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1.
Environ Int ; 181: 108289, 2023 Nov.
Article in English | MEDLINE | ID: mdl-37924605

ABSTRACT

In the quest to reconcile public perception of air pollution with scientific measurements, our study introduced a pioneering method involving a gradient boost-regression tree model integrating PM2.5 concentration, visibility, and image-based data. Traditional stationary monitoring often falls short of accurately capturing public air quality perceptions, prompting the need for alternative strategies. Leveraging an extensive dataset of over 20,000 public visibility perception evaluations and over 8,000 stationary images, our models effectively quantify diverse air quality perceptions. The predictive prowess of our models was validated by strong performance metrics for perceived visibility (R = 0.98, RMSE = 0.19), all-day PM2.5 concentrations (R: 0.77-0.78, RMSE: 8.31-9.40), and Central Weather Bureau visibility records (R = 0.82, RMSE = 9.00). Interestingly, image contrast and light intensity hold greater importance than scenery clarity in the visibility perception model. However, clarity is prioritized in PM2.5 and Central Weather Bureau models. Our research also unveiled spatial limitations in stationary monitoring and outlined the variations in predictive image features between near and far stations. Crucially, all models benefit from the characterization of atmospheric light sources through defogging techniques. The image-based insights highlight the disparity between public perception of air pollution and current policy implementation. In other words, policymakers should shift from solely emphasizing the reduction of PM2.5 levels to also incorporating the public's perception of visibility into their strategies. Our findings have broad implications for air quality evaluation, image mining in specific areas, and formulating air quality management strategies that account for public perception.


Subject(s)
Air Pollutants , Air Pollution , Air Pollutants/analysis , Particulate Matter/analysis , Environmental Monitoring/methods , Public Opinion , Air Pollution/analysis
2.
Sci Total Environ ; 860: 160224, 2023 Feb 20.
Article in English | MEDLINE | ID: mdl-36436640

ABSTRACT

Long-term impact tracking of urban water services is an important scientific basis for the sustainable development goals of future foreground systems. This study developed a dynamic life cycle assessment (DLCA) method that considers temporal variation and the resulting impacts to address the challenges of water treatment facilities based on the principles of life cycle assessment (LCA) and system dynamics (SD) models. The model was then demonstrated and validated for a water treatment facility in the Kinmen Islands, Taiwan. The SD model simulates long-term water demand in terms of growth in the domestic, agriculture, livestock, and manufacturing sectors, which provides specific inventory data for LCA calculations, with the aim of showing the impact change for future water treatment scenarios. The results showed that using imported water and reclaimed water reduced Kinmen's reliance on groundwater from 77 % to 43 % and reduced the vulnerability of urban water services. The environmental impact of water treatment plants is determined to be strongly related to the efficiency of water treatment. In the long run, wastewater treatment plants can reduce their impacts with an increase in efficiency (3.7 % impact reduction). Additionally, the development of reclaimed water technology and water savings can reduce the impact by 19 % and 13.7 %, respectively, compared to the implementation of desalination. In terms of energy policy, more profound energy savings were observed when energy saving and structure transformation were simultaneously carried out. On the other hand, desalination poses the most political risk and has energy-associated environmental impacts. The DLCA results from this study showcase the trend of impact variation over time and thus provide valuable insights for future policy-making in mapping out the benefits and priorities of policy promotion.


Subject(s)
Groundwater , Water Purification , Animals , Water Purification/methods , Environment , Public Policy , Life Cycle Stages , Water Supply
3.
Sci Total Environ ; 859(Pt 2): 160201, 2023 Feb 10.
Article in English | MEDLINE | ID: mdl-36395841

ABSTRACT

Urban water problems due to stormwater have been aggravated by the higher frequency of high-intensity precipitation events and the increase of paved surfaces. However, with appropriate stormwater management practices, such as low-impact development (LID), stormwater can provide an additional urban water resources rather than cause damage. This study aims to apply a water footprint to location determination of LID practices in the urban area. The LID planning procedure was demonstrated with the highest population density region in Taipei, Taiwan. In order to improve the spatial resolution of LID allocation, the "first-level dissemination area" with 450 residents was used as a spatial unit. The performance of LID practices was then evaluated with the simulation using the Storm Water Management Model (SWMM). Three LID practices, rainwater harvesting systems, permeable pavements, and bioretention systems, were selected. After the water footprint accounting, ten sites were suggested for LID implementation. The runoff reduction rate reached up to 65 % by rainwater harvesting systems or at least 3 % by permeable pavements. This study provides a simpler and more effective approach to ways of integrating an urban water footprint into LID planning and stormwater management in urban areas.


