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1.
Sci Total Environ ; 844: 157069, 2022 Oct 20.
Article in English | MEDLINE | ID: mdl-35780873

ABSTRACT

The utilization of ethanol as a component of motor gasolines is an extremely effective way to increase the detonation resistance and environmental properties. In Russia, despite the existing prerequisites for the development of bioethanol industry, the real production of bioethanol is not executed, which is associated with its high price. One of the promising ways of leveling this drawback is the utilization of water-cut waste from its production, involving ethyl alcohol impurity concentrate (EAIC) instead of pure ethanol. This is a mixture of head and bottoms fractions obtained in the process of ethyl alcohol purification by distillation. This research paper investigates the impact of the nature of hydrocarbon fraction blended with ethyl alcohol impurity concentrate on the final characterization of E85 fuel and, in particular, on its phase stability and Reid vapor pressure. Physicochemical characteristics of the developed fuel composition were studied. The results indicated that none of the possible classes of hydrocarbons could effectively solve the problems of phase stability and volatility of E85 fuel. Additionally, methyl tert-butyl ether (MTBE) was the only promising component. The composition, consisting of 70 % ethyl alcohol impurity concentrate and 30 % methyl tertiary butyl ether, met the requirements of American society for testing and materials (ASTM 5798) in almost all respects. A significant discrepancy is observed only in the water content, which is compensated by the great phase stability of the composition at low temperatures. In addition, this fuel composition is characterized by great potential competitiveness in Russian conditions and without fiscal support, which was proved by preliminary calculations of the cost of E85 fuel.


Subject(s)
Gasoline , Methyl Ethers , Ethanol , Hydrocarbons/analysis , Methyl Ethers/metabolism , Russia , Water
2.
Sci Total Environ ; 802: 149863, 2022 Jan 01.
Article in English | MEDLINE | ID: mdl-34525749

ABSTRACT

The depletion of fuel production and raising ecological issues have paid the progress of biofuels in the entire world. Among different biofuels is introducing renewable fuel additives as prospective beneficial blendstocks towards fulfilling systematic, low-carbon technologies internal combustion engines. This research article proposes a new approach to formulate a Fuzzy modeling for examining various promising alternative renewable oxygenated compounds, including ethanol, isopropanol, MTBE, and 2-methyl furan into heavy hydrocracked gasoline a base fuel. No previous study has utilized Fuzzy modeling in formulation of producing high octane fuel based on renewable additives compounds. The effect of selected additives was investigated on the antiknock characteristics. The results reported that the quality and quantity of heavy hydrocracked naphtha have been reinforced, using low carbon oxygenates. Besides, the acquired results provided the possibility to determine the optimum range of selected renewable oxygenates percentages of 30-50% wt. The calculated data of Fuzzy modeling were verified with experimental results. It illustrated that predicted environmental gasoline yields agreed well with experimental results. Finally, low carbon liquid fuel could contribute to produce high quality environmental gasoline, improve environmental characteristics, in terms of decreasing greenhouses emissions, and maximize the vehicles technologies.


Subject(s)
Gasoline , Petroleum , Biofuels , Octanes , Prospective Studies , Vehicle Emissions
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