Plasmon Excitations in Mixed Metallic Nanoarrays.

Features of the surface plasmon from macroscopic materials emerge in molecular systems, but differentiating collective excitations from single-particle excitations in molecular systems remains elusive. The rich interactions between single-particle electron-hole and collective electron excitations produce phenomena related to the chemical physics aspects within the atomic array. We study the plasmonic properties of atomic arrays of noble (Au, Ag, and Cu) and transition-metal (Pd, Pt) homonuclear chains using time-dependent density functional theory and their Kohn-Sham transition contributions. The response to the electromagnetic radiation is related to both the geometry-dependent confinement of sp-valence electrons and the energy position of d-electrons in the different atomic species and the hybridization between d and sp electrons. It is possible to tune the position of the plasmon resonance, split it into several peaks, and eventually achieve broadband absorption of radiation. Arrays of mixed noble and transition-metal chains may have strongly attenuated plasmonic behavior. The collective nature of the excitations is ascertained using their Kohn-Sham transition contributions. To manipulate the plasmonic response and achieve the desired properties for broad applications, it is vital to understand the origins of these phenomena in atomic chains and their arrays.

National Athletic Trainers' Association position statement: Preparticipation physical examinations and disqualifying conditions.

OBJECTIVE: To present athletic trainers with recommendations for the content and administration of the preparticipation physical examination (PPE) as well as considerations for determining safe participation in sports and identifying disqualifying conditions. BACKGROUND: Preparticipation physical examinations have been used routinely for nearly 40 years. However, considerable debate exists as to their efficacy due to the lack of standardization in the process and the lack of conformity in the information that is gathered. With the continuing rise in sports participation at all levels and the growing number of reported cases of sudden death in organized athletics, the sports medicine community should consider adopting a standardized process for conducting the PPE to protect all parties. RECOMMENDATIONS: Recommendations are provided to equip the sports medicine community with the tools necessary to conduct the PPE as effectively and efficiently as possible using available scientific evidence and best practices. In addition, the recommendations will help clinicians identify those conditions that may threaten the health and safety of participants in organized sports, may require further evaluation and intervention, or may result in potential disqualification.

Reliability, precision, accuracy, and validity of posterior shoulder tightness assessment in overhead athletes.

BACKGROUND: Posterior shoulder tightness with subsequent loss of humeral internal rotation range of motion has been linked to upper extremity lesions in overhead athletes. A valid clinical assessment is necessary to accurately identify posterior shoulder tightness as a contributor to injury. PURPOSE: To describe a modified supine assessment of posterior shoulder tightness by establishing the reliability, precision, clinical accuracy, and validity of the assessment. STUDY DESIGN: Cohort study (diagnosis); Level of evidence, 2. METHODS: Intrasession, intersession, and intertester reliability and precision were established by comparing the commonly used side-lying assessment of posterior shoulder tightness and the described modified supine assessment. Clinical accuracy of both methods was obtained using an electromagnetic tracking device to track humeral and scapular motion. Construct validity was established by identifying posterior shoulder tightness in a group of overhead athletes (baseball pitchers and tennis players) reported in the literature to have limited humeral internal rotation and posterior shoulder tightness. RESULTS: The side-lying intrasession intraclass correlation coeffecient (standard error of measurement), intersession intraclass correlation coeffecient (standard error of measurement), and intertester intraclass correlation coeffecient (standard error of measurement) were 0.83 cm (0.9), 0.42 cm (1.7), and 0.69 cm (1.4), respectively. The supine intrasession intraclass correlation coeffecient (standard error of measurement), intersession intraclass correlation coeffecient (standard error of measurement), and intertester intraclass correlation coeffecient (standard error of measurement) were 0.91 degrees (1.1 degrees ), 0.75 degrees (1.8 degrees ), and 0.94 degrees (1.8 degrees ), respectively. In side-lying, the clinical accuracy expected was 0.9 +/- 0.6 cm of error while, when measured supine, it was 3.5 degrees +/- 2.8 degrees of error. Both assessments resulted in minimal scapular protraction (approximately 3.5 degrees ). Between groups, baseball pitchers and tennis players had significantly less internal rotation range of motion (P < .0001) and greater posterior shoulder tightness (P = .004) when measured in supine, but not in side-lying (P = .312). CONCLUSION: Both methods resulted in good clinician accuracy and precision, suggesting that both can be performed accurately. The supine method can be assessed more reliably than side-lying between both sessions and testers. CLINICAL RELEVANCE: Clinicians may want to consider use of the supine method given the higher reliability, validity, and similar precision and clinical accuracy.

Proprioception and throwing accuracy in the dominant shoulder after cryotherapy.

CONTEXT: Application of cryotherapy modalities is common after acute shoulder injury and as part of rehabilitation. During athletic events, athletes may return to play after this treatment. The effects of cryotherapy on dominant shoulder proprioception have been assessed, yet the effects on throwing performance are unknown. OBJECTIVE: To determine the effects of a cryotherapy application on shoulder proprioception and throwing accuracy. DESIGN: Single-group, pretest-posttest control session design. SETTING: University-based biomechanics laboratory. PATIENTS OR OTHER PARTICIPANTS: Healthy college-aged subjects (n = 22). INTERVENTION(S): Twenty-minute ice pack application to the dominant shoulder. MAIN OUTCOME MEASURE(S): Active joint position replication, path of joint motion replication, and the Functional Throwing Performance Index. RESULTS: Subjects demonstrated significant increases in deviation for path of joint motion replication when moving from 90 degrees of abduction with 90 degrees of external rotation to 20 degrees of flexion with neutral shoulder rotation after ice pack application. Also, subjects exhibited a decrease in Functional Throwing Performance Index after cryotherapy application. No differences were found in subjects for active joint position replication after cryotherapy application. CONCLUSIONS: Proprioception and throwing accuracy were decreased after ice pack application to the shoulder. It is important that clinicians understand the deficits that occur after cryotherapy, as this modality is commonly used following acute injury and during rehabilitation. This information should also be considered when attempting to return an athlete to play after treatment.