High-temperature and stress response behavior of femtosecond laser pulses inscribed eccentric fiber Bragg gratings.

Eccentric fiber Bragg grating (EFBG) is inscribed in standard communication single-mode fiber using femtosecond laser pulses, and the temperature and strain sensing characteristics are experimentally demonstrated and analyzed. The EFBG exhibits strong thermal stability and good robustness in high-temperature measurement up to 1000 °C, and undergoes different thermal sensitivities during Bragg peak and the strong resonance coupled cladding spectral comb. The temperature sensitivity linearly increases with respect to the effective index of the resonant modes. Such a situation also occurs in axial strain measurement. These characteristics are of high interest for multiparametric sensing at high temperatures.

Generation of a vortex point adjustable vortex array based on decentered annular beam pumping.

An adjustable optical vortex array (OVA) based on decentered annular beam pumping has been demonstrated in an end-pumped Nd:YVO4 laser. This method allows for not only the transverse mode locking of different modes, but also the ability to adjust the mode weight and phase by manipulating the position of the focusing lens and axicon lens. To explain this phenomenon, we propose a threshold model for each mode. Using this approach, we were able to generate optical vortex arrays with 2-7 phase singularities, achieving a maximum conversion efficiency of 25.8%. Our work represents an innovative advancement in the development of solid-state lasers capable of generating adjustable vortex points.

Ultra-High Sensitivity Terahertz Microstructured Fiber Biosensor for Diabetes Mellitus and Coronary Heart Disease Marker Detection.

Diabetes Mellitus (DM) and Coronary Heart Disease (CHD) are among top causes of patient health issues and fatalities in many countries. At present, terahertz biosensors have been widely used to detect chronic diseases because of their accurate detection, fast operation, flexible design and easy fabrication. In this paper, a Zeonex-based microstructured fiber (MSF) biosensor is proposed for detecting DM and CHD markers by adopting a terahertz time-domain spectroscopy system. A suspended hollow-core structure with a square core and a hexagonal cladding is used, which enhances the interaction of terahertz waves with targeted markers and reduces the loss. This work focuses on simulating the transmission performance of the proposed MSF sensor by using a finite element method and incorporating a perfectly matched layer as the absorption boundary. The simulation results show that this MSF biosensor exhibits an ultra-high relative sensitivity, especially up to 100.35% at 2.2THz, when detecting DM and CHD markers. Furthermore, for different concentrations of disease markers, the MSF exhibits significant differences in effective material loss, which can effectively improve clinical diagnostic accuracy and clearly distinguish the extent of the disease. This MSF biosensor is simple to fabricate by 3D printing and extrusion technologies, and is expected to provide a convenient and capable tool for rapid biomedical diagnosis.

1.7 THz tuning range pivot-point-independent mode-hop-free external cavity diode laser.

A novel mode-hop-free (MHF) tunable external cavity diode laser (ECDL) is demonstrated without mechanical pivot-point tuning. By corotating a periscope with an etalon and a narrow band pass (NBP) filter inside an external cavity, the cavity single longitudinal mode selection can be maintained, and continuous tuning can be achieved with optimal synchronization. A MHF continuous tuning range of 1.7 THz has been achieved with a semiconductor gain chip at the wavelength of 652 ± 2 nm experimentally, and the theoretical tuning range can reach over 4.8 THz. The laser linewidth is estimated to be less than 1 MHz (FWHM) by a scanning Fabry-Perot (F-P) and a Michelson interferometer. 1 mW output power with variation of less than 10% in the tuning region of roughly 1.7 THz has been demonstrated.

ZnO/Cu2O heterojunction integrated fiber-optic biosensor for remote detection of cysteine.

