ABSTRACT
Advanced manufacturing technologies for efficient catalytic materials have triggered the rational design of catalysts as well as extensive investigation into preparative methodologies. Herein, we report the preparation of new versatile cellulose acetate/polyurethane (CA/PU) blends for efficient immobilization of CeO2 nanoparticles, the appropriate composition of polymer mixture being chosen after rigorous analysis (SEM, FTIR, optical, mechanical). The band gap energy for hybrid films ranged between 3.02 eV and 2.05 eV, the lowest value being measured for the film with Co-doped CeO2 NPs (B3 film). The best results in photodegradation of methylene blue under visible-light irradiation was attained after 50 min for B3 film (rate constant k = 45.34× 10-3 min-1), while the total mineralization of MB in the same conditions as evaluated by HPLC-ESI MS and TOC analyses was achieved after 90 min. Effect of co-ions (SO42-, Cl- or NO3-) on photocatalytic performance was studied, and scavenger tests were used to identify the active species involved in the photocatalytic mechanism. Also, the photocatalytic efficiency of B3 sample was tested for rhodamine B, metronidazole and 4-nitrophenol degradation. Evaluation of the stability and integrity of hybrid film after 5 catalysis cycles reveal that the photocatalytic potential is retained with no substantial structural changes.
ABSTRACT
Fuel cells are electrochemical, ecologically friendly appliances that transform chemical energy into electricity in a clean, simple, and effective manner. With the advancement of technology in the field of computer science, electronic downsizing, and the ongoing need for mobility, the demand for portable energy sources such as fuel cells has considerably increased. The proton exchange membrane, which is designed to be a good conductor for protons while isolating electrons to move from the anode to the cathode, imprinting them an external circuit, and thus creating electricity, is at the heart of such an energy source. Perfluorosulfonic acid-based (NAFION) membranes, first introduced over 50 years ago, are still the state of the art in the field of fuel cell proton exchange membranes today. However, because of the numerous drawbacks connected with the usage of NAFION membranes, the scientific community has shifted its focus to producing new generation membranes based on natural materials, such as cellulose. Therefore, we believe that a review of the most recent studies on the use of cellulose as a material for proton exchange membranes in fuel cells may be very much appreciated by the scientific community.
Subject(s)
Cellulose , Protons , Fluorocarbon Polymers , ElectricityABSTRACT
The design of high-performance nanocomposites with improved mechanical, thermal or optical properties compared to starting polymers has generated special interest due to their use in a wide range of targeted applications. In the present work, polymer nanocomposites composed of polyurethane elastomers based on polycaprolactone or polycaprolactone/poly(ethylene glycol) soft segments and titanium dioxide (TiO2) nanoparticles as an inorganic filler were prepared and characterized. Initially, the surface of TiO2 nanoparticles was modified with (3-iodopropyl) trimethoxysilane as a coupling agent, and thereafter, the tertiary amine groups from polyurethane hard segments were quaternized with the silane-modified TiO2 nanoparticles in order to ensure covalent binding of the nanoparticles on the polymeric chains. In the preparation of polymer nanocomposites, two quaternization degrees were taken into account (1/1 and 1/0.5 molar ratios), and the resulting nanocomposite coatings were characterized by various methods (Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, contact angle, thermogravimetric analysis, dynamic mechanical thermal analysis). The mechanical parameters of the samples evaluated by tensile testing confirm the elastomeric character of the polyurethanes and of the corresponding composites, indicating the obtaining of highly flexible materials. The absorbance/transmittance measurements of PU/TiO2 thin films in the wavelength range of 200-700 nm show that these partially block UV-A radiation and all UV-B radiation from sunlight and could possibly be used as UV-protective elastomeric coatings.
ABSTRACT
Cellulose has a long history dating back to ancient times in the evolution of humanity. It was a key material for basic needs, especially for the construction of shelters, paper making, which allowed our ancestors to perpetuate the valuable literary, philosophical or artistic works. In modern era, cellulose has acquired new dimensions of knowledge and scientific interest. This increased interest in cellulose is due to the need to exploit the still unknown resources that cellulose provides us, possibly due to the remarkable progress made lately in the field of fine characterization of the structure using sophisticated electron microscopes and other characterization techniques that have recently emerged. The growing demands of modern society in the direction of computerization and technology, have led the general interest to move from the classical writing paper to other types of "papers" that incorporates a high degree of ingenuity and intelligence, the so-called special papers, ranging from sensors, chips, motherboards, papers with a high degree of security, and many others. Among these, paper-based biosensors are of special interest, due to their high selectivity, simplicity, low price, and fast response. In this article we will review the new trends in the immobilization of biomolecules on various cellulose-based supports. In the first part, we will discuss the stages prior to the manufacture of a such support by specific chemical modification of the cellulosic substrate, followed by an overview of the most studied proteins, but also the most commonly used methods in monitoring protein adsorption on cellulosic substrates.
