Dealumination and Characterization of Natural Mordenite-Rich Tuffs.

The present study evaluates the feasibility of partially dealuminated natural mordenite as a catalyst support by studying improvement in its textural properties. This is the first study that reports the dealumination of natural zeolite-based tuffs from Ecuador. For this purpose, mordenite-rich tuffs were obtained from deposits close to Guayaquil, Ecuador. The raw material was micronized in order to increase its surface, and treated with NH4Cl. NH4+ cation-exchanged samples were finally reacted with HCl(aq) to complete the dealumination process. The partially dealuminated samples were characterized using techniques such as XRD, FT-IR, SEM-EDS, and identification of their textural properties. Dealumination with HCl(aq) increased the Si/Al ratio up to 9 and kept the crystallographic structure of natural mordenite, as XRD results showed that the structure of mordenite was not altered after the dealumination process. On the other hand, textural properties such as surface area and microporosity were improved as compared to natural mordenite. In view of these results, the feasibility of using natural mordenite as a catalyst support is discussed in this study.

The use of zeolite-based geopolymers as adsorbent for copper removal from aqueous media.

Copper has been proven to have hazardous effects on human beings depending on its concentration levels. Recently, there has been a growing interest in developing geopolymers using local industrial minerals and by-products. However, research on the adsorption of heavy metals by geopolymer based on mordenite-rich tuffs is still limited. The geopolymer adsorbents have been synthesized using natural Ecuadorian zeolite-rich tuffs containing quartz, mordenite calcite and amorphous content with 20.8%, 28.5%, 4.2% and 46.4%, respectively. The geopolymers showed a maximum compressive strength of 26.86 MPa for 28 d of curing time. In the present study, an Ecuadorian zeolite-based geopolymer's removal capacity on copper ions in aqueous solutions, varying concentration and contact time were tested. Kinetic models were developed using pseudo first-order, pseudo second-order and the Elovich model. The adsorption data, using Cu2+ concentrations from 20 to 160 ppm, at 25°C were described by the Langmuir and Freundlich isotherms. Linear coefficient of determination (R 2) results show that the Langmuir model fits the best. The attained adsorption capacity of 52.63 mg g-1 demonstrates the low-cost geopolymer's effectiveness for this study and its competitiveness compared with other studies. Adsorption kinetics follows the pseudo second-order kinetics model at the lower initial concentration of Cu2+.

Effects of Recycled Rubber Particles Incorporated as Partial Sand Replacement on Fresh and Hardened Properties of Cement-Based Concrete: Mechanical, Microstructural and Life Cycle Analyses.

Cement is one of the most valuable materials in today's society, as it is used in most construction developments known to mankind. However, the energy intensive process and significant environmental impacts related to the production of Ordinary Portland Cement have shown the importance of searching for more sustainable materials. Concrete uses different aggregates added to the cement binder to lower, not only cost, but other factors like environmental burden, while maintaining good mechanical properties. This study analyzes the properties of fresh and hardened concrete incorporating recycled rubber to replace fine aggregate. Locally sourced 2 mm diameter rubber was incorporated in a regular strength concrete matrix into three different replacement levels, i.e., 3%, 5%, and 10%. Compression, tensile, flexural, and modulus of elasticity of hardened concrete were carried out in specimens aged 7, 14, and 28 days. In addition, non-destructive ultrasonic pulse velocity and rebound number tests were only performed on specimens aged 28 days. Once the tests were carried out, the fresh and hardened concrete properties were obtained. Similarly, the compressive and flexural strengths had the exact relationship between the values obtained. On the other hand, the modulus of elasticity tends to decrease due to the presence of the rubber. Consequently, it is recommended not to develop mix designs with more than 5% rubber because it is not meaningfully affected. The fine aggregate can be partially replaced by the rubber, keeping almost the same performance compared with sand-only counterparts. In addition, the life cycle assessment showed a reduction of up to 40% in the global warming potential. In fact, the 15% recycled rubber concrete mix has a climate change indicator of approximately 245 kg of CO2 eq.

Preparation, characterization, and evaluation of compressive strength of polypropylene fiber reinforced geopolymer mortars.

The study of the fiber-matrix interface represents a crucial topic to determine the mechanical performance of geopolymer-based materials reinforced with polypropylene fibers (PPF). This research proposes the use of natural zeolite in the preparation geopolymers mortars through alkaline activation with NaOH, Ca(OH)2 and Na2SiO3, and with river sand as a fine aggregate. PPF were incorporated into the geopolymer-based mortar matrix in different proportions like 0, 0.5, and 1 wt.%. The mortars were cured for 24 h at 60 °C and then aged for six days more at room temperature. All samples analyzed through compressive strength were also characterized by X-ray diffraction, thermal analysis, Infrared Spectroscopy, and scanning electron microscopy techniques. The results indicated that the best mix design among the ones used: NaOH (10 M), Na2SiO3/NaOH = 3, Ca(OH)2 = 1.5 wt.% and PPF = 0.5 wt.%. The optimum mix design showed a compressive strength of 4.63 MPa on average. Besides, the fibers enhanced the compressive strength of those samples which the PP fibers probably have better dispersion inside the matrix of the geopolymer mortar.