ABSTRACT
A cavity-enhanced absorption spectrometer was used to saturate several lines of ammonia in the 1510 nm - 1560 nm region. Analysis of power broadening of the saturated absorption feature for one of the ammonia lines yielded a dipole moment value comparable to that of the lines in the nu(1)+nu(3) band in acetylene. Highly reproducible frequency measurements of four ammonia line centres were carried out using a frequency comb generated by a mode-locked Cr(4+):YAG laser. These results demonstrate the possible application of ammonia saturated absorption lines for frequency metrology and calibration in a spectral region lacking strong absorbers. To our knowledge, this is the first frequency measurement of saturated absorption lines in ammonia at near infrared frequencies and the first reported observation of saturated absorption lines in the nu(1)+2nu(4) band.
Subject(s)
Ammonia/analysis , Ammonia/chemistry , Lasers , Spectrum Analysis/instrumentation , Light , Scattering, RadiationABSTRACT
A cavity stabilized, SESAM mode-locked Cr4+:YAG laser capable of generating sub-100 fs pulses has been developed. Locking the 130-MHz pulse repetition frequency to that of a hydrogen maser-referenced frequency synthesizer provides a 30-nm wide frequency comb for the 1530-nm wavelength region. In conjunction with a pair of acetylene stabilized, external cavity diode lasers, this laser provides a high precision measurement tool for the determination of acetylene transition frequencies.
