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Carbohydr Polym ; 90(4): 1609-13, 2012 Nov 06.
Article in English | MEDLINE | ID: mdl-22944423

ABSTRACT

Nanocellulose from sugarcane bagasse was isolated by high pressure homogenization in a homogeneous media. Pretreatment with an ionic liquid (1-butyl-3-methylimidazolium chloride ([Bmim]Cl)) was initially involved to dissolve the bagasse cellulose. Subsequently, the homogeneous solution was passed through a high pressure homogenizer without any clogging. The nanocellulose was obtained at 80 MPa for 30 cycles with recovery of 90% under the optimum refining condition. Nanocellulose had been characterized by Fourier transformed infrared spectra, X-ray diffraction, thermogravimetric analysis, rheological measurements and transmission electron microscopy. The results showed that nanocellulose was 10-20 nm in diameter, and presented lower thermal stability and crystallinity than the original cellulose. The developed nanocellulose would be a very versatile renewable material.


Subject(s)
Cellulose/isolation & purification , Imidazoles/chemistry , Nanostructures/chemistry , Saccharum/chemistry , Cellulose/chemistry , Cellulose/ultrastructure , Hydrolysis , Microscopy, Electron, Transmission , Molecular Structure , Pressure , Spectroscopy, Fourier Transform Infrared , Temperature , Thermogravimetry , X-Ray Diffraction
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