ABSTRACT
Infrared electrochromic devices (IR-ECDs) are pivotal for dynamic thermal regulation. However, the quest for all-solid-state IR-ECDs with high stability and a broadly tunable range of emissivity remains a challenge. This study presents the development of an all-solid-state infrared electrochromic device (IR-ECD) with the structure of ITO/HxWO3/Ta2O5/Pd/Mg3Ni based on the hydrogen-induced metal-insulator transition of Mg-Ni alloy films. The emissivity modulation is improved by film stack optimization, with changes of 0.32 and 0.47 in the 3-5 and 7.5-14 µm bands, respectively. The introduction of an ultrathin Ti isolation layer between the catalytic and electrolyte layers enhances the cyclic stability. Our findings offer a novel strategy for the design and fabrication of all-solid-state IR electrochromic devices and highlight the potential of Mg-Ni alloy-based all-solid-state IR-ECDs in advanced energy and information fields.
ABSTRACT
Dynamic infrared emissivity regulators, which can efficiently modulate infrared radiation beyond vision, have emerged as an attractive technology in the energy and information fields. The realization of the independent modulation of visible and infrared spectra is a challenging and important task for the application of dynamic infrared emissivity regulators in the fields of smart thermal management and multispectral camouflage. Here, we demonstrate an electrically controlled infrared emissivity regulator that can achieve independent modulation of the infrared emissivity while maintaining a high visible transparency (84.7% at 400-760 nm). The regulators show high degree of emissivity regulation (0.51 at 3-5 µm, 0.41 at 7.5-13 µm), fast response ( < 600 ms), and long cycle life ( > 104 cycles). The infrared emissivity regulation is attributed to the modification of the carrier concentration in the surface depletion layer of aluminum-doped zinc oxide nanocrystals. This transparent infrared emissivity regulator provides opportunities for applications such as on-demand smart thermal management, multispectral displays, and adaptive camouflage.