Subject(s)
Rain , Water Movements , Water , Water Pollution , Computer Simulation
4.
Environ Sci Pollut Res Int ; 30(9): 22211-22221, 2023 Feb.
Article in English | MEDLINE | ID: mdl-36280634

ABSTRACT

Microwave co-pyrolysis of sewage sludge and leucaena wood was conducted to produce biochar as an adsorbent for CO2 capture. Both microwave power level and blending ratio were crucial factors affecting the CO2 adsorption capacity of biochar. At a power level of 150 W, the biochar produced by microwave co-pyrolysis of 25% sewage sludge and 75% leucaena wood possessed the highest CO2 adsorption capacity. When the biochar was produced at 100 W, its CO2 adsorption capacity was higher than predicted. Based on the proximate and elemental compositions of biochar, two equations were obtained to predict CO2 adsorption capacity. The proximate composition of biochar can provide more precise prediction of CO2 adsorption capacity than elemental composition according to the higher R2 value provided. The blending ratio of 50% would be most appropriate to produce the biochar with acceptable reduction in CO2 adsorption capacity and loss of quantity. The pseudo-second-order model would be most suitable for simulating the kinetic of CO2 adsorption. The biochar produced from 1 metric tonne of sewage sludge and leucaena wood can offset carbon tax by 83 US dollars. Based on experimental results and findings, microwave co-pyrolysis should be a feasible technique to produce biochar possessing high CO2 adsorption capacity.


Subject(s)
Carbon , Sewage , Adsorption , Pyrolysis , Microwaves , Kinetics , Carbon Dioxide , Charcoal
5.
J Clean Prod ; 365: 132893, 2022 Sep 10.
Article in English | MEDLINE | ID: mdl-35781986

ABSTRACT

The unprecedented outbreak of COVID-19 significantly improved the atmospheric environment for lockdown-imposed regions; however, scant evidence exists on its impacts on regions without lockdown. A novel research framework is proposed to evaluate the long-term monthly spatiotemporal impact of COVID-19 on Taiwan air quality through different statistical analyses, including geostatistical analysis, change detection analysis and identification of nonattainment pollutant occurrence between the average mean air pollutant concentrations from 2018-2019 and 2020, considering both meteorological and public transportation impacts. Contrary to lockdown-imposed regions, insignificant or worsened air quality conditions were observed at the beginning of COVID-19, but a delayed improvement occurred after April in Taiwan. The annual mean concentrations of PM10, PM2.5, SO2, NO2, CO and O3 in 2020 were reduced by 24%, 18%, 15%, 9.6%, 7.4% and 1.3%, respectively (relative to 2018-2019), and the overall occurrence frequency of nonattainment air pollutants declined by over 30%. Backward stepwise regression models for each air pollutant were successfully constructed utilizing 12 meteorological parameters (R2 > 0.8 except for SO2) to simulate the meteorological normalized business-as-usual concentration. The hybrid single-particle Lagrangian integrated trajectory (HYSPLIT) model simulated the fate of air pollutants (e.g., local emissions or transboundary pollution) for anomalous months. The changes in different public transportation usage volumes (e.g., roadway, railway, air, and waterway) moderately reduced air pollution, particularly CO and NO2. Reduced public transportation use had a more significant impact than meteorology on air quality improvement in Taiwan, highlighting the importance of proper public transportation management for air pollution control and paving a new path for sustainable air quality management even in the absence of a lockdown.

