Removal of pharmaceuticals and personal care products by two-stage biofiltration for drinking water treatment.

Contamination of drinking water with pharmaceuticals and personal care products (PPCPs) is an issue of health concerns. To effectively control the level of PPCPs in drinking water, a pilot study employing two parallel trains of two-stage biofiltration, i.e., a sand/anthracite (SA) biofilter coupled with a biologically-active granular activated carbon (GAC) post-filter contactor, was conducted as a post-treatment after coagulation in a drinking water treatment plant. Results showed the biofiltration process could effectively remove PPCPs with an average removal of 53.4%, where the GAC contactor played the dominant role to remove 48.1% of the total PPCPs. The molecular properties determined the removability of individual PPCPs, i.e., smaller molecules with simpler structure connectivity were more likely to be removed. Based on the quantitative structure-property relationships (QSPRs) analysis, a simple regression model was proposed to predict the removability of each PPCP across the biofiltration process. The drinking water equivalent level (DWEL) quotient method was developed to assess the health risks of detected PPCPs in water samples. The biofiltration process showed efficient capacity to reduce the health risks of PPCPs with an average removal of 79%, and the PPCPs in the effluents generally would not pose adverse health effects. Pearson correlation analysis explored the possible role of nitrogenous PPCPs (N-PPCPs) as the precursors of nitrogenous disinfection byproducts (N-DBPs) in drinking waters. Aromatic nitrogen in PPCPs was found to be a significant descriptor for the formation potential of trichloroacetonitrile (TCAN). In addition, it was found that pre-filter chlorination could slightly improve the biofiltration of PPCPs.

Removal of disinfection byproduct (DBP) precursors in water by two-stage biofiltration treatment.

The removal of precursors of 36 disinfection byproducts (DBPs) in effluents from flocculation/sedimentation process was evaluated across a pilot-scale two-stage biofiltration process, i.e., a sand/anthracite (SA) biofilter (empty bed contact time (EBCT) of 7.5 min) coupled with a biologically-active granular activated carbon (GAC) contactor (EBCT of 15 min). The biofiltration process exhibited a good capacity for removal of the total DBP formation potential (DBPFP) (by 25.90 ± 2.63%), and GAC contactors contributed most to the DBPFP removal (accounting for 60.63 ± 16.64% of the total removal). The removal percentage of DBPFPs of different structure types was in the following order: halonitroalkanes (58.50%) > haloaldehydes (33.62%) > haloacetic acids (HAAs, 28.13%) > haloalkanes (20.46%) > haloketones (13.46%) > nitrosamines (10.23%) > halonitriles (-8.82%) > haloalkenes (-9.84%). The precursors of bromo-DBPs (containing only bromine atoms) and maximal halogenated DBPs (containing 3 & 4 halo atoms) were removed largely compared to other DBPs. Among the total DBPFP, trihalomethanes (THMs), HAAs, and chloral hydrate were the dominant DBPs, and they accounted for >92% of the total targeted DBPs by weight. Pearson correlation analysis (CA) and principal components analysis (PCA) indicated a significant association among these dominant DBPs. Canonical correspondence analysis (CCA) revealed specific ultraviolet absorbance (SUVA254) could serve as a good surrogate parameter for DBPFP. Pre-chlorination upstream of the biofilters may not greatly impact the overall removal of DBPFP by SA/GAC biofiltration. In addition, results showed that SA/GAC biofiltration was a useful procedure to remove the inorganic DBP chlorite.

Pilot investigation of two-stage biofiltration for removal of natural organic matter in drinking water treatment.

A pilot study employing two parallel trains of two-stage biofiltration, i.e., a sand/anthracite (SA) biofilter followed by a biologically-active granular activated carbon (GAC) contactor, was conducted to test the efficiency, feasibility and stability of biofiltration for removing natural organic matter (NOM) after coagulation in a drinking water treatment plant. Results showed the biofiltration process could effectively remove turbidity (<0.1 NTU in all effluents) and NOM (>24% of dissolved organic carbon (DOC), >57% of UV254, and >44% of SUVA254), where the SA biofilters showed a strong capacity for turbidity removal, while the GAC contactors played the dominant role in NOM removal. The vertical profile of water quality in the GAC contactors indicated the middle-upper portion was the critical zone for the removal of NOM, where relatively higher adsorption and enhanced biological removal were afforded. Fluorescence excitation-emission matrix (EEM) analysis of NOM showed that the GAC contactors effectively decreased the content of humic-like component, while protein-like component was refractory for the biofiltration process. Nutrients (NH4-N and PO4-P) supplementation applied upstream of one of the two-stage biofiltration trains (called engineered biofiltration) stimulated the growth of microorganisms, and showed a modest effect on promoting the biological removal of small non-aromatic compositions in NOM. Redundancy analysis (RDA) indicated influent UV254 was the most explanatory water quality parameter for GAC contactors' treatment performance, and a high load of UV254 would result in significantly reduced removals of UV254 and SUVA254.