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1.
Phys Rev Lett ; 90(21): 216105, 2003 May 30.
Article in English | MEDLINE | ID: mdl-12786569

ABSTRACT

Laterally resolved measurements of the quantum size effect (QSE) in electron reflectivity are made with low energy electron microscopy on coherently strained Ag films on a W(110) surface. The evolution of the total film thickness with increasing number of atomic layers is determined accurately by dynamical theory analysis of the QSE features. Combined with a model of layer spacings obtained from first-principles calculations, this provides for a novel approach to determine the buried interface layer spacing, which is inaccessible to other methods.

2.
Chemosphere ; 39(9): 1421-32, 1999 Oct.
Article in English | MEDLINE | ID: mdl-10481244

ABSTRACT

This paper reports the development of optical scanning respirometer for determining the toxicity of chemicals to activated sludge. The respirometer is used to measure the dissolved oxygen concentration by monitoring the luminescence intensity of ruthenium dye immobilized in a polymer film in contact with the wastewater sample. The intensity is related to the extent of oxygen quenching of luminescence. The toxicity of chemicals can be evaluated by measuring the inhibition on respiration rate of microorganism using the scanning respirometer. The IC50 values (concentration of a chemical that exhibits 50% respiration inhibition) of various phenolic chemicals in activated sludge were determined. The performance of this method is compared with other toxicity methods. The experimental results indicate that the reproducibility and sensitivity of this respirometer are reasonably good.


Subject(s)
Environmental Pollutants/toxicity , Phenols/toxicity , Sewage/microbiology , Luminescent Measurements , Oxygen/metabolism , Reproducibility of Results , Ruthenium/chemistry , Sensitivity and Specificity , Toxicity Tests/methods
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