6.
Environ Sci Pollut Res Int ; 29(38): 58222-58230, 2022 Aug.
Article in English | MEDLINE | ID: mdl-35366723

ABSTRACT

There is growing awareness that nature-based solutions (NBS) prevent negative effects and secure ecosystem services. However, the potential of NBS to provide intended benefits has not been rigorously assessed. Water, food, and energy (WFE) are essential for human well-being. This study highlights the importance of NBS in terms of water, food, and energy. A set of on-site NBS that includes permeable pavements, plant microbial fuel cells, bio-filtration basins, and rain gardens is used to determine the contribution of NBS to the environmental and economic development of urban environments. The results of this study show that NBSs benefit an urban environment in terms of water treatment, stormwater retention, food production and energy generation, carbon sequestration, pollination, sedimentation retention, and cultural services dimension. This research highlights an urgent need for the integration of water, food, and energy plans to ensure that NBSs contribute to the environment and for the conservation of ecosystem services.


Subject(s)
Ecosystem , Water Purification , Economic Development , Filtration , Humans , Rain
7.
Environ Res ; 204(Pt D): 112349, 2022 03.
Article in English | MEDLINE | ID: mdl-34774835

ABSTRACT

Traffic-related air pollutants (TRAPs) pose a serious health hazard for residents and commuters in urban areas. In this study, a real-time mobile monitoring system was deployed in Taipei, a typical East Asian city with an overlap of high population density, traffic, and special structures (e.g., viaducts), to capture the on-road TRAPs at different times of the day. In general, black carbon, ultrafine particles (UFPs), CO concentrations, and lung deposition surface area (LDSA) were positively correlated with traffic flow, and for PM2.5, a more independent fluctuating concentration was observed. During rush-hour periods, the mean concentrations of UFPs, PM2.5, and LDSA were 6.12 × 104 ± 3.83 × 104 cm-3, 23 ± 8 µg/m3, and 2.29 × 102 ± 1.20 × 102 µm2/cm3, respectively. Additionally, the UFP number concentration and LDSA were two times higher along the high-traffic commuting route than along the lower traffic route. Pollutants tended to accumulate at sites near viaducts and high buildings and were significantly influenced by vehicle composition. In this study, the ratio of LDSA to total particle surface area concentration was used as an indicator of the degree of particle irregularity, which was directly related to aging during transport.


Subject(s)
Air Pollutants , Air Pollution , Air Pollutants/analysis , Air Pollution/analysis , Environmental Monitoring , Particulate Matter/analysis , Vehicle Emissions/analysis
8.
Sci Total Environ ; 812: 152559, 2022 Mar 15.
Article in English | MEDLINE | ID: mdl-34952076

ABSTRACT

Water-, energy-, and food (WEF) related practices, such as low impact development (LID), residential solar panels, and rooftop urban agriculture, have been applied to improve urban sustainability and resilience under climate change and urbanization. However, most practices require space. This requirement may result in competition for land. In addition, not all newly built practices benefit the environment from the life cycle perspective. Therefore, this study aims to develop a systematic WEF-related practice planning method to improve urban sustainability and resilience in a limited space. The core method is a multi-objective optimization model that considers the performance and environmental impacts of the selected practices. The assessment was conducted in a densely populated area in Taipei, the capital city of Taiwan, to describe the planning processes and demonstrate the feasibility of the methods. In the Taipei case, five goals were defined: the supply of WEF, the sponge city development target, and the greenhouse gas reduction target. The optimal results of the multi-objective optimization model indicated the closeness of the optimal implementation of WEF-related practices to achieving the goals. The results showed that the optimal arrangement of WEF-related practices could provide water supply benefits and was favorable for developing a sponge city. According to the sensitivities, to achieve urban sustainability and resilience, the priorities in order of importance are as follows: establish a rainwater harvesting system for buildings, encourage the implementation of rooftop photovoltaic systems, and improve the materials and processes used solar panel and bioretention cell production. The systematic planning method provides a quantitative assessment and delivers practical cross-sectoral integrated strategies for decision-making.


