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J Am Chem Soc ; 133(50): 20120-2, 2011 Dec 21.
Article in English | MEDLINE | ID: mdl-22103884

ABSTRACT

A water-soluble porphyrinato ytterbium complex linked with rhodamine B (Yb-2) showed mitochondria-specific subcellular localization and strong two-photon-induced NIR emissions (λ(em) = 650 nm, porphyrinate ligand π → π* transition; λ(em) = 1060 nm, Yb(III) (5)F(5/2) → (5)F(7/2) transitions; σ(2) = 375 GM in DMSO) with an impressive Yb(III) NIR emission quantum yield (1% at λ(ex) = 340 nm; 2.5% at λ(ex) = 430 nm) in aqueous solution.


Subject(s)
Mitochondria/chemistry , Spectroscopy, Near-Infrared , Water/chemistry , Ytterbium/chemistry , Solubility
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