ABSTRACT
Three new heteroleptic Ru complexes, CYC-B22, CYC-B23C, and CYC-B23T, were prepared as sensitizers for coadsorbent-free, panchromatic, and efficient dye-sensitized solar cells. They are simultaneously functionalized with highly conjugated anchoring and ancillary ligands to explore the electronic and steric effects on their photovoltaic characteristics. The coadsorbent-free device based on CYC-B22 achieved the best power conversion efficiency (PCE) of 8.63% and a panchromatic response extending to 850 nm. The two stereoisomers, CYC-B23C and CYC-B23T coordinated with an unsymmetrical anchoring ligand, display similar absorption properties and the same driving forces for electron injection as well as dye regeneration. Nevertheless, the devices show not only the remarkably distinct PCE (6.64% vs 8.38%) but also discernible stability. The molecular simulation for the two stereoisomers adsorbed on TiO2 clarifies the distinguishable distances (16.9 Å vs 19.0 Å) between the sulfur atoms in the NCS ligands and the surface of the TiO2, dominating the charge recombination dynamics and iodine binding and therefore the PCE and stability of the devices. This study on the steric effects caused by the highly conjugated and unsymmetrical anchoring ligand on the adsorption geometry and photovoltaic performance of the dyes paves a new way for advancing the molecular design of polypyridyl metal complex sensitizers.
ABSTRACT
The fluorescence and phosphorescence of 2,2'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)biphenyl shows good spectral matching with the absorption spectra of the MLCT1 and MLCT3 transitions of Ir(ppy)3. The red-shift of the 0-0 band in the phosphorescence at 77 K is due to the intramolecular pi-pi interactions between the oxadiazole side chains. Maximum brightness of 43,000 cd/m2 with an efficiency of 26 cd/A at 200 cd/m2 was achieved when BOBP was used as the host material for Ir(ppy)3 in the PHOLED study. [structure: see text].
Subject(s)
Biphenyl Compounds/chemistry , Luminescent Agents/chemistry , Organic Chemicals/chemistry , Oxadiazoles/chemistry , Biphenyl Compounds/chemical synthesis , Crystallography, X-Ray , Electrochemistry , Electrons , Lighting , Models, Molecular , Molecular Structure , Oxadiazoles/chemical synthesis , Photochemistry , StereoisomerismABSTRACT
We study both numerically and experimentally a specific geometric mode, named VW mode, in an end-pumped Nd:YVO4 laser with a plano-concave cavity near the 1/3-degeneracy. Three theoretical methods are used to analyze the transverse profiles, the operator method [J. Opt. Soc. Am. A 22, 1559 (2005)], the SU(2) wave representation [Phys. Rev. A 69, 053807 (2004)], and the Fox-Li approach. Some differences among them are addressed and clarified. Moreover, the generating conditions for VW mode are found peculiar and its propagation character is demonstrated. By comparing the experimental mode patterns with the three numerical results, we conclude that the field of a geometric mode in the operator method should be extended to include those of the reverse directional trajectories and the SU(2) coherent state representation is found too specific to produce the fringes within some transverse patterns.
ABSTRACT
Dye-doped organic light-emitting diode of ITO/alpha-NPB (70 nm)/Bebq(2)-1 (7 nm)/BCP (5 nm)/Bebq(2) (33 nm)/LiF (1 nm)/Al (150 nm) shows red electroluminescence with the efficiency of 2.9 cd/A at 100 cd/m(2) and maximum brightness of 62000 cd/m(2). The physical organic aspects of the current-induced fluorescent quenching effect are discussed. [structure: see text]
