Organic contaminants levels, distribution and risk assessment in Jeddah marine coastal zone sediments.

Herein, various organic contaminants were determined in surface sediments collected from the Jeddah coastal zone, Saudi Arabia, to assess their levels, origin and probable toxic effects on marine organisms. High hydrocarbons concentrations, indicative of an enhanced pollutant burden, were recorded in the Jeddah Lagoon (mean value 4100 mg/kg for total aliphatic hydrocarbons (∑AHC) and 5800 µg/kg for total polycyclic aromatic hydrocarbons (∑PAH)), whereas mean values in Mena Jeddah were 258 mg/kg for ∑AHC and 615 µg/kg for ∑PAH. By using molecular diagnostic ratios/indices and applying Positive Matrix Factorization, petroleum related pollution seems to predominate in Jeddah lagoons, whereas carcinogenic contaminants of pyrolytic origin were dominant in Mena Jedda. Additionally, municipal wastewaters were identified as a major source of pollution in Jeddah lagoons. Comparison of the concentrations of individual PAHs and polychlorinated biphenyls with sediment quality guidelines indicates that, despite their high total values, adverse biological effects are unlikely to occur.

Pollution status determination using trace metals and organic contaminants of the water column in coastal areas of the Red Sea and the Gulf of Aqaba: A baseline assessment.

Herein, we aim to provide a baseline assessment of the pollution status of the water column in coastal areas of Saudi Arabia (Red Sea and the Gulf of Aqaba), using trace metals (Cd, Co, Cr, Cu, Ni, Pb and Zn), total petroleum hydrocarbons (TPHs) and polycyclic aromatic hydrocarbons (PAHs), in seawater samples obtained from 71 sampling stations in June-July 2021. Concerning trace metals, the maximum concentrations for Co, Cu and Ni were detected in Al-Shuqaiq, whereas the highest Pb and Zn concentrations were found in the Jeddah lagoon waters. Elevated concentrations of TPHs and the highest sum of PAHs were recorded in surface waters of Al Lith, Jeddah lagoon and Jeddah Mena. Overall, the concentrations of all trace metals, TPHs and individual PAHs for which environmental standards have been stipulated for the Kingdom of Saudi Arabia fall well below the threshold values.

Imprint and short-term fate of the Agia Zoni II tanker oil spill on the marine ecosystem of Saronikos Gulf.

In this study we investigate the spatial and temporal imprint of the September 2017 Agia Zoni II tanker heavy fuel oil spill on the marine ecosystem of Saronikos Gulf (Greece). Based on the chemical fingerprinting approach, by means of gas chromatography - flame ionization detector, gas chromatography-mass spectrometry and the use of various diagnostic ratios, we characterize changes in the composition of the spilled oil at various sampling sites and evaluate major mechanisms affecting its fate i.e. dissolution/dispersion, evaporation, biodegradation, photo-oxidation and sedimentation during the first six months from the spill. Overall, the main effects of the incident were confined to the coastal zone during the first three months after the spill, where an extended petroleum imprint was recorded in many cases, with the determined concentrations of the total petroleum hydrocarbons and polycyclic aromatic hydrocarbons falling within the highest range of concentrations previously reported for similar oil spill incidents worldwide. In the first three months following the spill the oil was affected by a combination of volatilization, rapid biodegradation and photodegradation, the later playing a role in its early days weathering. Concerning sediments, an imprint related to the incident was recorded in a few cases, being, however, mild in respect to the high chronic petroleum-associated anthropogenic background of the impacted area.