Subject(s)
Sustainable Growth , Water , Cities , Food , Water Supply
9.
Sci Total Environ ; 773: 145018, 2021 Jun 15.
Article in English | MEDLINE | ID: mdl-33940710

ABSTRACT

Life cycle assessment (LCA) is a widely applied approach used to evaluate the environmental impacts of a product or service across its life cycle stages; however, the impacts of land use on ecosystem services are less addressed in most LCA studies. This study, therefore, aims to improve the LCA model by incorporating a new impact category of land use on ecosystem services at both midpoint and endpoint levels in the existing ReCiPe2016 impact assessment method. The impacts of land use in the LCA model included land occupation and land transformation. The soil quality-based indicator, soil organic carbon (SOC), was adopted to quantify the soil quality change in ecosystem services caused by land use. A site with contaminated soils was adopted to validate the proposed impact assessment approach and to compare the results of various remediation practices. Our results revealed that the characterization factors (CFs) varied with the type of land use intervention, with land occupation of settlements presenting the highest CFs and land occupation of forest presenting the most negative CFs and thus benefitting ecosystem services. These results were well reflected in the case study, while the type of land intervention was the key factor determining the impact level. The results suggested that long-term occupation, high contamination levels, and high material or energy use contributed to relatively higher impacts of land use on ecosystem services. The proposed approach enables the quantification of land use impacts on ecosystem services as expressed in monetary loss or benefit at the endpoint resource level. The impact assessment results indicated that the in situ bioremediation scenario contributed relatively higher impacts ($12,667 USD) than the excavation and thermal treatment scenario ($-37 USD). These monetary assessment results are informative and are expected to be used in the decision-making process towards achieving beneficial environmental outcomes.

10.
Sci Total Environ ; 752: 141954, 2021 Jan 15.
Article in English | MEDLINE | ID: mdl-33207517

ABSTRACT

A city is the place where food, energy, and water consumption happen. This consumption leads to challenges and has a strong impact on natural sources. Although researchers broadly agree on the importance of incorporating the concept of the food, energy, and water nexus into policy strategies and decision-making, the assessment system for how governance methods can improve the provision of these three essential services is relatively blank. To clarify the policy mechanisms and heterogeneity of sustainability issues related to the food, energy and water nexus at the city level, this study develops an indicator system to guide the implementations and optimize urban sustainability. A qualitative approach is employed to form the priority strategies in in four selected cities: Amsterdam, Eindhoven, Taipei, and Tainan. The results show that renewable energy plays an essential role in the food-energy-water nexus. In addition, we also observed that future work should focus on technological innovation. These observations imply that the unique combination of influence factors in food-energy-water sustainability offers a comprehensive outlook of the broad and complex challenges that a city faces due to resource limitations, which can help inform future governance practices. Finally, some policy recommendations are made for highlighting and the activities needed to work. The results of the present evaluation could be used as a tool to strengthen food-energy-water management in the future. They can guide managers to develop possible solutions that ensure resources are applied successfully according to the visions of multiple perspectives and help the relevant ministries to improve future consultation plans.

11.
Chemosphere ; 268: 128783, 2021 Apr.
Article in English | MEDLINE | ID: mdl-33168284

ABSTRACT

Energy recovery from sewage sludge was carried out by using microwave and conventional torrefaction. The microwave torrefaction was carried out by using a laboratory-scale microwave oven that provides single-mode microwave irradiation at 2.45 GHz, and the amount of sewage sludge for each experiment was approximately 20 g. The efficiency of microwave heating can be substantially promoted at higher power level, resulting in higher heating rate and maximum temperature. According to higher energy yield and heating value of torrefied sewage sludge, the optimum power level for bioenergy produced by microwave torrefaction of sewage sludge should be 200 W. Because of lower mass yield and temperature required to obtain the same yield, microwave heating can be more effective than conventional heating for sewage sludge torrefaction. The elemental composition of torrefied sewage sludge at 400 W was similar to that of anthracite, and its low hydrogen and oxygen contents could prevent excessive formation of smoke. Two correlations were obtained to predict the HHV of SS based on proximate and elemental compositions. With the recovery of liquid and gas products as bioenergy, the energy return on investment for microwave torrefaction of sewage sludge can be up to 16.4, much higher than the minimum value required for a sustainable society. Because of lower activation energy but higher pre-exponential factor, microwave heating can be approximately five times faster than conventional heating.


