1.
Dalton Trans
; 45(4): 1349-53, 2016 Jan 28.
Article
in English
| MEDLINE
| ID: mdl-26740231
ABSTRACT
Comproportionation reactions between MnCl2 and KMnO4 in the presence of arsonate or phosphonate ligands promote the cation-assisted assembly of high-nuclearity, wheel-shaped or toroidal {Mn8} () and {Mn24} () complexes; the closely corresponding reaction systems provide insights into the complexation behaviour of homologous phosphonate/arsonate ligand species.