Indium tin oxide, semiconductor nanomaterial ZnO, and Cu2O were first loaded on the surface of the optical fiber to form an optical fiber probe. Large-volume macroscopic spatial light is replaced by an optical fiber path, and remote light injection is implemented. Based on the optical fiber probe, a photoelectrochemical biosensor was constructed and remote detection of cysteine was realized. In this tiny device, the optical fiber probe not only acts as a working electrode to react with the analyte but also directs the light exactly where it is needed. Simultaneously, the electrochemical behavior of cysteine on the surface of the working electrode is dominated by diffusion-control, which provides strong support for quantitative detection. Then, under the bias potential of 0 V, the linear range of the fiber-optic-based cysteine biosensor was 0.01∼1 µM, the regression coefficient (R2) value was 0.9943. In spiked synthetic urine, the detection of cysteine was also realized by the integrated biosensor. Moreover, benefiting from the low optical fiber loss, the new structure also possesses a unique remote detection function. This work confirms that photoelectrochemical biosensors can be integrated via optical fibers and retain comparable sensing performance. Based on this property, different materials can also be loaded on the surface of the optical fiber for remote detection of other analytes. It is expected to facilitate the research on fiber-optic-based integrated biosensors and show application prospects in diverse fields such as biochemical analysis and disease diagnosis.

Fiber electric double-layer platform for a phase shifter based on the Pockels effect of liquid molecules.

The electric double layer (EDL) was formed at the interface of the electrode and liquid and has been widely used in a series of applications, ranging from batteries to biosensors, based on the electrical property changes. In this paper, we demonstrate a simple microfiber phase shifter based on the Pockels effect of liquid in the electric double layer. By constructing an EDL around the microfiber, the phase shifter can be achieved. Furthermore, the effects of ion concentration and molecular polarity of liquids on this phase shifter were studied. The fiber electric double-layer platform has the advantages of low voltage modulation and simple fabrication, which has the potential for use in wearable sensing devices, biopotential detection, and biomolecule detection.

Solving the overlapped absorbance profile in gas detection by Lorentz distribution solution based on direct absorption spectroscopy method.

A novel method of Lorentz distribution solution (LDS) from overlapped absorbance profile in time domain (incomplete absorbance profile in frequency domain) based on the direct absorption spectroscopy method (DAS) was experimentally demonstrated. It utilized the ratio of the integral in a certain interval on the lower horizontal axis of the Lorentzian profile to the integral in the entire interval on the horizontal axis has a certain relationship and can be expressed by a formula. This method effectively solves the difficulties of extracting gas concentration from incomplete absorbance profile. Formulation and detection procedure were presented, experiments were carried out to prove the method on the extraction of gas concentration from different overlapped absorbance profile and different concentration. Compared with the conventional DAS (C-DAS), the maximum relative errors on the concentration extraction are minimized from 25.55% to 2.64% at different concentration and absorbance profile. Meanwhile, the experimental results show that the obtained gas concentration by LDS presents a good linear relationship while those measured by C-DAS are significantly different.

In situ SERS detection of quinolone antibiotic residues in a water environment based on optofluidic in-fiber integrated Ag nanoparticles.

In this paper, we present a microstructured optofluidic in-fiber Raman sensor for the detection of quinolone antibiotic residue in a water environment based on Ag surface-enhanced Raman scattering (SERS) substrate grown on the surface of the suspended core of micro-hollow optical fiber (MHF). Here, MHF has a special structure with a suspended core and a microchannel inside, which can become a natural in-fiber optofluidic device. Meanwhile, the self-assembled Ag SERS substrate can be grown on the suspended core's surface through chemical bonds, forming a microstructured optofluidic device with a Raman enhancement effect. Therefore, it can effectively detect the Raman signal of unlabeled trace quinolone antibiotic residue (ciprofloxacin and norfloxacin) inside the optical fiber. The results show that the ciprofloxacin and norfloxacin detection limits (LOD) are 10-10M and 10-11M, respectively. Compared with the maximum residue limit (3.01×10-7mol/L) stipulated by the European Union, the results are much lower, and an ideal quantitative relationship can be obtained within the detection range. Significantly, this study provides an in-fiber microstructured optofluidic Raman sensor for the label-free detection of quinolone antibiotic residue, which will have good development prospects in the field of antibiotic water pollution environmental detection.

Terahertz Sensor via Ultralow-Loss Dispersion-Flattened Polymer Optical Fiber: Design and Analysis.

