Nonvolatile chirality switching in terahertz chalcogenide metasurfaces.

Actively controlling the polarization states of terahertz (THz) waves is essential for polarization-sensitive spectroscopy, which has various applications in anisotropy imaging, noncontact Hall measurement, and vibrational circular dichroism. In the THz regime, the lack of a polarization modulator hinders the development of this spectroscopy. We theoretically and experimentally demonstrate that conjugated bilayer chiral metamaterials (CMMs) integrated with Ge2Sb2Te5 (GST225) active components can achieve nonvolatile and continuously tunable optical activity in the THz region. A THz time-domain spectroscopic system was used to characterize the device, showing a tunable ellipticity (from ‒36° to 0°) and rotation of the plane polarization (from 32° to 0°) at approximately 0.73 THz by varying the GST225 state from amorphous (AM) to crystalline (CR). Moreover, a continuously tunable chiroptical response was experimentally observed by partially crystallizing the GST225, which can create intermediate states, having regions of both AM and CR states. Note that the GST225 has an advantage of nonvolatility over the other active elements and does not require any energy to retain its structural state. Our work allows the development of THz metadevices capable of actively manipulating the polarization of THz waves and may find applications for dynamically tunable THz circular polarizers and polarization modulators for THz emissions.

Terahertz metasurface with multiple BICs/QBICs based on a split ring resonator.

Bound state in the continuum (BIC) refers to the trapped state in the radiation continuum of a system. In the terahertz band, BIC provides a unique and feasible method to design devices with ultra-high quality factor (Q factor) and to achieve intense terahertz-matter interaction, which is of great value to terahertz science and technology. Here, multiple BICs protected by the resonance symmetry in the terahertz metasurface consisting of metallic split ring resonators (SRR) is demonstrated. The evolution from the BIC to the quasi-BIC (QBIC) is induced by changing the gap width of the SRRs. The proposed BICs are experimentally demonstrated and analyzed by the coupled mode theory along with the numerical simulation. It is found that the leakage behavior of these QBICs is strongly affected by the intrinsic Ohmic loss in the SRRs while it is quite robust to the tilted incidence.

Spin-Decoupled Interference Metasurfaces for Complete Complex-Vectorial-Field Control and Five-Channel Imaging.

Light is a complex vectorial field characterized by its amplitude, phase, and polarization properties, which can be further represented by four basic parameters, that is, amplitudes and phases of two orthogonally polarized components. Controlling these parameters simultaneously and independently at will using metasurfaces are essential in arbitrarily manipulating the light propagation. However, most of the studies so far commonly require a great number of different meta-atoms or rely on diffraction under oblique incidence, which lack convenience and flexibility in design and implementation. Here, a new metasurface paradigm is proposed that can completely manipulate the amplitudes and phases of two spin components based on the interference effect, where only two different meta-atoms are applied. For proof-of-concept demonstration, two five-channel meta-holograms for imaging and information encryption are designed and experimentally characterized. The interference method provides a simple route toward compact complex and multifunctional meta-devices.

Terahertz multi-level nonvolatile optically rewritable encryption memory based on chalcogenide phase-change materials.

Fast and efficient information processing and encryption, including writing, reading, and encryption memory, is essential for upcoming terahertz (THz) communications and information encryption. Here, we demonstrate a THz multi-level, nonvolatile, optically rewritable memory and encryption memory based on chalcogenide phase-change materials, Ge2Sb2Te5 (GST). By tuning the laser fluence irradiated on GST, we experimentally achieve multiple intermediate states and large-area amorphization with a diameter of centimeter-level in the THz regime. Our memory unit features a high operating speed of up to 4 ns, excellent reproducibility, and long-term stability. Utilizing this approach, hexadecimal coding information memories are implemented, and multiple writing-erasing tests are successfully carried out in the same active area. Finally, terahertz photoprint memory is demonstrated, verifying the feasibility of lithography-free devices. The demonstration suggests a practical way to protect and store information and paves a new avenue toward nonvolatile active THz devices.

Integrated Terahertz Generator-Manipulators Using Epsilon-near-Zero-Hybrid Nonlinear Metasurfaces.

In terahertz (THz) technologies, generation and manipulation of THz waves are two key processes usually implemented by different device modules. Integrating THz generation and manipulation into a single compact device will advance the applications of THz technologies in various fields. Here, we demonstrate a hybrid nonlinear plasmonic metasurface incorporating an epsilon-near-zero (ENZ) indium tin oxide (ITO) layer to seamlessly combine efficient generation and manipulation of THz waves across a wide frequency band. The coupling between the plasmonic resonance of the metasurface and the ENZ mode of the ITO thin film enhances the THz conversion efficiency by more than 4 orders of magnitude. Meanwhile, such a hybrid device is capable of shaping the polarization and wavefront of the emitted THz beam via the engineered nonlinear Pancharatnam-Berry (PB) phases of the plasmonic meta-atoms. The presented hybrid nonlinear metasurface opens a new avenue toward miniaturized integrated THz devices and systems with advanced functionalities.

Temperature-controlled terahertz polarization conversion bandwidth.

Active control of metasurfaces has attracted widespread attention because of the adjustable electromagnetic properties obtained. Here we designed and experimentally studied a dynamically controllable polarization converter in the terahertz band. By designing the structural parameters and utilizing the insulator-to-metal phase transition of vanadium dioxide and principle of current resonance, dynamic tunability of the polarization conversion function from dual-broadband (0.45∼0.77 THz and 0.97∼1.2 THz) to ultra-broadband (0.38∼1.20 THz) can be realized with a high polarization conversion ratio. The scheme proposed here can find potential applications in integrated terahertz systems, sensing, imaging and communications areas.