Subject(s)
Heating , Sewage , Kinetics , Microwaves , Temperature
12.
Chemosphere ; 249: 126139, 2020 Jun.
Article in English | MEDLINE | ID: mdl-32045758

ABSTRACT

Heterogeneous Fenton oxidation of trichloroethylene (TCE) catalyzed by sewage sludge biochar was studied. The highest TCE removal efficiency was 83% at pH 3.1, catalyzed by 300 W biochar. The biochars produced at higher microwave power levels provided better catalytic effect, due to higher iron contents and specific surface areas. Reactivity of sewage sludge biochar maintained after several uses, which provides an advantage for using as a permeable reactive barrier to remediate groundwater pollution. Chromium, copper, nickel, lead, and zinc were found in the leachate generated from sewage sludge biochar, and most of the concentrations were lower than the standards for non-drinking water use. Besides, copper, zinc, and iron were found in the reaction solutions of Fenton oxidation. Because of the highest dosage required for Fenton oxidation, the environmental impact caused by 200 W biochar is highest. The environmental impact caused by 300 W biochar is lowest. Among the four endpoint impact categories in the life cycle assessment (LCA), human health is the highest concern, whereas ecosystem quality is the least. According to experimental and LCA results, the optimum microwave power level would be 300 W. The primary impact source is microwave pyrolysis because of high energy usage.


Subject(s)
Charcoal/chemistry , Trichloroethylene/chemistry , Catalysis , Ecosystem , Environmental Pollution , Iron/chemistry , Oxidation-Reduction , Sewage/chemistry
13.
Chemosphere ; 235: 413-422, 2019 Nov.
Article in English | MEDLINE | ID: mdl-31272001

ABSTRACT

This study aims to investigate the feasibility of desalinating secondary effluent from a domestic wastewater treatment plant (DWTP) using membrane capacitive deionization (MCDI) for reclamation purposes. The desalination performance of a MCDI stack with 10 pairs of 20 cm × 20 cm activated carbon electrodes was evaluated in single-pass mode. As evidenced, the MCDI stack outperformed the capacitive deionization stack. The water quality characteristics of the inflows and product water were also analyzed. Our results revealed that MCDI can effectively remove undesired ions such as calcium and nitrate from the DWTP effluent for water reclamation. In particular, the solution conductivity of the product water was observed to be as low as 1.27 µS/cm. Removal of the ions was easily performed by the electrostatic field-assisted deionization process. The use of MCDI for low-salinity wastewater reclamation demonstrated favorable energy performance with a low volumetric energy input and a molar energy input of 0.12 kWh/m3 and 0.03 kWh/mole, respectively; and the energy efficiency of this system is expected to be further improved by energy recovery or incorporation of energy-producing processes. These results are indicative of the benefits of using MCDI as part of the treatment processes for the reclamation of wastewater with low salinity.


Subject(s)
Waste Disposal, Fluid/methods , Wastewater/chemistry , Carbon , Charcoal , Electric Conductivity , Electrodes , Membranes, Artificial , Nitrates , Salinity , Sodium Chloride , Water , Water Purification/methods
14.
Sci Total Environ ; 687: 152-160, 2019 Oct 15.
Article in English | MEDLINE | ID: mdl-31207505

ABSTRACT

Landfills provide the most commonly used waste disposal solution. They are designed to reduce the risk of environmental or public health hazards due to waste disposal, and are used for waste management purposes in many places around the world. Depending on the design of the site and recovery methods, landfill sites can work as a potential reserve of energy and water for society. Landfill biogas is a source of renewable energy, and surface water can be collected in a retention pond. Although researchers broadly agree on the importance of incorporating the concept of the energy and water nexus into policy strategies and decision-making, the lack of studies focused on how governance methods that incorporate energy-water linkages at landfill sites can improve the provision of these two essential services has hindered progress in this direction. This study analyzes the links between water-energy nexus at a restored landfill site in Taipei City, Taiwan. The study tracks leachate and methane production at the site over the time periods when the landfill was actively receiving waste and after its closure and since its restoration. The results of model simulation of leachate yield and methane collection under different conditions show that energy and water production changed considerably during the time span under consideration. We identified an increasing trend of water and energy production in the landfill operation phase and a decreasing trend of water and energy production in the landfill restoration phase. In addition, we also identify a synergy between energy generation and water volume during the operation phase, and show that no trade-offs between energy generation and water volume were observed during any of the phases studied. These observations imply that greater water volumes will always lead to greater energy production, which can help inform future landfill design and governance practices.

