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2.
Polymers (Basel) ; 13(1)2020 Dec 22.
Article in English | MEDLINE | ID: mdl-33375196

ABSTRACT

The fire behaviour of flexible polyurethane foams was studied using a cone calorimeter, with a special emphasis on the collapse step. Only one peak of heat release rate, ranging from 200 to 450 kW/m2, is observed for thin foams, depending on the foam density and the heat flux. On the contrary, heat release rate (HRR) curves exhibit two peaks for 10 cm-thick foams, the second one corresponding to the pool fire formed after foam collapse. In all cases, the collapse occurs at a constant rate through the whole thickness. The rate of the recession of the front was calculated using digital and infrared cameras. Interestingly, its value is relatively constant whatever the heat flux (especially between 25 and 35 kW/m2), probably because of the very low heat conductivity preventing heat transfer through the thickness. The rate increases for the lightest foam but the fraction of burnt polymer during collapse is constant. Therefore, the pool fire is more intense for the densest foam. A simple macroscopic model taking into account only the heat transfer into the foam leads to much lower front recession rates, evidencing that the collapse is piloted by the cell walls' rigidity.

3.
Carbohydr Polym ; 184: 1-8, 2018 Mar 15.
Article in English | MEDLINE | ID: mdl-29352899

ABSTRACT

Alginate derived from seaweed is a natural polysaccharide able to form stable gel through carbohydrate functional groups largely used in the food and pharmaceutical industry. This article deals with the use of sodium alginate as an adhesive binder for wood fibres/textile waste fibres biocomposites. Several aldehyde-based crosslinking agents (glyoxal, glutaraldehyde) were compared for various wood/textile waste ratios (100/0, 50/50, 60/40, 70/30 and 0/100 in weight). The fully biomass derived composites whose properties are herewith described satisfy most of the appropriate requirements for building materials. They are insulating with a thermal conductivity in the range 0.078-0.089 W/m/K for an average density in the range 308-333 kg/m3 according to the biocomposite considered. They are semi-rigid with a maximal mechanical strength of 0.84 MPa under bending and 0.44 MPa under compression for 60/40 w/w wood/textile waste biocomposites with a glutaraldehyde crosslinking agent.

4.
J Mater Sci Mater Med ; 28(10): 145, 2017 Aug 19.
Article in English | MEDLINE | ID: mdl-28823063

ABSTRACT

For many practitioners, longevity of full glass ceramic crowns in the posterior area, molars and premolars, remains a real challenge. The purpose of this article is to identify and evaluate the parameters that can significantly influence their resistance when preparing a tooth. The analysis proposed in this article relies on interrelated studies conducted at three levels: in vitro (mechanical tests), in silico (finite elements simulations) and in vivo (clinical survival rates). The in vitro and the in silico studies proved that an appropriate variation of the geometric design of the preparations enables to increase up to 80% the mechanical strength of ceramic reconstructions. The in vivo clinical study of CAD/CAM full ceramic crowns was performed in accordance with the principles stated within the in vitro and the in silico studies and provided a 98.97% success rate over a 6 years period. The variations of geometric design parameters for dental preparation allows for reconstructions with a mechanical breaking up to 80% higher than that of a non-appropriate combination. These results are confirmed in clinical practice.


Subject(s)
Bicuspid , Ceramics , Computer-Aided Design , Molar , Tooth Crown , Cementation/methods , Dental Materials , Dental Restoration Failure , Humans , Materials Testing , Mechanics
5.
Dent Mater ; 28(10): e229-38, 2012 Oct.
Article in English | MEDLINE | ID: mdl-22717295

ABSTRACT

OBJECTIVE: The dentin-enamel junction (DEJ) plays a crucial role in dental biomechanics; however, little is known about its structure and mechanical behavior. Nevertheless, natural teeth are a necessary model for prosthetic crowns. The mechanical behavior of the natural DEJ and the dentin ceramic junction (DCJ) manufactured with a CAD-CAM system are compared. METHODS: The reference samples undergo no modification, while the experimental samples were drilled to receive a cemented feldspathic ceramic crown. Longitudinally cut samples were used to achieve a planar object observation and to look "inside" the tooth. A complete apparatus enabling the study of the compressive mechanical behavior of the involved tooth by a non-contact laser speckle interferometry (SI) was developed to allow nanometric displacements to be tracked during the compression test. RESULTS: It is observed that the DEJ acted as a critical zone accommodating the movement between dentin and enamel. A smooth transition occurs between dentin and enamel. In the modeled prosthetic, the same kind of accommodation effects also occurs, but with a steeper transition slope between dentin and ceramic. SIGNIFICANCE: On the natural tooth, the stress accommodation arises from a differential behavior between enamel and dentin from the DEJ. In the ceramic crown, the cemented dentin-ceramic junction should play this role. This study demonstrates the possible realization of prosthetic crown reconstructions approaching biomechanical behaviors.


Subject(s)
Ceramics/chemistry , Crowns , Dental Enamel/chemistry , Dental Prosthesis Design/methods , Dentin/chemistry , Tooth Crown/chemistry , Computer-Aided Design , Dental Stress Analysis , Humans , Image Interpretation, Computer-Assisted , Interferometry/instrumentation , Interferometry/methods
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