Evaluation of the effectiveness of nonthermal plasma disinfection.

As concern has increased regarding the interaction between efficiency and safety of disinfection, plasma becomes a viable alternative for disinfection in comparison with traditional methods. Dielectric barrier discharge (DBD) is applied to deactivate Bacillus subtilis and Escherichia coli , respectively, and disinfection efficiency is experimentally evaluated in this study. Tests are conducted with different working gases to investigate their effects on disinfection. Results show that Ar plasma diluted with 25% O2 enhances the germicidal effects to5.9 and 6.9 (log reduction) for B. subtilis and E. coli, respectively, and OES results show that active Ar and O species play important roles to weaken cell wall of microbes and further disinfect E. coli and B. subtilis. Analysis of protein and total sugar release indicates that active species such as ozone, NO and Ar* produced by plasma result in hydrolysis of the cell. In the meantime, charged particles produced by plasma would affect the amount of sugar released, resulting in different germicidal effects. Overall, plasma can disinfect microorganisms mainly via the generation of oxidising agents including ozone, NO and UV with a comparatively short treatment period, which is typically less than 5 min.

Photocatalytic removal of trichloroethylene from water with LaFeO3.

Tricholorethylene (TCE) has been recognized as second common organic pollutant found in groundwater in Taiwan. Several advanced oxidation processes (AOPs) have been applied for TCE removal and photocatalytic is one of promising AOP techniques. In this study, LaFeO3 is successfully synthesized via sol-gel method and investigated for its photocatalytic oxidation rate toward TCE in water. Experimental results indicate that 95% removal efficiency of TCE can be achieved in aqueous solution with LaFeO3 (2 g/L) as photocatalyst within 1 h of Xenon lamp illumination. Additionally, the influences of initial TCE concentration, light intensity, photocatalyst loading, and pH value on the TCE removal efficiency are evaluated as well. The highest energy efficiency obtained in this study is 10.8 mg TCE/kWh and the value is higher than those reported in previous studies. Besides, removal mechanisms have been identified and the results indicate that the overall removal efficiency reaches 82%, with adsorption and photolysis accounting for 20% and 39%, respectively.

Photocatalytic oxidation of toluene and isopropanol by LaFeO3/black-TiO2.

Large amount of volatile organic compounds (VOCs) are emitted from industrial, mobile, and domestic sources, causing adverse effects on human health and environment. Among VOCs, toluene and isopropanol (IPA) are commonly used as solvent, soldering flux, and spray paint and their emissions need to be reduced. Several VOCs abatement technologies are available to reduce VOC emission and photocatalytic oxidation of VOC is regarded as a viable technique due to its advantage of utilizing solar energy. TiO2 has been investigated for its oxidation capability toward VOCs because of its good photocatalytic activity. However the utilization is limited to UV due to its wider bandgap; furthermore, its fast recombination rate of electron-hole pair reduces the oxidation rate of VOCs. Black-TiO2 and perovskite-type photocatalyst such as LaFeO3 can be applied to enhance photocatalytic activity due to narrower bandgap and longer electron-hole pair lifetime. In this study, black-TiO2 and LaFeO3 are prepared and investigated for their photocatalytic oxidation rates toward toluene and IPA. Results show that toluene removals achieved with black-TiO2 and LaFeO3 are 89% and 98% while IPA removals are 90% and 94%, respectively. Both photocatalysts show better photocatalytic activity than TiO2 and good absorption capability toward visible light. Graphical abstract.