A novel cyclic olefin copolymer (COC)-based polymer optical fiber (POF) with a rectangular porous core is designed for terahertz (THz) sensing by the finite element method. The numerical simulations showed an ultrahigh relative sensitivity of 89.73% of the x-polarization mode at a frequency of 1.2 THz and under optimum design conditions. In addition to this, they showed an ultralow confinement loss of 2.18 × 10-12 cm-1, a high birefringence of 1.91 × 10-3, a numerical aperture of 0.33, and an effective mode area of 1.65 × 105 µm2 was obtained for optimum design conditions. Moreover, the range dispersion variation was within 0.7 ± 0.41 ps/THz/cm, with the frequency range of 1.0-1.4 THz. Compared with the traditional sensor, the late-model sensor will have application value in THz sensing and communication.

On-line SERS detection of bilirubin based on the optofluidic in-fiber integrated GO/Ag NPs for rapid diagnosis of jaundice.

In this paper, we propose a self-assembled graphene oxide (GO)/Ag NPs SERS Raman sensor based on a novel type of optofluidic MHF as a point-of-care testing (POCT) device. This device is used to diagnose jaundice and its related diseases through on-line detection of free bilirubin content in human serum. This optofluidic Raman sensor is composed of a microstructured hollow fiber (MHF) with a microstructured channel and a suspended core, which allows the sample solution to flow in the channel while interacting with the strong evanescent field on the suspended core. Here, the suspended core was modified by a GO/Ag NPs SERS substrate. When the sample flows through the channel, and interacts with the strong evanescent field generated by the suspended core, the on-line SERS signal is generated and can be coupled back to the suspended core to be detected. In addition, both the electrostatic interaction and interference between GO/Ag NPs with the target enriched bilirubin. The results show that the detection concentration range of bilirubin aqueous, bilirubin in albumin and bilirubin in human blood are all in the range of 2 µM-100 µM, and all have a good linear response. The limit of detection reaches the order of 10-6 M. This rapid, sensitive and label-free SERS Raman sensor of free bilirubin in blood can detect excessive levels of bilirubin in the actual blood environment of the human body, providing a broad prospect for clinically accurate diagnosis of jaundice and related diseases.

Transverse mode locking of different frequency-degenerate families based on annular beam pumping.

Optical vortex arrays have been achieved in an end-pumped Nd:YVO4 laser pumped by an annular beam. Spontaneous transverse mode locking of Laguerre-Gaussian modes in different frequency-degenerate families has been obtained by merely adjusting the pump power. A maximum output power of 0.88 W and optical conversion efficiency of 13.6% are achieved for optical vortex arrays. Optical vortex arrays formed in different frequency-degenerate families of Laguerre-Gaussian modes can be actively controlled by the position of the axicon. This work provides a way to research transverse mode locking of Laguerre-Gaussian modes in different frequency-degenerate families based on annular beam pumping.

Continuous In-Line Chromium Coating Thickness Measurement Methodologies: An Investigation of Current and Potential Technology.

Coatings or films are applied to a substrate for several applications, such as waterproofing, corrosion resistance, adhesion performance, cosmetic effects, and optical coatings. When applying a coating to a substrate, it is vital to monitor the coating thickness during the coating process to achieve a product to the desired specification via real time production control. There are several different coating thickness measurement methods that can be used, either in-line or off-line, which can determine the coating thickness relative to the material of the coating and the substrate. In-line coating thickness measurement methods are often very difficult to design and implement due to the nature of the harsh environmental conditions of typical production processes and the speed at which the process is run. This paper addresses the current and novel coating thickness methodologies for application to chromium coatings on a ferro-magnetic steel substrate with their advantages and limitations regarding in-line measurement. The most common in-line coating thickness measurement method utilized within the steel packaging industry is the X-ray Fluorescence (XRF) method, but these systems can become costly when implemented for a wide packaging product and pose health and safety concerns due to its ionizing radiation. As technology advances, nanometer-scale coatings are becoming more common, and here three methods are highlighted, which have been used extensively in other industries (with several variants in their design) which can potentially measure coatings of nanometer thickness in a production line, precisely, safely, and do so in a non-contact and non-destructive manner. These methods are optical reflectometry, ellipsometry and interferometry.

