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1.
Phys Rev Lett ; 125(19): 196403, 2020 Nov 06.
Article in English | MEDLINE | ID: mdl-33216567

ABSTRACT

While the breakdown of the perturbation expansion for the many-electron problem has several formal consequences, here we unveil its physical effect: flipping the sign of the effective electronic interaction in specific scattering channels. By decomposing local and uniform susceptibilities of the Hubbard model via their spectral representations, we prove how entering the nonperturbative regime causes an enhancement of the charge response, ultimately responsible for the phase-separation instabilities close to the Mott metal-insulator transition. Our analysis opens a new route for understanding phase transitions in the nonperturbative regime and clarifies why attractive effects emerging from a strong repulsion can induce phase separations but not s-wave pairing or charge-density wave instabilities.

2.
Nat Mater ; 16(10): 998-1002, 2017 10.
Article in English | MEDLINE | ID: mdl-28892051

ABSTRACT

The charge mobility of molecular semiconductors is limited by the large fluctuation of intermolecular transfer integrals, often referred to as off-diagonal dynamic disorder, which causes transient localization of the carriers' eigenstates. Using a recently developed theoretical framework, we show here that the electronic structure of the molecular crystals determines its sensitivity to intermolecular fluctuations. We build a map of the transient localization lengths of high-mobility molecular semiconductors to identify what patterns of nearest-neighbour transfer integrals in the two-dimensional (2D) high-mobility plane protect the semiconductor from the effect of dynamic disorder and yield larger mobility. Such a map helps rationalizing the transport properties of the whole family of molecular semiconductors and is also used to demonstrate why common textbook approaches fail in describing this important class of materials. These results can be used to rapidly screen many compounds and design new ones with optimal transport characteristics.

3.
Phys Rev Lett ; 115(9): 096405, 2015 Aug 28.
Article in English | MEDLINE | ID: mdl-26371669

ABSTRACT

We report the formation and observation of an electron liquid in Sr(2-x)La(x)TiO4, the quasi-two-dimensional counterpart of SrTiO3, through reactive molecular-beam epitaxy and in situ angle-resolved photoemission spectroscopy. The lowest lying states are found to be comprised of Ti 3d_{xy} orbitals, analogous to the LaAlO3/SrTiO3 interface and exhibit unusually broad features characterized by quantized energy levels and a reduced Luttinger volume. Using model calculations, we explain these characteristics through an interplay of disorder and electron-phonon coupling acting cooperatively at similar energy scales, which provides a possible mechanism for explaining the low free carrier concentrations observed at various oxide heterostructures such as the LaAlO3/SrTiO3 interface.

4.
Phys Rev Lett ; 110(24): 246405, 2013 Jun 14.
Article in English | MEDLINE | ID: mdl-25165946

ABSTRACT

Identifying the fingerprints of the Mott-Hubbard metal-insulator transition may be quite elusive in correlated metallic systems if the analysis is limited to the single particle level. However, our dynamical mean-field calculations demonstrate that the situation changes completely if the frequency dependence of the two-particle vertex functions is considered: The first nonperturbative precursors of the Mott physics are unambiguously identified well inside the metallic regime by the divergence of the local Bethe-Salpeter equation in the charge channel. In the low-temperature limit this occurs for interaction values where incoherent high-energy features emerge in the spectral function, while at high temperatures it is traceable up to the atomic limit.

5.
Phys Rev Lett ; 108(25): 256401, 2012 Jun 22.
Article in English | MEDLINE | ID: mdl-23004626

ABSTRACT

By comparing photoemission spectroscopy with a nonperturbative dynamical mean field theory extension to many-body ab initio calculations, we show in the prominent case of pentacene crystals that an excellent agreement with experiment for the bandwidth, dispersion, and lifetime of the hole carrier bands can be achieved in organic semiconductors, provided that one properly accounts for the coupling to molecular vibrational modes and the presence of disorder. Our findings rationalize the growing experimental evidence that even the best band structure theories based on a many-body treatment of electronic interactions cannot reproduce the experimental photoemission data in this important class of materials.

6.
Phys Rev Lett ; 106(16): 166403, 2011 Apr 22.
Article in English | MEDLINE | ID: mdl-21599392

ABSTRACT

The consequences of several microscopic interactions on the photoemission spectra of crystalline organic semiconductors are studied theoretically. It is argued that their relative roles can be disentangled by analyzing both their temperature and their momentum-energy dependence. Our analysis shows that the polaronic thermal band narrowing, which is the foundation of most theories of electrical transport in organic semiconductors, is inconsistent in the range of microscopic parameters appropriate for these materials. An alternative scenario is proposed to explain the experimental trends.

7.
Phys Rev Lett ; 103(26): 266601, 2009 Dec 31.
Article in English | MEDLINE | ID: mdl-20366327

ABSTRACT

We analyze a model that accounts for the inherently large thermal lattice fluctuations associated with the weak van der Waals intermolecular bonding in crystalline organic semiconductors. In these materials the charge mobility generally exhibits a "metalliclike" power-law behavior, with no sign of thermally activated hopping characteristic of carrier self-localization, despite apparent mean free paths comparable to or lower than the intermolecular spacing. Our results show that such a puzzling transport regime can be understood from the simultaneous presence of band carriers and incoherent states that are dynamically localized by the thermal lattice disorder.

