Characterization of aerosolized particles in effluents from carbon fibre composites incorporating nanomaterials during simultaneous fire and impact.

This work investigates the aerosols emitted from carbon fibre-reinforced epoxy composites (CFC) incorporating nanomaterials (nanoclays and nanotubes), subjected to simultaneous fire and impact, representing an aeroplane or automotive crash. Simultaneous fire and impact tests were performed using a previously described bespoke testing methodology with the capability to collect particles released from the front/back faces of the impacted composites plus the effluents. In this work the methodology has been further developed by connecting the Dekati Low Pressure Impactor (DLPI) and Mini Particle Sampler (MPS) sampling system in the extraction chimney. The aerosols emitted have been characterized using various devices devoted to the analysis of aerosols. The influence of the nanoadditives in the matrix on the number concentration and the size distribution of airborne particles produced, was studied with a cascade impactor in the 5 nm-10 µm range. The morphology of the separated soot fractions was examined by SEM. The measurement of aerodynamic size of particles that can deposit in human respiratory tract indicate that 75% of the soot and particles released from CFC could deposit in the lungs reaching the bronchi region at a minimum. There was however, a minimal difference between the number particle concentrations or particle-size mass distribution of particles from CFC and CFC containing nanoadditives. Moreover, no fibres were found in the effluents.

Evaluation of nanosilica emission in polydimethylsiloxane composite during incineration.

At the end of their life cycle, it is expected that many industrial silicone components end up in incineration waste plants. Hence, the issue concerning the risks resulting from the generation of fumes (combustion gas and aerosol) has to be addressed. The aim of our work was to investigate the behavior and fate of nanosilicas from filled polydimethylsiloxane nanocomposites burnt under two different scenarios of incineration. Combustion tests have been performed at lab-scale using a particular tubular furnace and a specific cone calorimeter. The collected fumes (particulate matter and gas phase) have been characterized using various techniques. The results show persistent nanosilica particles, newly produced nanosilica particles in the fumes and in the residues, as well as silicon oxycarbide SixOyCz particles which seem to originate from polysiloxane matrix decomposition.

Physical, morphological and chemical modification of Al-based nanofillers in by-products of incinerated nanocomposites and related biological outcome.

The number of products containing nanomaterials is increasing this last ten years. Information and literature about the end-of-life of nanocomposites often remains partial and does not address the overall fate and transformations of nanoparticles that may affect biological responses. This paper underlines that the physico-chemical features of nanoparticles can be modified by the incineration process and the available toxicological data on pristine nanofillers might not be relevant to assess the modified nanoparticles included in soot. Combustion tests have been performed at lab-scale using a cone calorimeter modified to collect fumes (particulate matter and gas phase) and have been characterized using various techniques. Nanocomposites selected were poly(ethylene vinyl acetate) containing Al-based nanoparticles, i.e. boehmites or alumina. Evaluations of in vitro cytotoxicity responses on pristine nanofillers, soot and residual ash, show that safe boehmite nanoparticles, become toxic due to a chemical modification after incineration process.

Characterization of aerosols and fibers emitted from composite materials combustion.

This work investigates the aerosols emitted during combustion of aircraft and naval structural composite materials (epoxy resin/carbon fibers and vinyl ester/glass fibers and carbon nanotubes). Combustion tests were performed at lab-scale using a modified cone calorimeter. The aerosols emitted have been characterized using various metrological devices devoted to the analysis of aerosols. The influence of the nature of polymer matrices, the incorporation of fibers and carbon nanotubes as well as glass reinforcements on the number concentration and the size distribution of airborne particles produced, was studied in the 5 nm-10 µm range. Incorporation of carbon fibers into epoxy resin significantly reduced the total particle number concentration. In addition, the interlaced orientation of carbon fibers limited the particles production compared to the composites with unidirectional one. The carbon nanotubes loading in vinyl ester resin composites influenced the total particles production during the flaming combustion with changes during kinetics emission. Predominant populations of airborne particles generated during combustion of all tested composites were characterized by a PN50 following by PN(100-500).

Behavior and Fate of Halloysite Nanotubes (HNTs) When Incinerating PA6/HNTs Nanocomposite.

Nanoclay-based nanocomposites have been widely studied and produced since the late 1990s, and frequently end up in waste disposal plants. This work investigates the behavior of PA6/HNTs nanocomposites (nylon-6 incorporating halloysite nanotubes) during incineration. Incineration tests were performed at lab-scale using a specific tubular furnace modified in order to control the key incineration parameters within both the combustion and postcombustion zones. The combustion residues and combustion aerosol (particulate matter and gas phase) collected downstream of the incinerator furnace were characterized using various aerosol analysis techniques. Time tracking of the gas and particle-number concentrations revealed two-step char formation during combustion. HNTs transformed into other mineral structures which were found in both the aerosol and the residues. During combustion of the polymer, it appears that HNTs contribute to the formation of a cohesive char layer that protects the residual material.