All-fiber bidirectional optical modulator derives from the microfiber coated with ITO electrode.

A cheap, compact, and simply prepared all-fiber bidirectional optical modulator based on the Pockels effect of water and the band population effect was first, to the best of our knowledge, proposed and demonstrated. The transparent conductive oxide indium-tin-oxide (ITO) was coated on the surface of a nonadiabatic microfiber and first used as a modulating electrode on the microfiber. The device was realized by just submerging the microfiber in water. With supplying an electric field perpendicular to the interface between the microfiber and water, the refractive index was modulated in the electric double layer near the tapered region of the microfiber, under the Pockels effect of water. Subsequently, the interference spectrum was modulated. Meanwhile, the intensity of the light was modulated due to the band population effect in the space-charge layer. In this Letter, the proposed all-fiber optical modulator can realize simultaneous bidirectional modulation of the phase and intensity of output light. Experimentally, the maximum phase shift and the extinction ratio were 4.38 nm and 4.87 dB at 1550 nm, respectively. Significantly, the work used the Pockels effect of water and the band population effect to realize an all-fiber optical modulator, showing great potential in the optical phase modulators, optical switches, and electric field sensors.

In-fiber optofluidic online SERS detection of trace uremia toxin.

In this Letter, we propose a microstructured in-fiber optofluidic surface-enhanced Raman spectroscopy (SERS) sensor for the initial inspection of uremia through the detection of unlabeled urea and creatinine. As a natural microfluidic device, microstructured hollow fiber has a special structure inside. Through chemical bonds, the SERS substrate can be modified and grown on the surface of the suspended core. Here, the silver nanoparticles (Ag NPs) are embedded on the poly diallyl dimethyl ammonium chloride-modified graphene oxide sheet to achieve the self-assembled SERS substrate. The reduced distance between Ag NPs can increase the strong hot spots that generate enhanced Raman signals. Therefore, it can effectively detect the Raman signal of unlabeled trace uremic toxin analytes (urea, creatinine) inside the optical fiber. The results show that under simulated biophysical conditions, the limit detection (LOD) for urea is 10-4M and the linearity is good, especially at the clinical conventional concentration range (2.5-6.5×10-3M). In addition, the online Raman detection of creatinine aqueous solution LOD is 10-6M, which also has good linearity. Significantly, this Letter provides a microstructured optofluidic in-fiber Raman sensor for the preliminary detection of uremia, which will have good development prospects in the field of clinical biomedicine.

All-fiber phase modulator and switch based on local surface plasmon resonance effect of the gold nanoparticles embedded in gel membrane.

All-fiber modulators and switches have drawn great interest in the photonics domain, and they are applied in viable photonic and optoelectronic devices. In this work, with the assistance of an agarose membrane, aspherical gold nanoparticles are embedded on the surface of the microfiber treated with the piranha solution. An all-fiber Mach-Zehnder interferometer was used to realize a low-cost, low-loss, and conveniently prepared all-fiber phase modulator. By taking advantage of the local surface plasmon resonance effect of gold nanoparticles embedded in the agarose membrane, under the excitation of near-infrared region light, the gold nanoparticles were excited to change the effective refractive index of one arm of the Mach-Zehnder interferometer. A maximum phase shift of ∼6π at 1550 nm was obtained from the device. In addition, an all-optical switch was achieved with a rising edge time of 47 ms and falling edge time of 14 ms. The proposed all-fiber modulator and switch based on the local surface plasmon resonance effect of gold nanoparticles embedded in agarose membrane will provide great potential in all-optical fiber systems.

Design and optical characterization of an efficient polarized organic light emitting diode based on refractive index modulation in the emitting layer.

Luminescent liquid Crystal (LC) material is regarded as the most promising material for polarized organic light emission due to their intrinsic characteristics including orderly alignment and luminescence. Nevertheless, the optical extraction efficiency of LC based organic light emitting diodes (OLEDs) devices still requires significant effort and innovation towards real-world applications. In this paper, we propose the design of a highly linearly polarized light-emission from OLEDs with integrated refractive index nanograting in the emissive layer (EML) based on photo aligned luminescent liquid crystal material. The simulation results indicate that the geometrically optimized polarized device yields an external quantum efficiency (EQE) up to 47% with a polarized ratio up to 28 dB at a 550 nm emission wavelength. This conceptual design offers a new opportunity to achieve efficient polarized organic luminescence, and it is (to the best of our knowledge) the first approach that enhances the light extraction of OLEDs based on luminescent liquid crystal via index grating in the EML.

