1.
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 12): 486-8, 2014 Dec 01.
Article
in English
| MEDLINE
| ID: mdl-25552973
ABSTRACT
The title salt, [Pd(C3H4N2)4]Cl2, was obtained unexpectedly by the reaction of palladium(II) dichloride with equimolar amounts of 1-chloro-1-nitro-2,2,2-tris-(pyrazol-yl)ethane in methanol solution. The Pd(2+) cation is located on an inversion centre and has a square-planar coordination sphere defined by four N atoms of four neutral pyrazole ligands. The average Pd-N distance is 2.000â (2)â Å. The two chloride anions are not coordinating to Pd(2+). They are connected to the complex cations through N-Hâ¯Cl hydrogen bonds. In addition, C-Hâ¯Cl hydrogen bonds are observed, leading to a three-dimensional linkage of cations and anions.