Fabrication of novel amine-functionalized magnetic silica nanoparticles for toxic metals: kinetic and isotherm modeling.

In this research, an amine-functionalized magnetic silica nanosorbent was prepared using the co-precipitation technique, and this nanosorbent can be effortlessly detached using an external magnetic field. FTIR and SEM analyses identified that the nanosorbent holds extraordinary adsorption characteristics for toxic metals' (copper, cadmium, zinc, and nickel) removal. The adsorption-affecting parameters were optimized, and the thermodynamic studies assessed that the adsorption process seemed to be spontaneous, feasible, and exothermic. The pseudo-first-order and Freundlich models perfectly fit the kinetic and equilibrium data, respectively. Langmuir monolayer capacity of the nanosorbent was analyzed using nonlinear evaluation methods such as 419.9 mg/g for copper, 321.9 mg/g for nickel, 217.3 mg/g for cadmium, and 137.6 mg/g for zinc. The used adsorbent was simply rejuvenated using the 0.2 N HCl solution subsequently with intense agitation. The result of the present research confirms that the produced nanosorbent can be effectively utilized for industrial wastewater management.

Insights of CMNPs in water pollution control.

The various toxic contaminants such as dyes, heavy metals, pesticides, rare-earth elements, and hazardous chemicals are the major threats to all the flora and fauna. Owing to the harmful ill effects caused by the toxic contaminants, it is necessary to eliminate these compounds from the authors' ecosystem. The chitosan magnetic nanomaterials (CMNPs) are one of the superior materials used in the wastewater treatment through various conventional technologies. The chitosan is a natural source obtained from the crustacean shells of crabs, prawns etc. The magnetic nanomaterial prepared by the reinforcement of chitosan is highly effective in the removal of heavy metals, dyes, organic matter, and harmful chemicals. It is used in various technologies such as adsorption, flocculation, immobilisation, photocatalytic technology, and bioremediation. This possesses unique surface and magnetic characteristics, Moreover, it is simple, economically feasible, and eco-friendly material used efficiently in wastewater treatment. This review paper depicts the overview of CMNP in the industrial effluent treatment.

Investigating the prospects of bacterial biosurfactants for metal nanoparticle synthesis - a comprehensive review.

Establishing biological synthesis of nanoparticles is increasing nowadays in the field of nanotechnology. The search for an optimal source with durability, stability, capacity to withstand higher environmental conditions with excellent characteristics is yet to meet. Consequently, there is need to create an eco-friendly strategy for metal nanoparticle synthesis. One approach investigated in this review is the use of biosurfactants to enhance the synthesis biologically. In comparison with the other technologies, biosurfactants are less toxic and exhibit higher properties. This method is different from the conventional practice like physical and chemical methods. Several research studies represented that the biosurfactant influences the production of nanoparticles about 2-50 nm. In this manner, the research towards the biosurfactant has raised. This review also addressed the feasibility of biosurfactant and their benefits in the synthesis of metallic nanoparticles. The findings from this review can recommend a conceivable use of biosurfactant as a source for metal nanoparticle synthesis.

Surface adsorption of poisonous Pb(II) ions from water using chitosan functionalised magnetic nanoparticles.

In this study, chitosan functionalised magnetic nano-particles (CMNP) was synthesised and utilised as an effective adsorbent for the removal of Pb(II) ions from aqueous solution. The experimental studies reveal that adsorbent material has finer adsorption capacity for the removal of heavy metal ions. Parameters affecting the adsorption of Pb(II) ions on CMNP, such as initial Pb(II) ion concentration, contact time, solution pH, adsorbent dosage and temperature were studied. The adsorption equilibrium study showed that present adsorption system followed a Freundlich isotherm model. The experimental kinetic studies on the adsorption of Pb(II) ions exhibited that present adsorption process best obeyed with pseudo-first order kinetics. The maximum monolayer adsorption capacity of CMNP for the removal of Pb(II) ions was found to be 498.6 mg g-1. The characterisation of present adsorbent material was done by FTIR, energy disperse X-ray analysis and vibrating sample magnetometer studies. Thermodynamic parameters such as Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) have declared that the adsorption process was feasible, exothermic and spontaneous in nature. Sticking probability reported that adsorption of Pb(II) ions on CMNP was favourable at lower temperature and sticking capacity of Pb(II) ions was very high.