Nanocellulose-based membranes with pH- and temperature-responsive pore size for selective separation.

Smart gating membranes have drawn much attention due to the controllable pore structure. Herein, a smart gating membrane with dual responsiveness was prepared from bacteria cellulose (BC) grafted with pH- and temperature-responsive polymers. By external stimulation, the average pore size of the membrane can be controlled from 33.75 nm to 144.81 nm, and the pure water flux can be regulated from 342 to 2118 L·m-2·h-1 with remarkable variation in the pH range of 1-11 and temperature range of 20-60 °C. The adjustability of pore size is able to achieve the gradient selective separation of particles and polymers with different sizes. In addition, owing to the underwater superoleophobicity and the nanoscale pore structure, the membrane separation efficiencies of emulsified oils are higher than 99 %. Moreover, the controllable pore size endows the membrane with good self-cleaning performance. This nanocellulose-based smart gating membrane has potential applications in the fields of controllable permeation, selective separation, fluid transport, and drug/chemical controlled release systems.

Fluorescent Eu-MOF@nanocellulose-based nanopaper for rapid and sensitive detection of uranium (â ¥).

Radioactive uranium leaks into natural water bodies mainly in the form of uranyl ions (UO22+), posing ecological and human health risks. Fluorescent europium-based metal-organic frameworks (Eu-MOFs) have been demonstrated to be effective fluorescent sensors for UO22+, but the large size, powder state and poor dispersity limit their further application. In this work, fluorescent Eu-MOFs were in-situ grown on TEMPO-oxidized cellulose nanofibers (TOCNFs), which is the first time that spherical Eu-MOF crystals with sizes below 10 nm were prepared. Fluorescence spectral analysis revealed a nine-fold increase in the fluorescence intensity of TOCNF@Eu-MOF compared to Eu-MOF. The nanocomposites achieved rapid and sensitive fluorescence quenching to UO22+ through the "antenna effect" and unsaturated Lewis basic sites on the ligands binding with UO22+. Moreover, TOCNF@Eu-MOF demonstrated excellent selectivity and anti-interference for UO22+ detection. For the nanopaper-based sensor made from TOCNF@Eu-MOF, the Stern-Volmer quenching constant (KSV) was calculated as 8.21 × 104 M-1, and the lowest limit of detection (LOD) was 6.6 × 10-7 M, significantly lower than the 1.32 × 10-6 M of Eu-MOFs. In addition, the nanopaper exhibited good fluorescence stability and cyclic detection performance, enabling the rapid and convenient detection of UO22+ in the aqueous phase within 30 s by simple dipping.

In situ growth of Ag2S quantum dots on cellulose nanocrystals and their near-infrared bioimaging performance.

Elongated nanoparticles show distinct advantages over spherical nanoparticles in bioimaging because of surface area-to-volume, rate of clearance from the body and elimination mechanism. In this work, we investigated the fluorescence emission properties of the hybrid system by decorating silver sulfide quantum dots (Ag2S QDs) in situ on the surface of cellulose nanocrystal (CNC) with unique rod shape, modifiability and biocompatibility. This water-dispersible fluorescent probe has both absorption and fluorescence in near-infrared (NIR) region. By varying the amount of surface ligands, uniformly dispersed Ag2S QDs with different crystalline states but similar sizes were prepared due to the anchoring effect of CNC. The fluorescence quantum yield of fluorescent probes can be improved up to 109-fold (from 0.04 % to 4.36 %). In addition, the CNC-restricted interparticle spacing of Ag2S QDs (< 10 nm), in combination with the overlap of wide fluorescence emission and ultraviolet absorption, significantly enhanced the 1070 nm emission in the NIR-II region via fluorescence resonance energy transfer (FRET). Further conjugation of these CNC probes with folic acid-polyethylene glycol-amino (FA-PEG-NH2) enables in vitro bioimaging of Hela cells, which are potentially applicable for in vivo cancer detection system. The synthetic strategy provides a new way for one-pot preparation of fluorescent probes with both high NIR-I absorption and NIR-II fluorescence.

A smart gating nanocellulose membrane showing selective separation and self-cleaning performance.

