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1.
Chem Commun (Camb) ; (20): 2929-31, 2009 May 28.
Article in English | MEDLINE | ID: mdl-19436913

ABSTRACT

Monodisperse uniform zirconium-titanium mixed oxide microspheres (approximately 3 microm) with different zirconium/titanium ratios are easily synthesized (using Zr(acac)(4) and Ti(OBu)(4) as precursors) by a sol-gel method and have been characterized for their enrichment of phosphopeptides from standard protein alpha-casein.


Subject(s)
Microspheres , Phosphopeptides/metabolism , Titanium/chemistry , Zirconium/chemistry , Amino Acid Sequence , Caseins/chemistry , Caseins/metabolism , Molecular Sequence Data , Phase Transition , Phosphopeptides/chemistry , Porosity , Protein Binding , Surface Properties , Titanium/metabolism , Zirconium/metabolism
2.
Chem Commun (Camb) ; (9): 1085-7, 2009 Mar 07.
Article in English | MEDLINE | ID: mdl-19225644

ABSTRACT

Monodispersed mesoporous silica spheres (MMSS) with periodical large-pore size (up to 200 A) and uniform particle size (1-1.7 mum) have successfully been synthesized by utilizing a new kind of surfactant, and they also demonstrated great potential application in HPLC.


Subject(s)
Chromatography, High Pressure Liquid , Silicon Dioxide/chemistry , Microscopy, Electron, Scanning , Particle Size , Porosity , Silicon Dioxide/chemical synthesis , Surface-Active Agents/chemistry , Temperature
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