Effects of activated carbon characteristics on the electrosorption capacity of titanium dioxide/activated carbon composite electrode materials prepared by a microwave-assisted ionothermal synthesis method.

Titanium dioxide (TiO2)/ activated carbon (AC) composite materials, as capacitive deionization electrodes, were prepared by a two-step microwave-assisted ionothermal synthesis method. The electrosorption capacity of the composite electrodes was studied and the effects of AC characteristics were explored. These effects were investigated by multiple analytical techniques, including X-ray photoelectron spectroscopy, thermogravimetry analysis and electrochemical impedance spectroscopy, etc. The experimental results indicated that the electrosorption capacity of the TiO2/AC composite electrode is dependent on the characteristics of AC including the pore structure and the surface property. An enhancement in electrosorption capacity was observed for the TiO2/AC composite electrode prepared from the AC with higher mesopore content and less hydrophilic surface. This enhancement is due to the deposition of anatase TiO2 with suitable amount of Ti-OH. On the other hand, a decline in electrosorption capacity was observed for the TiO2/AC composite electrode prepared from the AC with higher micropore content and highly hydrophilic surface. High content of hydrogen bond complex formed between the functional group on hydrophilic surface with H2O, which will slow down the TiO2 precursor-H2O reaction. In such situation, the effect of TiO2 becomes unfavorable as the loading amount of TiO2 is less and the micropore can also be blocked.

Effects of insulin replacement on cardiac apoptotic and survival pathways in streptozotocin-induced diabetic rats.

Increased myocyte apoptosis in diabetic hearts has been previously reported. Therefore, the purpose of this study was to evaluate the effects of insulin on cardiac apoptotic, hypertrophic, and survival pathways in streptozotocin (STZ)-induced diabetic rats. Forty-eight male Wistar rats at 8 weeks of age were randomly divided into control group (Control), STZ-induced (65 mg/kg STZ i.v.) Type 1-like diabetic rats (DM), and DM rats with 4 IU insulin replacement (DI) for 4 and 8 weeks, respectively. The levels of protein involved in cardiac apoptotic, hypertrophic, and survival pathways were measured by Western blotting. Cardiac mitochondrial-dependent apoptotic pathways, such as Bad, cytosolic cytochrome c, activated caspase 9 and 3, and calcineurin-nuclear factor activation transcription 3 (NFAT3) hypertrophic pathway in DM were increased compared to Control and attenuated in DI group after 8 weeks whereas those were not found after 4 weeks. Cardiac anti-apoptotic Bcl2 and phosphorylated-Bad were significantly decreased in DM group but not in DI group after 8 weeks. Insulin-like growth factor-I receptor (IGFIR), phosphatidylinositol 3'-kinase (PI3K), and the protein kinase B (Akt) were significantly decreased in DM relative to Control and DI after 8 weeks whereas those were not found after 4 weeks. Insulin replacement not only prevents activation of the cardiac mitochondrial-dependent apoptotic pathway and calcineurin-related NFAT3 hypertrophic pathway in diabetes but it also enhances the cardiac insulin/IGFIR-PI3K-Akt survival pathway, all of which are attenuated with insulin therapeutic duration-dependent manners. The findings may provide possible diabetes-related apoptotic, hypertrophic, and survival pathways for potentially preventing cardiac abnormality in diabetes.

H2 production potential in thermophilic mixed fermentation.

The effect of pH on dark fermentative H(2) production at 55 degrees C was studied using three different inocula namely windrow yard waste compost (G), anaerobic organic waste compost (H) and activated sludge (A) and 2 g/L glucose as substrate. The sequential batch experiments were performed by controlling the pH at 5, 5.5 and 6. The highest molar H(2) yields were found to be 1.7 at pH 5 for G and H and 1.6 at pH 5.5 for A, while severe drops in the subsequent runs were associated with lactate fermentation. At pH 5.5 in G, despite the butyrate formation ceased, lower but more stable H(2) yields of about 1.1 were obtained through acetate-ethanol fermentation. Besides, the clostridial thermopiles prevalent at pH 5 were substituted by Thermoanaerobacterium-related species at pH 5.5 and 6. The findings suggested that for a stable H(2) yield through acetate-butyrate fermentation at 55 degrees C with compost inoculum G or H, the pH has to be controlled between pH 5 and 5.5. This is one of the few papers discussing the effects of pH on H(2) production through thermophilic mixed fermentation of glucose by using three different natural mixed culture inocula.