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1.
Chem Commun (Camb) ; 50(87): 13289-91, 2014 Nov 11.
Article in English | MEDLINE | ID: mdl-25233370

ABSTRACT

Two new Eu(3+) and Au(3+) BODIPY-complexes capable of chromo-fluorogenically detecting micromolar concentrations of V-type nerve agent surrogates by a simple displacement assay are described.


Subject(s)
Boron Compounds/chemistry , Chemical Warfare Agents/analysis , Europium/chemistry , Gold/chemistry , Organometallic Compounds/chemistry , Organothiophosphorus Compounds/analysis , Molecular Structure , Organometallic Compounds/chemical synthesis
2.
Molecules ; 15(12): 9135-44, 2010 Dec 10.
Article in English | MEDLINE | ID: mdl-21150827

ABSTRACT

The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields γ-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles. A comparative study with the reactivity of this enediolates with epoxides is included.


Subject(s)
Aziridines/chemistry , Amino Acids/chemical synthesis , Amino Acids/chemistry , Epoxy Compounds/chemistry , Ketones/chemistry
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