8.
J Phys Condens Matter ; 20(23): 235203, 2008 Jun 11.
Article in English | MEDLINE | ID: mdl-21694294

ABSTRACT

We study the transition probability and coherence of a two-site system, interacting with an oscillator. Both properties depend on the initial preparation. The oscillator is prepared in a thermal state and, even though it cannot be considered as an extended bath, it produces decoherence because of the large number of states involved in the dynamics. In the case in which the oscillator is initially displaced, a coherent dynamics of charge entangled with oscillator modes takes place. Coherency is, however, degraded as far as the oscillator mass increases, producing an increasingly large recoherence time. Calculations are carried on by exact diagonalization and compared with two semiclassical approximations. The role of the quantum effects are highlighted in the long time dynamics, where semiclassical approaches give rise to a dissipative behaviour. Moreover, we find that the oscillator dynamics has to be taken into account, even in a semiclassical approximation, in order to reproduce a thermally activated enhancement of the transition probability.

9.
Nat Mater ; 5(12): 982-6, 2006 Dec.
Article in English | MEDLINE | ID: mdl-17086169

ABSTRACT

In organic field-effect transistors (FETs), charges move near the surface of an organic semiconductor, at the interface with a dielectric. In the past, the nature of the microscopic motion of charge carriers--which determines the device performance--has been related to the quality of the organic semiconductor. Recently, it was discovered that the nearby dielectric also has an unexpectedly strong influence. The mechanisms responsible for this influence are not understood. To investigate these mechanisms, we have studied transport through organic single-crystal FETs with different gate insulators. We find that the temperature dependence of the mobility evolves from metallic-like to insulating-like with increasing dielectric constant of the insulator. The phenomenon is accounted for by a two-dimensional Fröhlich polaron model that quantitatively describes our observations and shows that increasing the dielectric polarizability results in a crossover from the weak to the strong polaronic coupling regime. This represents a considerable step forward in our understanding of transport through organic transistors, and identifies a microscopic physical process with a large influence on device performance.

10.
J Phys Condens Matter ; 18(32): 7669-85, 2006 Aug 16.
Article in English | MEDLINE | ID: mdl-21690879

ABSTRACT

We give an analytical formula in term of continued fraction expansions for the spectral function of a tunnelling electron, coupled to a local lattice oscillation, in a two-site cluster at non-zero temperature. We also study the spectral function of the polaron, a better defined quasi-particle in the anti-adiabatic regime and at sufficiently low temperature. The exact results obtained allow us to look into a wide range of temperature and coupling. Asymptotic results can be obtained directly from the continued fraction expansions in both adiabatic and anti-adiabatic regimes. In the intermediate/strong anti-adiabatic case, in contrast to the usual Lang-Firsov approximation scheme, we found that there is no shrinking of the polaron band as temperature increases. Polaron bandwidth gets broader by temperature effects.

11.
Phys Rev Lett ; 94(3): 036406, 2005 Jan 28.
Article in English | MEDLINE | ID: mdl-15698295

ABSTRACT

Isotope effects (IEs) are powerful tools to probe directly the dependence of many physical properties on lattice dynamics. In this Letter we investigate the onset of anomalous IEs in the spinless Holstein model by employing the dynamical mean field theory. We show that the isotope coefficients of the electron effective mass and of the dressed phonon frequency are sizable also far away from the polaronic crossover and mark the importance of nonadiabatic lattice fluctuations. We draw a nonadiabatic phase diagram in which we identify a novel crossover, not related to polaronic features, where the IEs attain their largest anomalies.

12.
Phys Rev Lett ; 91(18): 186405, 2003 Oct 31.
Article in English | MEDLINE | ID: mdl-14611298

ABSTRACT

The formation of a finite-density polaronic state is analyzed in the context of the Holstein model using the dynamical mean-field theory. The spinless and spinful fermion cases are compared to disentangle the polaron crossover from the bipolaron formation. The exact solution of dynamical mean-field theory is compared with weak-coupling perturbation theory, noncrossing (Migdal), and vertex correction approximations. We show that polaron formation is not associated with a metal-insulator transition, which is instead due to bipolaron formation.

13.
Phys Rev Lett ; 91(25): 256403, 2003 Dec 19.
Article in English | MEDLINE | ID: mdl-14754132

ABSTRACT

We present a unified view of the transport properties of small polarons in the Holstein model at low carrier densities, based on the dynamical mean-field theory. The nonperturbative nature of the approach allows us to study the crossover from classical activated motion at high temperatures to coherent motion at low temperatures. Large quantitative discrepancies from the standard polaronic formulas are found. The scaling properties of the resistivity are analyzed, and a simple interpolation formula is proposed in the nonadiabatic regime.

14.
Phys Rev Lett ; 88(11): 117003, 2002 Mar 18.
Article in English | MEDLINE | ID: mdl-11909423

ABSTRACT

The evidence for the key role of the sigma bands in the electronic properties of MgB2 points to the possibility of nonadiabatic effects in the superconductivity of these materials. These are governed by the small value of the Fermi energy due to the vicinity of the hole doping level to the top of the sigma bands. We show that the nonadiabatic theory leads to a coherent interpretation of T(c) = 39 K and the boron isotope coefficient alphaB = 0.30 without invoking very large couplings and it naturally explains the role of the disorder on T(c). It also leads to various specific predictions for the properties of MgB2 and for the material optimization of these types of compounds.

15.
Phys Rev Lett ; 87(20): 206406, 2001 Nov 12.
Article in English | MEDLINE | ID: mdl-11690499

ABSTRACT

We present a novel path integral Monte Carlo scheme to solve the Fröhlich polaron model. At intermediate and strong electron-phonon couplings, the polaron self-trapping is properly taken into account at the level of an effective action obtained by a preaveraging procedure with a retarded trial action. We compute the free energy at several couplings and temperatures in three and two dimensions. Our results show that the accuracy of the Feynman variational upper bound for the free energy is always within a few percent. The method can be generalized to the N-polarons case.

19.
Phys Rev B Condens Matter ; 38(4): 2596-2602, 1988 Aug 01.
Article in English | MEDLINE | ID: mdl-9946569
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