Coupling Plasmonic System for Efficient Wavefront Control.

Efficient and flexible manipulation of electromagnetic waves using metasurfaces has attracted continuous attention in recent years. However, previous studies mainly apply sole resonance effect to accomplish the task. Here, we show that introducing a meta-coupling effect would reveal further physical insights in the electromagnetic wave control. To demonstrate this, a reflection-type coupling system composed by two identical linear resonances in a metal-insulator-metal configuration is theoretically proposed using the coupled-mode theory, whose phase diagram can be well controlled upon the coupling changes. Such intriguing optical property is verified by a double C-shaped resonator in the terahertz regime, where the coupling effect can be tuned by changing their either relative distance or rotation. More importantly, the reflection phase shift around the working frequency can be efficiently engineered without having to change the dimensions of the resonators. Two efficient anomalous metasurface deflectors are designed and experimentally characterized, whose maximum measured efficiency is more than 70%. The proposed controlling strategy further enriches the designing freedoms of metasurfaces and may find broad applications in realizing efficient and tunable functional devices.

Extrinsic optical activity in all-dielectric terahertz metamaterial.

Chiral metamaterials have attracted wide interest because strong optical activity at designed frequencies could be achieved beyond that in natural materials. Here we propose an all-dielectric metamaterial with strong extrinsic circular dichroism and circular birefringence by periodically arranging symmetry-broken dielectric Mie resonators at terahertz frequencies. The strong interaction between the electric and magnetic resonances from circularly polarized incident waves dominates the performance of the all-dielectric metamaterial, which exhibits a 60% circular dichroism in transmission and a polarization rotation angle of 60° at maximum, respectively. Additionally, the spectral range of the circular dichroism with preserved amplitude can be adjusted continuously in the frequency range from 0.67-0.79 THz by tuning the tilt angle of the incident wave. Our findings will be of great potential in polarization control applications such as asymmetric transmission, optical isolation, and on-chip chiral manipulation.

Coherent Perfect Diffraction in Metagratings.

Metasurfaces are 2D engineered structures with subwavelength granularity, offering a wide range of opportunities to tailor the impinging wavefront. However, fundamental limitations on their efficiency in wave transformation, associated with their deeply subwavelength thickness, challenge their implementation in practical application scenarios. Here, it is shown how the coherent control of metagratings through multiple wave excitations can provide new opportunities to achieve highly reconfigurable broadband metasurfaces with large diffraction efficiency, beyond the limitations of conventional approaches. Remarkably, energy distribution between the 0th and higher diffraction orders can be continuously tuned by changing the relative phase difference between two excitation waves, enabling coherent control, with added benefits of enhanced efficiency and bandwidth. This concept is demonstrated for a thin electric metagrating operating at terahertz frequencies, showing that coherent control can overcome several of the limitations of single-layer ultrathin metastructures, and extend their feasibility in various practical scenarios.

Ultra-broadband microwave metamaterial absorber with tetramethylurea inclusion.

The absorption region of a water-based absorber was expanded by introducing tetramethylurea (TMU) into the inclusion, whose dielectric properties are tunable through the concentration of TMU. The dielectric spectroscopy of a TMU/water mixture was deconstructed using a Debye model. We designed a four-layer ultra-broadband microwave absorber with a supernatant micro-structure. Simulation and experiment results indicate that the absorber can achieve 90% perfect absorption, covering a broad frequency range of 4-40 GHz. The concentration dependence of the absorber was also studied experimentally and numerically. The concentration control provides a more practical and large frequency-region modulation of perfect absorption.

Temperature-Controlled Asymmetric Transmission of Electromagnetic Waves.

Chiral materials can exhibit different levels of transmission for opposite propagation directions of the same electromagnetic wave. Here we demonstrate thermal switching of asymmetric transmission of linearly polarized terahertz waves. The effect is observed in a terahertz metamaterial containing 3D-chiral metallic inclusions and achiral vanadium dioxide inclusions. The chiral structure exhibits pronounced asymmetric transmission at room temperature when vanadium dioxide is in its insulator phase. As the metamaterial is heated, the insulator-to-metal phase transition of vanadium dioxide effectively renders the structure achiral and the transmission asymmetry vanishes. We demonstrate the effect numerically and experimentally, describe it analytically and explain the underlying physical mechanism based on simulated surface current distributions. Potential applications include directionally asymmetric active devices as well as intensity and polarization modulators for electromagnetic waves.

Terahertz electric field modulated mode coupling in graphene-metal hybrid metamaterials.

Taking advantage of the tunable conductivity of graphene under high terahertz (THz) electric field, a graphene-metal hybrid metamaterial consisting of an array of three adjoined orthogonally oriented split-ring resonators (SRRs) is proposed and experimentally demonstrated to show a maximum modulation depth of 23% in transmission when the THz peak field reaches 305 kV/cm. The transmission of the sample is dominated by the antisymmetric and symmetric resonant modes originating from the strong magneto-inductive and conductive coupling among the three SRRs, respectively. Numerical simulations and model calculations based on a coupled oscillator theory were performed to explain the modulation process. It is found that the graphene coating impairs the resonances by increasing the damping of the modes and decreasing the coupling between the SRRs whereas the strong THz field restores the resonances by decreasing the conductivity of graphene.