A New Mechanism of the Selective Photodegradation of Antibiotics in the Catalytic System Containing TiO2 and the Inorganic Cations.

The mechanism of sulfisoxazole (SFF) selective removal by photocatalysis in the presence of titanium (IV) oxide (TiO2) and iron (III) chloride (FeCl3) was explained and the kinetics and degradation pathways of SFF and other antibiotics were compared. The effects of selected inorganic ions, oxygen conditions, pH, sorption processes and formation of coordination compounds on the photocatalytic process in the presence of TiO2 were also determined. The Fe3+ compounds added to the irradiated sulfonamide (SN) solution underwent surface sorption on TiO2 particles and act as acceptors of excited electrons. Most likely, the SFF degradation is also intensified by organic radicals or cation organic radicals. These radicals can be initially generated by reaction with electron holes, hydroxyl radicals and as a result of electron transfer mediated by iron ions and then participate in propagation processes. The high sensitivity of SFF to decomposition caused by organic radicals is associated with the steric effect and the high bond polarity of the amide substituent.

[Evaluation of changes in hemodynamic parameters after the use of electronic nicotine delivery systems among regular cigarette smokers]. / Ocena zmian wybranych parametrów hemodynamicznych po uzyciu elektronicznych inhalatorów nikotyny wsród regularnych palaczy papierosów.

A relatively new device, described by producers as a device to help smokers quit, nicotine inhaler is an electronic (e-cigarette). Its mission is to provide the body with small doses of nicotine behavior "ceremonial" burning product is not tested for efficacy and toxicity The aim of this study was to compare the effects of nicotine absorbed from cigarette conventional and electronic changes in systolic and diastolic blood pressure and heart rate. Because of the potential interaction of carbon monoxide contained in cigarette smoke and nicotine conventional to changes on the parameters is also going to examine changes in the concentration of carboxyhemoglobin after smoking cigarettes and using e-cigarettes. study group consisted of 42 people, including 21 women and 21 men aged from 18 to 62 years who declared daily cigarette smoking. In this study it was found that as a result of cigarette smoking are increasing all the analyzed conventional hemodynamic parameters, these increases probably normally associated with nicotine absorbed by the smoker with the smoke. It was also a clear increase in carboxyhemoglobin, which is associated with a high concentration of carbon monoxide in cigarette smoke. If you use the e-cigarettes tested were observed increases in diastolic blood pressure and pulse, but none of the parameters did not change significantly, indicating that either the use of e-cigarette by the respondents did not supply the body with absorbable nicotine or for the increase in haemodynamic parameters studied did not correspond only nicotine but also other smoke constituents that interact with nicotine to the smoker body as carbon monoxide.

[Exposure to respirable suspended particles in smoking and non-smoking sections of pubs in southern Poland]. / Narazenie na pyl respirabilny w pubach poludniowej Polski z wydzielonymi miejscami dla palacych papierosy i niepalacych.

Particulate matter (PM), including fine particulate matter (PM2.5), is one of the main pollutant which it damages of human health seriously. Tobacco smoke is significant source of PM2.5 in indoor microenvironments. New bill of complete smoking ban in all public places in Poland is currently under consideration in polish parliament. Proposed maximum allowed concentration of PM2.5 for all non-smoking sections is 0.03 mg/m3. Concentrations of tobacco-specific fine particulate matter (PM2.5) were monitored in thirteen pubs located in southern part of Poland during winter season. All examined pubs had two types of sections: smoking and non-smoking. PM2.5 concentrations were monitored during one hour in each section using DustTrak monitor (TSI Inc., USA). The Wilcoxon matched pair test was used to compare pollutant concentrations in smoking vs. non-smoking sections. Average 1-hour PM2.5 concentration in smoking sections was 1.25 +/- 1.85 mg/ m3 and varied from 0.18 do 7.21 mg/ m3. Average 1-hour PM2.5 concentration in non-smoking sections was 0.35 +/- 0.29 mg/m3 and varied from 0.056 to 1.01 mg/m3. The highest temporary PM2.5 concentration of 25.5 mg/m3 was found in a pub located in cellar storey were with volume of 60 m3, 13 smokers and no air-condition. There was little difference in PM2.5 levels between smoking and non-smoking section.