1.
Chem Commun (Camb)
; 50(87): 13289-91, 2014 Nov 11.
Article
in English
| MEDLINE
| ID: mdl-25233370
ABSTRACT
Two new Eu(3+) and Au(3+) BODIPY-complexes capable of chromo-fluorogenically detecting micromolar concentrations of V-type nerve agent surrogates by a simple displacement assay are described.
Subject(s)
Boron Compounds/chemistry , Chemical Warfare Agents/analysis , Europium/chemistry , Gold/chemistry , Organometallic Compounds/chemistry , Organothiophosphorus Compounds/analysis , Molecular Structure , Organometallic Compounds/chemical synthesis
2.
Molecules
; 15(12): 9135-44, 2010 Dec 10.
Article
in English
| MEDLINE
| ID: mdl-21150827
ABSTRACT
The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields γ-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles. A comparative study with the reactivity of this enediolates with epoxides is included.