1.
RSC Adv
; 14(21): 14703, 2024 May 02.
Article
in English
| MEDLINE
| ID: mdl-38716107
ABSTRACT
[This corrects the article DOI: 10.1039/D4RA02616K.].
2.
RSC Adv
; 14(18): 12883-12887, 2024 Apr 16.
Article
in English
| MEDLINE
| ID: mdl-38650692
ABSTRACT
A novel method was developed for synthesizing γ-alkyl ketones via nickel-catalyzed cross-electrophile coupling of cyclopropyl ketones and non-activated primary alkyl chlorides. High reactivity and selectivity can be achieved with sodium iodide as a crucial cocatalyst that generates a low concentration of alkyl iodide via halide exchange, thus avoiding the formation of alkyl dimers. This reaction possessed excellent regioselectivity and high step economy circumventing in situ or pregenerated organometallics.