[Effects of Biochar Input on Changes of Available Nutrient Elements in Riparian Soils with Different Landuse Types].

Biochar, as a new environmentally friendly material, has been used to improve soil quality and for pollution remediation. Biochar input has a significant impact on available nutrients in the soil. Based on the different land use types (forestland, grassland, cultivated land, and barren land) in the riparian zone of Taihu Lake, the effects of biochar application on the available content of nutrients in different land use types of soil were compared, and the dynamics of nutrient change was also discussed. Results show that the addition of biochar can significantly affect the available nutrient content in riparian soil, however the influential degrees for carbon, nitrogen, and phosphorus were different. After the input of biochar, dissolved organic carbon in riparian soils showed a clear downward trend, while the available nitrogen increased slightly, and the available phosphorus increased significantly. For woodland, grassland, arable land and wasteland soils, the contents of dissolved organic carbon decreased by 33.3%, 27.4%, 29.5%, and 51.4%, while the contents of available nitrogen increased by 10.8%, 18.2%, 16.4%, and 15.2%, and the contents of available phosphorus increased by 40.0%, 50.2%, 34.0%, and 43.6%, respectively. Compared with the concentrations between the control group soil (CK) and the biochar additive group soil (BC), the concentrations of dissolved organic carbon and available phosphorus exhibited large differences between the two groups regarding available nitrogen concentrations. Among the four types of riparian soils, the effects of biochar on the availability of different nutrients were different.

Effects of soil amendments on cadmium transfer along the lettuce-snail food chain: Influence of chemical speciation.

Cadmium (Cd) trophic transfer along the soil-lettuce-snail food chain was investigated using the root bags-based pot experiments. Two amendments (corn straw biochar and micro-hydroxyapatite (µHAP)) were investigated on Cd (0, 2.5, and 5 mg/kg soil) availability in soils, chemical distribution in plant cells and accumulation in snails. After 60 days, both the CaCl2 extractable Cd in rhizosphere soil (CdCaCl2,rhizo) and Cd accumulation in lettuce decreased with amendments addition. Biochar had a great capacity to reduce both Cd contents and toxicity-sensitive associated Cd (CdFi+Fii) percentages in lettuce roots at 2.5 mg/kg Cd contaminated soil; while µHAP generates a higher reduction in both Cd contents and chain transfer associated Cd (CdFi+Fii+Fiii) percentages in lettuce shoots at 5 mg/kg Cd contaminated soil. Linear regression showed that both contents of root CdFi+Fii and shoot CdFi+Fii+Fiii are better correlated with the CdCaCl2,rhizo (R2 > 0.70, p < 0.01). After 15 days feeding, almost 90% content of Cd accumulated in snail viscera. µHAP had a higher reduction in snail soft tissues Cd accumulation than biochar. Distributions of Cd in snail tissues are significantly correlated with CdFi+Fii+Fiii in shoots (viscera R2 = 0.835; soft tissue R2 = 0.771). Established quantitative relationships could be used to predict the bioavailability and transfer of Cd in terrestrial food chain in the presence of amendments.

[Chemical structure of fructosan from Condonopsis pilosula].

OBJECTIVE: To study the polysaccharide of Condonopsis pilosula. METHOD: The polysaccharide, CPP-1, was purified by DE-52 cellulose and Sephadex G-200 gel column chromatography. Purity and molecular weight of the polysaccharide were determined by gel permeation chromatography. Methylation analysis, periodate oxidation and degradation, IR, 1H-NMR and 13C-NMR methods were adopted to elucidate the chemical structure. RESULT: The molecular weight of CPP-1 was estimated to be 7.5 x 10(4), and the structure of CPP-1 was a beta-(2 --> 1) linked beta-D-fructosan. CONCLUSION: CPP-1 was a neutral homosaccharide.

[Chemical constituents of Notoseris rhombiformis].

AIM: To investigate the chemical constituents from the whole plant of the endemic plant Notoseris rhombiformis Shih. METHODS: Column chromatography was used for separation and purification, while spectral analysis was used for structure elucidation. RESULTS: Eight compounds were isolated from the whole plant of this Chinese endemic plant and their structures were elucidated as notoserolide A (1), notoserolide D (2), austricin (3), jacquilenin (4), 3 beta, 14-dihydroxy-11 beta, 13-dihydrocostunolide (5), p-hydroxyphenylacetic acid (6), luteolin-7-O-beta-D-glucopyranoside (7) and daucosterol (8), respectively. CONCLUSION: All compounds were isolated from this plant for the first time. Among them, 2 is a new compound.

[Application of beta-cyclodextrin inclusion technique in new dosage form of angelica sinensis essential oil].

OBJECTIVE: To make a solid form of Angelica Sinensis essential oil by preparing its inclusion compound with beta-cyclodextrin and evaluate the inclusion rate, dissolution rate and liberating rate of this complex. METHOD: GC-MS, X-ray diffraction and thin-layer chromatography were applied to characterize the essential oil and the inclusion compound. RESULT: The inclusion compound was shown to form a new phase by X-ray diffraction analysis. GC-MS and TLC check-up corroborated the composition of the free oil and the inclusion oil remaining the same. CONCLUSION: The results showed Angelica Sinensis essential oil was more stable with beta-cyclodextrin inclusion. The preparation of this inclusion compound has advantages in limited amount, long time effect, easily preserved and convenient administration as a new dosage form.