power dependence measurements of the emission strength revealed a predominantly linear behavior at the laser peak intensity lower than 1 GW·cm-2, contributed mainly by photoexcitation of electrons from the valence band of diamond to the NV0 centers, followed by relaxation via electron-hole recombination. In the higher power regions, however, nonresonant two-photon interband excitation of the diamond matrix dominates the photoluminescence processes. Best fits of the experimental data to semiempirical models revealed an ionization coefficient of ∼1 cm-1 for the one-photon valence-to-defect excitation and a saturation intensity of 180 ± 60 GW·cm-2 for the two-photon interband excitation. The study provides new insight into the photoionization of NV0 centers and the interband excitation properties of diamond in the UV region.

Compact, tunable polarization transforming reflector for quasi-optical devices used in terahertz science.

We describe the design, fabrication, and characterization of a compact polarization transforming reflector (PTR). The device can be easily tuned over a broad frequency range, has very little insertion losses, and can easily be integrated into quasi-optical systems that are based on a half-cube design. By varying the distance between the wire grid and a flat mirror, the polarization state of an arbitrary polarized Gaussian incident beam can be set to an output Gaussian beam in either linear or circular polarization. In addition, by varying the orientation of the wire grid, the PTR can be used as a universal polarizer, a property that has not been discussed or demonstrated in the literature. The ability to control the electric field polarization at Terahertz (THz) frequencies is essential for many applications, such as THz spectroscopy and high-field electron paramagnetic resonance spectroscopy.

Relaxation of a dense ensemble of spins in diamond under a continuous microwave driving field.

Decoherence of Rabi oscillation in a two-level quantum system consists of two components, a simple exponential decay and a damped oscillation. In dense-ensemble spin systems like negatively charged nitrogen-vacancy (NV-) centers in diamond, fast quantum state decoherence often obscures clear observation of the Rabi nutation. On the other hand, the simple exponential decay (or baseline decay) of the oscillation in such spin systems can be readily detected but has not been thoroughly explored in the past. This study investigates in depth the baseline decay of dense spin ensembles in diamond under continuously driving microwave (MW). It is found that the baseline decay times of NV- spins decrease with the increasing MW field strength and the MW detuning dependence of the decay times shows a Lorentzian-like spectrum. The experimental findings are in good agreement with simulations based on the Bloch formalism for a simple two-level system in the low MW power region after taking into account the effect of inhomogeneous broadening. This combined investigation provides new insight into fundamental spin relaxation processes under continuous driving electromagnetic fields and paves ways to better understanding of this underexplored phenomena using single NV- centers, which have shown promising applications in quantum computing and quantum metrology.