1.
Angew Chem Int Ed Engl
; 62(52): e202313659, 2023 Dec 21.
Article
in English
| MEDLINE
| ID: mdl-37966018
ABSTRACT
We report the first reductive vinylation of alkyl iodides. The reaction uses a vinyl thianthrenium salt, a palladium catalyst, and an alkyl zinc intermediate formed in situ to trap the Ln PdII (vinyl) complex formed after oxidative addition before it undergoes undesired homocoupling to form butadiene.
