Mitigating life-cycle environmental impacts and increasing net ecosystem economic benefits via optimized fertilization combined with lime in pomelo production in Southeast China.

Excessive fertilization is acknowledged as a significant driver of heightened environmental pollution and soil acidification in agricultural production. Combining fertilizer optimization with soil acidity amendment can effectively achieve sustainable crop production in China, especially in Southeast China. However, there is a lack of long-term studies assessing the environmental and economic sustainability of combining fertilizer optimization with soil acidity amendment strategies, especially in fruit production. A four-year field experiment was conducted to explore pomelo yield, fruit quality, and environmental and economic performance in three treatments, e.g., local farmer practices (FP), optimized NPK fertilizer application (OPT), and OPT with lime (OPT+L). The results showed that the OPT+L treatment exhibited the highest pomelo yield and fruit quality among the three treatments. The OPT treatment had the lowest net greenhouse gas (GHG) emissions among the three treatments, which were 90.1 % and 42.6 % lower than those in FP and OPT+L, respectively. It is essential to note that GHG emissions associated with lime production constitute 40.7 % of the total emissions from fertilizer production. The OPT+L treatment reduced reactive nitrogen (Nr) emissions and phosphorus (P) losses, compared to FP and OPT. Moreover, the OPT+L treatment increased the net ecosystem economic benefit by 220.3 % and 20.3 % compared with the FP and OPT treatments, respectively. Overall, the OPT and OPT+L treatments underscore the potential to achieve environmentally friendly and economically sustainable pomelo production. Our study provides science-based evidence to achieve better environmental and economic performance in pomelo production through optimized NPK fertilization and alleviating soil acidification by lime.

Comparatively Evolution and Expression Analysis of GRF Transcription Factor Genes in Seven Plant Species.

Growth regulatory factors (GRF) are plant-specific transcription factors that play pivotal roles in growth and various abiotic stresses regulation. However, adaptive evolution of GRF gene family in land plants are still being elucidated. Here, we performed the evolutionary and expression analysis of GRF gene family from seven representative species. Extensive phylogenetic analyses and gene structure analysis revealed that the number of genes, QLQ domain and WRC domain identified in higher plants was significantly greater than those identified in lower plants. Besides, dispersed duplication and WGD/segmental duplication effectively promoted expansion of the GRF gene family. The expression patterns of GRF gene family and target genes were found in multiple floral organs and abundant in actively growing tissues. They were also found to be particularly expressed in response to various abiotic stresses, with stress-related elements in promoters, implying potential roles in floral development and abiotic stress. Our analysis in GRF gene family interaction network indicated the similar results that GRFs resist to abiotic stresses with the cooperation of other transcription factors like GIFs. This study provides insights into evolution in the GRF gene family, together with expression patterns valuable for future functional researches of plant abiotic stress biology.

Biomimetic Gradient Hydrogel Actuators with Ultrafast Thermo-Responsiveness and High Strength.

Most current hydrogel actuators suffer from either poor mechanical properties or limited responsiveness. Also, the widely used thermo-responsive poly-(N-isopropylacrylamide) (PNIPAM) homopolymer hydrogels have a slow response rate. Thus, it remains a challenge to fabricate thermo-responsive hydrogel actuators with both excellent mechanical and responsive properties. Herein, ultrafast thermo-responsive VSNPs-P(NIPAM-co-AA) hydrogels containing multivalent vinyl functionalized silica nanoparticles (VSNPs) are fabricated. The ultrafast thermo-responsiveness is due to the mobile polymer chains grafted from the surfaces of the VSNPs, which can facilitate hydrophobic aggregation, inducing the phase transition and generating water transport channels for quick water expulsion. In addition, the copolymerization of NIPAM with acrylic acid (AA) decreases the transition temperature of the thermo-responsive PNIPAM-based hydrogels, contributing to ultrafast thermo-responsive shrinking behavior with a large volume change of as high as 72.5%. Moreover, inspired by nature, intelligent hydrogel actuators with gradient structure can be facilely prepared through self-healing between the ultrafast thermo-responsive VSNPs-P(NIPAM-co-AA) hydrogel layers and high-strength VSNPs-PAA-Fe3+ multibond network (MBN) hydrogel layers. The obtained well-integrated gradient hydrogel actuators show ultrafast thermo-responsive performance within only 9 s in 60 °C water, as well as high strength, and can be used for more practical applications as intelligent soft actuators or artificial robots.

Reduction of PVA Aerogel Flammability by Incorporation of an Alkaline Catalyst.

Sodium hydroxide was used as a base catalyst to reduce the flammability of poly(vinyl alcohol) (PVA) aerogels. The base-modified aerogels exhibited significantly enhanced compressive moduli, likely resulting in decreased gallery spacing and increased numbers of "struts" in their structures. The onset of decomposition temperature decreased for the PVA aerogels in the presence of the base, which appears to hinder the polymer pyrolysis process, leading instead to the facile formation of dense char. Cone calorimetry testing showed a dramatic decrease in heat release when the base was added. The results indicate that an unexpected base-catalyzed dehydration occurs at fire temperatures, which is the opposite of the chemistry normally observed under typical synthesis conditions.

Sustainable, Low Flammability, Mechanically-Strong Poly(vinyl alcohol) Aerogels.

Poly(vinyl alcohol) (PVA), tannic acid (TA) and sodium hydroxide (NaOH) were used to prepare low-flammability, mechanically-strong aerogels via an environmentally-friendly freeze-drying method. Because of the strong interaction between TA and PVA through hydrogen bonds, PVA/TA/NaOH aerogels exhibited compressive moduli as high as 12.7 MPa, 20 times that of the control PVA aerogel. The microstructure of the aerogels in this study showed that the addition of NaOH disrupted the typical "card of house" aerogel structure, while the samples with TA showed a stereoscopic uniform structure. The thermal stabilities of aerogels were tested by thermogravimetric analysis, showing both a decrease on the onset of decomposition temperature, and a reduction in decomposition rate after initial char formation. The peak heat release rate and total heat release, as measured by cone calorimetry, dropped by 69% and 54%, respectively, after adding TA and NaOH.