A smart gating membrane based on thermal-sensitive poly (N-isopropyl acrylamide) (PNIPAM)-grafted nanocellulose and carbon nanotube (CNT) was prepared. The presence of PNIPAM shell on cellulose nanofibrils (CNFs) endow the composite membrane with thermal responsiveness. By external stimulation, an increase temperature from 10 °C to 70 °C allows the average pore size of the membrane to be controlled from 28 nm to 110 nm, as well as the water permeance from 440 L·m-2·h-1·bar-1 to 1088 L·m-2·h-1·bar-1. The gating ratio of the membrane can reach 2.47. The photothermal effect of CNT rapidly warms up the membrane to the lowest critical solution temperature in the water, avoiding the constraint that the whole water phase cannot be heated throughout the practical use process. The membrane can precisely control the nanoparticles to concentrate at 25.3 nm, 47.7 nm or 102 nm by adjust the temperature. In addition, the water permeance can be restored to 370 L·m-2·h-1·bar-1 by washing the membrane under light. The smart gating membrane has a wide application in substance multi-stage separation and selective separation, and it can realize self-cleaning.

Nanocellulose-based lightweight porous materials: A review.

Nanocellulose has been widely concerned and applied in recent years. Because of its high aspect ratio, large specific surface area, good modifiability, high mechanical strength, renewability and biodegradability, nanocellulose is particularly suitable as a base for constructing lightweight porous materials. This review summarizes the preparation methods and applications of nanocellulose-based lightweight porous materials including aerogels, cryogels, xerogels, foams and sponges. The preparation of nanocellulose-based lightweight porous materials usually involves gelation and drying processes. The characteristics and influencing factors of three main drying methods including freeze, supercritical and evaporation drying are reviewed. In addition, the mechanism of physical and chemical crosslinking during gelation and the effect on the structure and properties of the porous materials in different drying methods are especially focused on. This contribution also introduces the application of nanocellulose-based lightweight porous materials in the fields of adsorption, biomedicine, energy storage, thermal insulation and sound absorption, flame retardancy and catalysis.

Dispersion Properties of Nanocellulose: A Review.

The development of science and technology brings forward higher and higher requirements for the properties of materials. Nanocellulose, with many fascinating properties including large specific surface area, template structure, good modifiability, biodegradability, and etc., has wide application prospects. The surface properties and interfacial compatibility of nanocellulose are the keys to its application performance. This review mainly summarizes the colloid and surface chemistry of nanocellulose and their effects on the dispersity in various solvents and polymer matrices, and especially focuses on the impact of surface hydrophilicity/hydrophobicity, charge repulsion and steric hindrance on the dispersion properties. Various surface modification methods to improve the dispersion performance of nanocellulose, such as oxidation, etherification, esterification, amidation, graft polymerization, and etc., are summarized. In addition, the application of nanocellulose as the dispersant for Pickering emulsion, carbon nanomaterials, metal nanoparticles and etc. is also introduced. The development trend and potential application of nanocellulose are finally prospected.

Water-dispersible, biocompatible and fluorescent poly(ethylene glycol)-grafted cellulose nanocrystals.

Fluorescent nanoprobe with good water dispersibility was synthesized by the coupling of fluorescent 1,8-naphthalimide dye (NANI) as well as biocompatible poly (ethylene glycol) (PEG) to cellulose nanocrystals (CNC). FTIR, TGA and XPS analysis confirmed the successful covalent conjugation of NANI and PEG. The rod-like morphology of CNC was generally retained after two-step successive grafting of NANI and PEG. The contact angle and transmittance measurements showed that the grafted PEG brushes improve the hydrophilicity of fluorescent CNC probes and their dispersibility in high-concentration NaCl solutions. The fluorescent CNC probe had good biocompatibility and was successfully used for the bioimaging of Hela cells in physiological environment at high salt concentration. Laser confocal microscopy showed that the fluorescent CNC probe can penetrate the cell membrane and disperse uniformly in the cell with good biocompatibility. The fluorescent CNC probe with nanometer size, strong fluorescence emission and high salt-tolerance possess potential application in biomedical field.