Mitigating CO2 emissions through an industrial symbiosis approach: Leveraging cork ash carbonation.

This study explores for the first time the potential use of carbonation as a method for managing cork ash, a byproduct of biomass waste incineration. Additionally, the cork ash was combined with fly ash from municipal solid waste incineration to leverage the carbonation reaction's ability to stabilize heavy metals. The findings suggest that subjecting biomass ash to carbonation can lead to the formation of mineral carbonates, effectively capturing CO2 and reducing its release into the atmosphere. The combination of various alkaline wastes and the stabilization of leachable heavy metals through carbonation reactions also opens opportunities for synergies between different industrial sectors. Finally, the study proposes a route for the obtained materials valorisation via 'end of waste': the reuse of the resulting materials as substitutes for natural resources, particularly in applications like building materials and polymer composites, can further enhance carbon dioxide savings.

Sustainability Analysis of Processes to Recycle Discharged Lithium-Ion Batteries, Based on the ESCAPE Approach.

There are several recycling methods to treat discharged lithium-ion batteries, mostly based on pyrometallurgical and hydrometallurgical approaches. Some of them are promising, showing high recovery efficiency (over 90%) of strategic metals such as lithium, cobalt, and nickel. However, technological efficiency must also consider the processes sustainability in terms of environmental impact. In this study, some recycling processes of spent lithium-ion batteries were considered, and their sustainability was evaluated based on the ESCAPE "Evaluation of Sustainability of material substitution using CArbon footPrint by a simplifiEd approach" approach, which is a screening tool preliminary to the Life Cycle Assessment (LCA). The work specifically focuses on cobalt recovery comparing the sustainability of using inorganic or organic acid for the leaching of waste derived from lithium-ion batteries. Based on the possibility to compare different processes, for the first time, some considerations about technologies optimization have been done, allowing proposing strategies able to save chemicals. In addition, the energy mix of each country, to generate electricity has been considered, showing its influence on the sustainability evaluation. This allows distinguishing the countries using more low-carbon sources (nuclear and renewables) for a share of the electricity mix, where the recycling processes result more sustainable. Finally, this outcome is reflected by another indicator, the eco-cost from the virtual pollution model 99' proposed by Vogtländer, which integrates the monetary estimation of carbon footprint.

Environmental Impact of Surgical Masks Consumption in Italy Due to COVID-19 Pandemic.

The COVID-19 pandemic suddenly changed the lifestyle of billions of people. Face masks became indispensable to protect from the contagion providing a significant environmental impact. The aim of this work is to propose possible solutions to decrease masks' impact on the environment. For this reason, different masks (surgical and fabric) were considered, and the CO2 emissions associated with the mask materials production were calculated. Carbon Footprint (CF) for each material composing the masks was evaluated through the database Ces Selector 2019. The software Qgis (version 2.18.20) allows us to elaborate the CO2 emissions maps for each Italian region. Finally, for surgical masks, which are often imported from abroad, the CF related to transport was considered. It results that fabric masks are a sustainable solution to prevent contagion. The total CO2 emission associated with the use of fabric masks from the beginning of the pandemic (March 2020) to December 2021 resulted in about 7 kton compared to 350 kton for surgical masks.

Analysis of the lockdown effects due to the COVID-19 on air pollution in Brescia (Lombardy).

SARS-CoV-2 virus (COVID-19) pandemic has impacted several countries, with also some differences at local levels. When lockdown restrictions were imposed, the concentrations of some air pollutants were reduced, as reported in some other cities in the world. This was often considered a positive by-product of the pandemic. However, often literature reporting the connection of air quality (AQ) and lockdown, suffers of limited and incomplete data analysis, not considering, for example, some confounding factors. This work presents a methodology, and the results of its application, to assess the impact of pandemic restrictions on AQ (in particular nitrogen oxides, NO2 and particulate matter, PM10) in spring 2020 in Brescia, located in one of the most affected areas in terms of virus diffusion and in one of the most polluted areas in Europe (Po Valley, Italy). In particular, the proposed methodology integrates data and AQ modelling simulations to distinguish between the changes in the PM10 and NO2 pollutants concentration that occurred due to the restriction measures and due to other factors, like spatial-temporal characteristics (for example the seasonality), meteorological factors, and governmental actions that were introduced in the past to improve the air quality. Results show that NO2 is strongly dependent to traffic emission. On the contrary, although the expected decrease in PM10 concentrations, the results highlight that the reduction of transport emission would not help to avoid severe air pollution, due to the other pollution sources that contribute to its origin. The results presented for the first time in this work are of particular interest because they may be used as a basis to investigate in more details the sources that can impact on the air quality in Brescia, with the aim to propose effective measures able to reduce it.

A post-pandemic sustainable scenario: What actions can be pursued to increase the raw materials availability?

On January 30, 2020, COVID-19 outbreak, detected for the first time in Wuhan (China), was declared by WHO a Public Health Emergency. In a strongly connected world, the consequent slowdown of the Chinese economy contributed to disrupt the global supply chains of several products. In a post-pandemic scenario, the expected rapid increase in demand of critical raw materials (associated with the transition to more green energy sources), coupled with the problems that some mining activities are relegated only in certain countries and regions, must be considered in a sustainable perspective. This work analyses the literature about (critical) raw materials and COVID-19, not only to present the impact of the pandemic on their supply, but also to propose some actions that should be pursued in a post-pandemic renaissance scenario, to increase raw materials availability, with great attention to most critical ones, in the frame of circular economy principles. The post-pandemic possibilities are evaluated and suitable actions are suggested to secure the raw materials availability for the foreseen increase of investments in crucial and strategic sectors, in accord with the UN Sustainable Development Goals (SDGs). The proposed actions can be summarized as policy, strategy, economy, and technology activities.