Bioinspired functional SLIPSs and wettability gradient surfaces and their synergistic cooperation and opportunities for enhanced condensate and fluid transport.

Bioinspired smart functional surfaces have received increasing attention in recent years owed to their tunable wettability and enhanced droplet transport suggesting them as excellent candidates for industrial and nanotechnology-related applications. More specifically, bioinspired slippery lubricant infused porous surfaces (SLIPSs) have been proposed for their low adhesion enabling continuous dropwise condensation (DWC) even of low-surface tension fluids. In addition, functional surfaces with chemical and/or structural wettability gradients have also been exploited empowering spontaneous droplet transport in a controlled manner. Current research has focused on the better understanding of the mechanisms and intimate interactions taking place between liquid droplets and functional surfaces or on the forces imposed by differences in surface wettability and/or by Laplace pressure owed to chemical or structural gradients. Nonetheless, less attention has been paid to the synergistic cooperation of efficiently driving droplet transport via chemical and/or structural patterns/gradients on a low surface energy/adhesion background imposed by SLIPSs, with the consequent promising potential for microfluidics and condensation heat transfer applications amongst others. This review provides a detailed and timely overview and summary on recent advances and developments on bioinspired SLIPSs and on wettability gradient surfaces with focus on their synergistic cooperation for condensation and fluid transport related applications. Firstly, the fundamental theory and mechanisms governing complex droplet transport on homogeneous, on wettability gradient surfaces and on inclined SLIPSs are introduced. Secondly, recent advances on the fabrication and characterization of SLIPSs and functional surfaces are presented. Then, the condensation performance on such functional surfaces comprising chemical or structural wettability gradients is reviewed and their applications on condensation heat transfer are summarized. Last a summary outlook highlighting the opportunities and challenges on the synergistic cooperation of SLIPSs and wettability gradient surfaces for heat transfer as well as future perspective in modern applications are presented.

Numerical study on the desorption processes of oil droplets inside oil-contaminated sand under cavitation micro-jets.

The removal of the adsorbed oil droplet is critical to deoiling treatment of oil-bearing solid waste. Ultrasonic cavitation is regarded as an extremely useful method to assist the oil droplets desorption in the deoiling treatment. In this paper, the effects of cavitation micro-jets on the oil droplets desorption were studied. The adsorbed states of oil droplets in the oil-contaminated sand were investigated using a microscope. Three representative absorbed states of the oil droplets can be summarized as: (1) the individual oil droplet adsorbed on the particle surface (2) the clustered oil droplets adsorbed on the particle surface; (3) the oil droplet adsorbed in a gap between particles. The micro-jet generation during the bubble collapse near a rigid wall under different acoustic pressure amplitudes at an ultrasonic frequency of 20 kHz was investigated numerically. The desorption processes of the oil droplets at the three representative absorbed states under micro-jets were also simulated subsequently. The results showed that the acoustic pressure has a great influence on the velocity of micro-jet, and the initial diameter of cavitation bubbles is significant for the cross-sectional area of micro-jets. The wall jet caused by a micro-jet impacting on the solid wall is the most important factor for the removal of the absorbed oil droplets. The oil droplet is broken by the jet impinging, and then it breaks away from the solid wall due to the shear force generated by the wall jet. In addition to a higher sound pressure, the cavitation bubble at a larger initial diameter is more important for the desorption of the clustered oil droplets. Conversely, the micro-jet generated by the cavitation bubble at a smaller initial diameter (0.1 mm) is more appropriate for the desorption of the oil droplet in a narrow or sharp-angled gap.

Changes in pore size distribution inside sludge under various ultrasonic conditions.

The pore size distribution is quite significant for determining the transport capacity of heat and moisture in sludge during the drying process. It is crucial to investigate the transformation of the pore size in sludge under sonication. In this paper, the microstructures of pores inside sludge before and after ultrasonic treatment with various ultrasonic conditions were observed using a microscope. Fractal geometry and image analysis were combined to quantitatively identify the evolution of pore size in sludge undergoing various acoustic energy densities and treatment times. The surface fractal dimension (df) was applied to characterize the pore size distribution of sludge. The results confirmed that sonication has a positive influence on the characteristics of pore structure inside the sludge and that the average pore size increases with increasing ultrasonic energy level, as determined by both acoustic energy density and treatment time. The df appropriately characterizes and quantifies the evolution of the pore size distribution of sludge under various ultrasonic conditions. This work is quite valuable for further investigating and evaluating moisture removal in the sludge drying process assisted by ultrasonic treatment.