Seven-coordinate group 6 metal hydrides obtained by H2 activation at B(C6F5)3 adducts of N2 complexes: Frustrated Lewis Pair-type Reactivity of the B-N linkage.

The adducts 2M,R of general formula trans-[(L)M{R2P(CH2)2PR2}2{N2B(C6F5)3}] (L = ø or N2, M = Mo or W, R = Et or Ph), formed from Lewis acid-base pairing of B(C6F5)3 to a dinitrogen ligand of zero-valent group 6 bis(phosphine) complexes trans-[M{R2P(CH2)2PR2}2(N2)2] are shown to react with dihydrogen to afford hepta-coordinated bis(hydride) complexes [M(H)2{R2P(CH2)2PR2}{N2B(C6F5)3}] 3M,R which feature the rare ability to activate both dinitrogen and dihydrogen at a single metal center, except in the case where M = Mo and R = Ph for which fast precipitation of insoluble [Mo(H)4(dppe)2] (dppe = 1,2-bis(diphenylphosphino)ethane) occurs. The frustrated Lewis pair (FLP)-related reactivity of the B-N linkage in compounds 3W,R was explored and led to distal N functionalization without involvement of the hydride ligands. It is shown in one example that the resulting bis(hydride) diazenido compounds may also be obtained through a sequence involving first FLP-type N-functionalization followed by oxidative addition of H2. Those oily compounds were found to have limited stability in solution or in their isolated states. Finally, treatment of 3W,Et with the Lewis base N,N-dimethylaminopyridine (DMAP) affords the simple but unknown bis(hydride)-dinitrogen species [W(H)2(depe)2(N2)] 11Et (depe = 1,2-bis(diethylphosphino)ethane) which direct, selective formation from trans-[W(N2)2(depe)2] is not possible.

An orbitally adapted push-pull template for N2 activation and reduction to diazene-diide.

A Lewis superacidic bis(borane) C6F4{B(C6F5)2}2 was reacted with tungsten N2-complexes [W(N2)2(R2PCH2CH2PR2)2] (R = Ph or Et), affording zwitterionic boryldiazenido W(ii) complexes trans-[W(L)(R2PCH2CH2PR2)2(N2{B(C6F5)2(C6F4B(C6F5)3})] (L = ø, N2 or THF). These compounds feature only one N-B linkage of the covalent type, as a result of intramolecular boron-to-boron C6F5 transfer. Complex trans-[W(THF)(Et2PCH2CH2PEt2)2(N2{B(C6F5)2C6F4B(C6F5)3})] (5) was shown to split H2, leading to a seven-coordinate complex [W(H)2(Et2PCH2CH2PEt2)2(N2{B(C6F5)2}2C6F4)] (7). Interestingly, hydride storage at the metal triggers backward C6F5 transfer. This reverts the bis(boron) moiety to its bis(borane) state, now doubly binding the distal N, with structural parameters and DFT computations pointing to dative N→B bonding. By comparison with an N2 complex [W(H)2(Et2PCH2CH2PEt2)2(N2{B(C6F5)3}] (10) differing only in the Lewis acid (LA), namely B(C6F5)3, coordinated to the distal N, we demonstrate that two-fold LA coordination imparts strong N2 activation up to the diazene-diide (N22-) state. To the best of our knowledge, this is the first example of a neutral LA coordination that induces reduction of N2.

Assessing Combinations of B(C6 F5 )3 and N2 -Derived Molybdenum Nitrido Complexes for Heterolytic Bond Activation.

Two different dinitrogen-derived molybdenum nitrido complexes varying by their geometry, ligand spheres and oxidations states were shown to engage their N ligand in dative bonding with the strong Lewis acid B(C6 F5 )3 . The stable adducts were assessed for frustrated Lewis pair-type heterolytic E-H bond splitting of hydrosilanes (E=Si) and HB(C6 F5 )2 . Whereas Si-H bond activation was achieved, HB(C6 F5 )2 was shown to substitute B(C6 F5 )3 in a quantitative or equilibrated fashion, depending on the nature of the nitrido complex. No B-H bond splitting was observed. Thermodynamics of these reactions, computed by DFT, are in agreement with the experimental outcomes.

Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation.

To prepare N2-derived cationic boryldiazenido-tungsten complexes as models of semimetallic metal-borinium frustrated Lewis pairs activating N2, we have attempted halide abstraction from trans-(diarylboryl)diazenido-halo-tungsten complexes. Reactions with Tl+ led to adducts in which coordination of the cation differs depending on the boryldiazenide substituents and the ancillary ligand. Chloride scavenging was not observed.