15.
Sci Total Environ ; 654: 822-831, 2019 Mar 01.
Article in English | MEDLINE | ID: mdl-30448672

ABSTRACT

Contaminated sediment may pose a serious threat to human health and ecosystems. However, sediment remediation is typically an expensive and time-consuming process. Therefore, an effective decision-making process for the remediation of contaminated sediment is essential for identifying the optimal approach. Since a single assessment for sediment remediation may be insufficient, combining different analytical approaches is highly recommended. The objective of this study was to develop a comprehensive assessment framework based on the concept of green and sustainable remediation that considers various environmental, economic, and social aspects for the management of contaminated sediment. We propose a framework based on human health risk assessment (HHRA) and cost-benefit analysis (CBA) and apply the multicriteria decision analysis (MCDA) technique to implement integrated and sustainable strategies for sediment management. We used the framework to determine the best alternative for managing heavy-metal-contaminated sediment in a river in Northern Taiwan. The results of the pre-remediation HHRA indicated an unacceptably high cancer risk to children, while the CBA revealed that a remediation project was economically feasible. Moreover, the results of the MCDA revealed that a strategy involving in-situ capping with anthracite-based activated carbon would be relatively inexpensive and result in low risk to human health. In addition, this strategy would have a higher environmental impact and greater public acceptance as compared to a method involving the dredging and washing of soil. Thus, in this case study, in-situ capping using anthracite-based activated carbon was identified as the preferable remediation alternative from multiple perspectives. The proposed framework should allow decision-makers to choose the optimal integrated management strategy for similar river sites with contaminated sediment.

16.
Sci Total Environ ; 607-608: 786-794, 2017 Dec 31.
Article in English | MEDLINE | ID: mdl-28711008

ABSTRACT

Water availability, resulting from either a lack of water or poor water quality is a key factor contributing to regional water stress. This study proposes a set of sector-wise characterization factors (CFs), namely consumptive and degradative water stresses, to assess the impact of water withdrawals with a life cycle assessment approach. These CFs consider water availability, water quality, and competition for water between domestic, agricultural and industrial sectors and ecosystem at the watershed level. CFs were applied to a case study of regional water management of industrial water withdrawals in Taiwan to show that both regional or seasonal decrease in water availability contributes to a high consumptive water stress, whereas water scarcity due to degraded water quality not meeting sector standards has little influence on increased degradative water stress. Degradative water stress was observed more in the agricultural sector than in the industrial sector, which implies that the agriculture sector may have water quality concerns. Reducing water intensity and alleviating regional scale water stresses of watersheds are suggested as approaches to decrease the impact of both consumptive and degradative water use. The results from this study may enable a more detailed sector-wise analysis of water stress and influence water resource management policies.

17.
Environ Sci Pollut Res Int ; 24(3): 3163-3171, 2017 Jan.
Article in English | MEDLINE | ID: mdl-27864736

ABSTRACT

The purposes of this study are to develop a healthy commute map indicating cleanest route in Taipei metropolitan area for any given journey and to evaluate the pollutant doses exposed in different commuting modes. In Taiwan, there are more than 13.6 million motorcycles and 7.7 million vehicles among the 23 million people. Exposure to traffic-related air pollutants can thus cause adverse health effects. Moreover, increasing the level of physical activity during commuting and longer distances will result in inhalation of more polluted air. In this study, we utilized air pollution monitoring data (CO, SO2, NO2, PM10, and PM2.5) from Taiwan EPA's air quality monitoring stations in Taipei metropolitan area to estimate each pollutant exposure while commuting by different modes (motorcycling, bicycling, and walking). Spatial interpolation methods such as inverse distance weighting (IDW) were used to estimate each pollutant's distribution in Taipei metropolitan area. Three routes were selected to represent the variety of different daily commuting pathways. The cleanest route choice was based upon Dijkstra's algorithm to find the lowest cumulative pollutant exposure. The IDW interpolated values of CO, SO2, NO2, PM10, and PM2.5 ranged from 0.42-2.2 (ppm), 2.6-4.8 (ppb), 17.8-42.9 (ppb), 32.4-65.6 (µg/m3), and 14.2-38.9 (µg/m3), respectively. To compare with the IDW results, concentration of particulate matter (PM10, PM2.5, and PM1) along the motorcycle route was measured in real time. In conclusion, the results showed that the shortest commuting route for motorcyclists resulted in a much higher cumulative dose (PM2.5 3340.8 µg/m3) than the cleanest route (PM2.5 912.5 µg/m3). The mobile personal monitoring indicated that the motorcyclists inhaled significant high pollutants during commuting as a result of high-concentration exposure and short-duration peaks. The study could effectively present less polluted commuting routes for citizen health benefits.