Investigation of a highly compact intracavity actively Q-switched cascade diamond Raman laser.

A laser diode (LD) pumped intracavity chemical vapor deposition (CVD) diamond cascade Raman laser is reported here. By rotating a Brewster plate (BP) in the laser resonator, the Raman laser with tunable output coupling rate is achieved. The highly compact diamond laser emitted 1240 nm and 1485 nm Stokes light simultaneously via optimization of the pumping direction. The slope efficiency of the intracavity diamond laser is improved by optimizing the output coupling rate and adjusting the repetition rate of the 1064 nm fundamental laser. Ultimately, the maximum slope efficiency of the first Stokes light (1240 nm) is 16.8%, and the corresponding output power is about 0.6 W. The maximum peak power is 2.5 kW when the power of 808 nm LD is 34.7 W.

A solid-state colorimetric fluorescence Pb2+-sensing scheme: mechanically-driven CsPbBr3 nanocrystallization in glass.

Highly toxic Pb2+ poses a great threat to the health of human beings and ecosystems, urgently calling for an efficient Pb2+ detection method. Herein, we demonstrated a brand-new solid-state fluorescence Pb2+-sensing scheme based on a type of Pb2+-responsive borate glass powder that is able to precipitate CsPbBr3 nanocrystals on the glass surface upon grinding with Pb2+ sources, following a mechanically driven glass crystallization mechanism. Pb2+ sensing is achieved via the Pb2+ concentration-dependent green emission of CsPbBr3 as an indicator signal and independent red emission of Eu3+ as a reference signal. Under UV light irradiation, the obvious emissive color variation from red to green as Pb2+ concentration varies enables the intuitive Pb2+-sensing by naked eyes. With the aid of a spectrometer and smartphone, Pb2+ concentration can be quantitatively determined with the detection limit as low as ∼70 ppm and ∼400 ppm, respectively. The semi-quantitative Pb2+ detection is also possible by comparing the emissive color with the calibrated color card. Hopefully, the proposed solid-state fluorescence Pb2+-sensing strategy with high selectivity can be used for portable and quick Pb2+ analysis in daily life.

An Ultrashort Wavelength Multi/Demultiplexer via Rectangular Liquid-Infiltrated Dual-Core Polymer Optical Fiber.

We propose a rectangular liquid-infiltrated dual-core polymer optical fiber (POF) for short-range communication systems by the beam propagation method (BPM). The POF multi/demultiplexer (MUX/DEMUX) at the wavelengths of 0.52/0.65-µm, 0.57/0.65-µm, and 0.52/0.57-µm are devised. The simulation results demonstrate that the ultrashort length of three ultrashort POF couplers are 183.6 µm, 288 µm, and 799.5 µm. Compared with the conventional optical fiber couplers, these results could have significant applications in the miniaturization of optical devices for visible light communication.

Investigation on 1.3 µm laser performance with Nd:Gd0.69Y0.3TaO4 and Nd:Gd0.68Y0.3NbO4 mixed crystals.

Laser performances around 1.3 µm are investigated in 879 nm laser diode (LD) end pumped Nd3+ doped mixed crystals with Nd:Gd0.69Y0.3TaO4 and Nd:Gd0.68Y0.3NbO4 crystals for the first time to our best knowledge. The maximum average power in LD end pumped Nd:Gd0.69Y0.3TaO4 1328 nm laser reaches 435 mW at 50 Hz with an optical-to-optical efficiency of 5.0% and a slope efficiency of 6.9%. In comparison, the highest average power of LD end pumped Nd:Gd0.68Y0.3NbO4 laser at 1337 nm is 190 mW at 50 Hz, corresponding to an optical-to-optical efficiency of 3.5% and a slope efficiency of 4.2%.