Borane-catalysed dinitrogen borylation by 1,3-B-H bond addition.

The borylation of ligated dinitrogen by 1,3-B-H bond addition over a W-N[triple bond, length as m-dash]N unit using various hydroboranes has been examined. In a previous study, we have shown that Piers' borane (1) reacted with the tungsten dinitrogen complex 2 to afford a boryldiazenido-hydrido-tungsten species. The ease and mildness of this reaction have encouraged us to extend its scope, with the working hypothesis that 1 could potentially catalyse the 1,3-B-H bond addition of other hydroboranes. Under productive reaction conditions, dicyclohexylborane (HBCy2) and diisopinocampheylborane (HBIpc2) underwent retro-hydroboration to give cyclohexylborane (H2BCy) or isopinocampheylborane (H2BIpc), respectively; these monoalkylboranes act as N2-borylating agents in the presence of a catalytic amount of 1. Under similar conditions, 9-borabicyclononane (9-BBN) slowly adds over the W-N[triple bond, length as m-dash]N unit without rearrangement to a monoalkylborane. Catecholborane (HBcat) undergoes the 1,3-B-H bond addition without the need for a catalyst. We were not able to build more than one covalent B-N bond between the terminal N of the N2 ligand and the boron reagent with this methodology.

Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes.

We have prepared and characterized a series of unprecedented group 6-group 11, N2-bridged, heterobimetallic [ML4(η1-N2)(µ-η1:η1-N2)Au(NHC)]+ complexes (M = Mo, W, L2 = diphosphine) by treatment of trans-[ML4(N2)2] with a cationic gold(I) complex [Au(NHC)]+. The adducts are very labile in solution and in the solid, especially in the case of molybdenum, and decomposition pathways are likely initiated by electron transfers from the zerovalent group 6 atom to gold. Spectroscopic and structural parameters point to the fact that the gold adducts are very similar to Lewis pairs formed out of strong main-group Lewis acids (LA) and low-valent, end-on dinitrogen complexes, with a bent M-N-N-Au motif. To verify how far the analogy goes, we computed the electronic structures of [W(depe)2(η1-N2)(µ-η1:η1-N2)AuNHC]+ (10W+) and [W(depe)2(η1-N2)(µ-η1:η1-N2)B(C6F5)3] (11W). A careful analysis of the frontier orbitals of both compounds shows that a filled orbital resulting from the combination of the π* orbital of the bridging N2 with a d orbital of the group 6 metal overlaps in 10W+ with an empty sd hybrid orbital at gold, whereas in 11W with an sp3 hybrid orbital at boron. The bent N-N-LA arrangement maximizes these interactions, providing a similar level of N2 "push-pull" activation in the two compounds. In the gold case, the HOMO-2 orbital is further delocalized to the empty carbenic p orbital, and an NBO analysis suggests an important electrostatic component in the µ-N2-[Au(NHC)]+ bond.

Frustrated Lewis Pair Chemistry Enables N2 Borylation by Formal 1,3-Addition of a B-H Bond in the Coordination Sphere of Tungsten.

The first example of a formal 1,3-B-H bond addition across the M-N≡N unit of an end-on dinitrogen complex has been achieved. The use of Piers' borane HB(C6 F5 )2 was essential to observe this reactivity and it plays a triple role in this transformation: 1) electrophilic N2 -borylation agent, 2) Lewis acid in a frustrated Lewis pair-type B-H bond activation, and 3) hydride shuttle to the metal center. This chemistry is supported by NMR spectroscopy and solid-state characterization of products and intermediates. The combination of chelate effect and strong σ donation in the diphosphine ligand 1,2-bis(diethylphosphino)ethane was mandatory to avoid phosphine dissociation that otherwise led to complexes where borylation of N2 occurred without hydride transfer.

Radical Germylzincation of α-Heteroatom-Substituted Alkynes.

The regio- and stereoselective addition of germanium and zinc across the C-C triple bond of nitrogen-, sulfur-, oxygen-, and phosphorus-substituted terminal and internal alkynes is achieved by reaction with a combination of R3GeH and Et2Zn. Diagnostic experiments support a radical-chain mechanism and the ß-zincated vinylgermanes that show exceptional stability are characterized by NMR spectroscopy and X-ray crystallography. The unique feature of this new radical germylzincation reaction is that the C(sp2)-Zn bond formed remains available for subsequent in situ Cu(I)- or Pd(0)-mediated C-C or C-heteroatom bond formation with retention of the double bond geometry. These protocols offer modular access to elaborated tri- and tetrasubstituted vinylgermanes decorated with heteroatom substituents ß to germanium that are useful for the preparation of stereodefined alkenes.