Subject(s)
Air Pollution , Environmental Exposure , Air Pollutants/analysis , Environmental Monitoring/methods , Humans , Particulate Matter/analysis , Taiwan , Time Factors , Transportation
18.
Bioresour Technol ; 142: 620-4, 2013 Aug.
Article in English | MEDLINE | ID: mdl-23774221

ABSTRACT

Rice straw is an abundant resource for the production of biofuels and bio-based products. How to convert the recalcitrant lignocellulose effectually is a critical issue. The objective of this study was to investigate the products, mechanism, and kinetics of rice straw pyrolysis by using microwave heating. The highest energy densification ratio of solid residues was achieved at the microwave power level of 300 W. The atomic H/C and O/C ratios of solid residues were much lower than those of rice straw. The primary components of gaseous product were CO, H2, CO2, and CH4, whose molecular fractions were 57%, 21%, 14%, and 8%, respectively. The more gaseous product and the less solid residues were obtained at higher microwave power levels, while the liquid production remained the same and showed a maximum of about 50 wt.%. The kinetic parameters of rice straw pyrolysis were increased with increasing microwave power level.


Subject(s)
Microwaves , Oryza , Kinetics
19.
Bioresour Technol ; 131: 166-71, 2013 Mar.
Article in English | MEDLINE | ID: mdl-23347924

ABSTRACT

This study used life cycle assessment software SimaPro 7.2 and impact assessment model IMPACT 2002+ to evaluate the environmental impact and benefits of a biochar cofiring supply chain used for electricity generation. The biochar was assumed to be produced by rice straw torrefaction and the case study was located in Taoyuan County, Taiwan. This supply chain may provide impact reduction benefits in five categories (aquatic ecotoxicity, terrestrial ecotoxicity, land occupation, global warming, and non-renewable energy) but cause higher impacts than coal firing systems in other categories. Damage assessment of cofiring systems indicated that damage to human health was higher while the damage categories of ecosystem quality, climate change, and resources were lower. Carbon reduction could be 4.32 and 4.68metric tons CO2eq/ha/yr at 10% and 20% cofiring ratios, respectively. The improvement of electricity generation efficiency of cofiring systems may be the most important factor for reducing its environmental impact.


Subject(s)
Charcoal/chemistry , Coal/analysis , Conservation of Energy Resources/methods , Environment , Incineration/methods , Models, Chemical , Software , Computer Simulation
20.
Int J Environ Res Public Health ; 9(10): 3724-39, 2012 Oct 17.
Article in English | MEDLINE | ID: mdl-23202770

ABSTRACT

Watersheds are recognized as the most effective management unit for the protection of water resources. For surface water supplies that use water from upstream watersheds, evaluating threats to water quality and implementing a watershed management plan are crucial for the maintenance of drinking water safe for humans. The aim of this article is to establish a risk assessment model that provides basic information for identifying critical pollutants and areas at high risk for degraded water quality. In this study, a quantitative risk model that uses hazard quotients for each water quality parameter was combined with a qualitative risk model that uses the relative risk level of potential pollution events in order to characterize the current condition and potential risk of watersheds providing drinking water. In a case study of Taipei Source Water Area in northern Taiwan, total coliforms and total phosphorus were the top two pollutants of concern. Intensive tea-growing and recreational activities around the riparian zone may contribute the greatest pollution to the watershed. Our risk assessment tool may be enhanced by developing, recording, and updating information on pollution sources in the water supply watersheds. Moreover, management authorities could use the resultant information to create watershed risk management plans.


Subject(s)
Models, Theoretical , Water Pollutants/analysis , Water Pollution/analysis , Water Supply/analysis , Drinking Water , Enterobacteriaceae/isolation & purification , Humans , Nitrogen/analysis , Nitrogen/standards , Phosphorus/analysis , Phosphorus/standards , Risk Assessment , Taiwan , Water Pollutants/standards , Water Pollution/prevention & control , Water Supply/standards
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