Evidence of enhanced atmospheric ammoniacal nitrogen in Hells Canyon national recreation area: implications for natural and cultural resources.

Agriculture releases copious fertilizing pollutants to air sheds and waterways of the northwestern United States. To evaluate threats to natural resources and historic rock paintings in remote Hells Canyon, Oregon and Idaho, deposition of ammonia (NH3), nitrogen oxides (NOx), sulfur dioxide (SO2), and hydrogen sulfide (H2S) at five stations along 60 km of the Snake River valley floor were passively sampled from July 2002 through June 2003, and ozone data and particulate chemistry were obtained from the Interagency Monitoring of Protected Visual Environments (IMPROVE) station at Hells Canyon. NH3 concentrations were high; biweekly averages peaked at 5-19 ppb in spring and summer and the nutrient-laden Snake River is a likely source. Fine particulate ammonium nitrate (NH4NO3) averaged 2.6 microg/m3 during the 20% of worst visibility days with winter drainage of air masses from the Snake River Basin and possibly long distance transport from southern California. Other pollutants were within background ranges. NH3 is corrosive to clay-based pictographs; nitrogen deposition can alter natural biotic communities and terrestrial ecosystem processes at levels reported here.

A statistical analysis of visibility-impairing particles in federal Class I areas.

It is widely agreed that visibility conditions in many Class I areas are impaired to some extent. This paper provides an estimate of the degree of impairment in many of the Class I areas with respect to each of the six haze-forming aerosol classes as described in the supporting documents to the U.S. Environmental Protection Agency Regional Haze Rule. Analyses are performed comparing data from the Interagency Monitoring of Protected Visual Environments network to a modified version of the default natural conditions estimates from the Regional Haze Rule. Uncertainties in the measured annual mean concentrations and biases in the default natural condition estimates because of the effects of geography and meteorology are discussed. It is determined that all of the Class I areas in the contiguous 48 United States are significantly impaired with respect to sulfate aerosols, most of the Class I areas are significantly impaired with respect to nitrate and elemental carbon aerosols, and impairment with respect to organic mass, soil mass, and coarse mass is generally less discernable. No attempt is made to determine adverse impacts with respect to any specific source or group of sources.

Effects of Indoor Pyrotechnic Displays on the Air Quality in the Houston Astrodome.

Fine and coarse particulate mass samples were collected during baseball games with pyrotechnic displays and control games without displays. The average fine and coarse particulate masses were 173 and 141 mg/m3, respectively, for the one-hour period immediately following the pyrotechnic displays. The particulate matter generated by the pyrotechnic displays was composed of the following elements (arranged from most to least abundant): K, S, Mg,Ti, Cl, Si, Ca, Al, Sr, V, Zn, Mn, and Pb. Although the average particulate mass concentrations were high during the first hour, the ventilation system reduced the concentrations by up to 41% during the second hour after the display.